The Influence of Temperature on the Oxidation Potentials of Mixtures of Ferric and Ferrous Chlorides in Hydrochloric Acid Solution

1932 ◽  
Vol 36 (2) ◽  
pp. 679-687 ◽  
Author(s):  
S. R. Carter ◽  
T. J. Glover
2021 ◽  
Vol 62 (3) ◽  
pp. 204-212
Author(s):  
Abdel Fouda ◽  
Asmaa Idress ◽  
Mohamed Atia ◽  
Mohamed Yassen

The corrosion performance of aluminum in 1 M hydrochloric acid solution in the existence and absence of Candesartan drug was examined utilizing, potentiodynamic polarization (PDP) and AC impedance (EIS) tests. It was found that the inhibition efficacy (%IE) of Candesartan drug was influenced by its doses and temperature and reached to 92.9% at 40x10-6 M, 30oC. The adsorption isotherm agreed with Langmuir model. From Tafel data the investigated Candesartan drug acts as mixed kind inhibitor. The influence of temperature on the rate of dissolution and the thermodynamic parameters in the existence and absence of Candesartan drug were also, studied and explained. All tests gave similar results.


10.30544/71 ◽  
2015 ◽  
Vol 21 (4) ◽  
pp. 253-258 ◽  
Author(s):  
Branislav Marković ◽  
Miroslav Sokić ◽  
Željko Kamberović ◽  
Dragana Živković ◽  
Nada Štrbac ◽  
...  

Present work is focused on the copper (I) sulphide leaching with sodium chloride in hydrochloric acid solution and with introduction of gaseous oxygen. Chemical reactions of leaching and their thermodynamic probabilities are predicted based on the literature data and products which were formed during the process and the overall leaching reaction was defined. The influence of temperature and time on the leaching degree of copper was experimentally determined. The quantity of dissolved copper increases with the increase of both investigated parameters. Elemental sulphur was formed as the main leaching product, precipitated at the particle surfaces and chloride ions have a role to disrupt the creation of this passive layer.


1975 ◽  
Vol 28 (9) ◽  
pp. 1901 ◽  
Author(s):  
SF Lincoln ◽  
AC Sandercock ◽  
DR Stranks

The parameters describing chloride exchange on indium(III), determined by 35Cl N.M.R., are: k(298 K)= (8.8�0+4) x 106 s-1, ΔH? = 45.7�2.3 kJ mol-1 and ΔS? = 42�8 J mol-1 K-1; and k(298 K)= (2.0�0.1)x106 s-1, ΔH? = 37.7�1.9 kJ mol-1, and ΔS? = 3�6 J mol-1 K-1 in 10.95M and 7.00M aqueous hydrochloric acid respectively, calculated from the observed exchange rate kex4[InCl4(H2O)2-].��� For thallium(III) lower limits of kex(219 K) = 1.6 x 106 s-1 and 1.3 x 106 s-1 were obtained in 10.95M and 7.00M aqueous hydrochloric acid, respectively, where [TlCl6]3- is assumed to be the exchanging species.


RSC Advances ◽  
2017 ◽  
Vol 7 (40) ◽  
pp. 24576-24588 ◽  
Author(s):  
H. S. Gadow ◽  
M. M. Motawea

The inhibitive effect and adsorption behavior of ginger roots extract (GRE) on the corrosion of carbon steel in 1.0 M HCl solution at different temperatures were investigated.


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