Laser flash photolysis determination of absolute rate constants for reactions of bromine atoms in solution

1993 ◽  
Vol 115 (18) ◽  
pp. 8340-8344 ◽  
Author(s):  
J. C. Scaiano ◽  
M. Barra ◽  
M. Krzywinski ◽  
R. Sinta ◽  
G. Calabrese
Keyword(s):  
Rate Constants ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Absolute Rate

scholarly journals Measurements of Rate Constants for HO2 + NO and NH2 + NO Reactions by Time-Resolved Photoionization Mass Spectrometry

1995 ◽  
Vol 16 (1) ◽  
pp. 43-51 ◽  
Author(s):  
Takashi Imamura ◽  
Nobuaki Washida
Keyword(s):  
Mass Spectrometry ◽  
Rate Constants ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Absolute Rate ◽  
Time Resolved ◽  
Photoionization Mass Spectrometry

Absolute rate constants for HO2 + NO and NH2 + NO reactions were measured by a photoionization mass spectrometry coupled with a laser flash photolysis. HO2 and NH2 radicals were photoionized by an Ar resonance lamp and were detected as their parent ions (HO2+ and NH2+). The rate constants were determined to be K(HO2 + NO)=(6.5  ± 2.0) 10−12cm3molecule−1s−1K(NH2 + NO)=(1.9  ± 0.3) 10−11cm3molecule−1s−1 Both rates are consistent with those previously reported.

Direct detection of methylphenylgermylene and 1,2-dimethyl-1,2-diphenyldigermene — Kinetic studies of their reactivities in solution

2006 ◽  
Vol 84 (7) ◽  
pp. 934-948 ◽  
Author(s):  
William J Leigh ◽  
Ileana G Dumbrava ◽  
Farahnaz Lollmahomed
Keyword(s):  
Acetic Acid ◽  
Rate Constants ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Direct Detection ◽  
Kinetic Studies ◽  
Laser Flash ◽  
Absolute Rate ◽  
Hydrocarbon Solvents ◽  
Diffusion Controlled

Photolysis of 1,3,4-trimethyl-1-phenylgermacyclopent-3-ene (5) in hydrocarbon solvents containing isoprene, methanol, or acetic acid affords 2,3-dimethyl-1,3-butadiene (DMB) and the expected trapping products of methyl phenylgermylene (GeMePh) in chemical yields exceeding 90%. The germylene has been detected in hexane solution by laser flash photolysis as a short-lived species (τ ~ 2 µs) exhibiting a UV-vis absorption spectrum centered at λmax = 490 nm. It decays with second-order kinetics and a rate constant close to the diffusion-controlled limit, with the concomitant growth of a second longer-lived transient (λmax = 420 nm) that is assigned to a mixture of (E)- and (Z)-1,2-dimethyl-1,2-diphenyldigermene (4). Absolute rate constants have been determined for the reactions of the germylene with primary and tertiary amines (n-BuNH2 and Et3N, respectively), acetic acid (AcOH), a terminal alkyne and alkene, isoprene, DMB, CCl4, and the group 14 hydrides Et3SiH and Bu3SnH. GeMePh is slightly more reactive than GePh2 towards all the reagents studied in this work; both are significantly less reactive than GeMe2 toward the same substrates. Absolute rate constants for the reactions of 4 have also been measured or assigned upper limits in every case and are compared to previously reported values for tetraphenyl- and tetramethyl-digermene with the same reagents.Key words: germylene, digermene, kinetics, laser flash photolysis, germirane, germirene, vinylgermirane, complex, UV–vis spectrum, insertion, addition.

Determination of rate constants for some reactions of CBr radicals by VUV laser flash photolysis

1983 ◽  
Vol 80 (3) ◽  
pp. 345-350 ◽  
Author(s):  
L. Hellner ◽  
K.T.V. Grattan ◽  
M.H.R. Hutchinson
Keyword(s):  
Rate Constants ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash

Spectral Properties and Absolute Rate Constants for β-Scission of Ring-Substituted Cumyloxyl Radicals. A Laser Flash Photolysis Study

2002 ◽  
Vol 67 (7) ◽  
pp. 2266-2270 ◽  
Author(s):  
Enrico Baciocchi ◽  
Massimo Bietti ◽  
Michela Salamone ◽  
Steen Steenken
Keyword(s):  
Rate Constants ◽  
Spectral Properties ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Absolute Rate

Proton Transfer in Anthocyanins and Related Flavylium Salts. Determination of Ground-State Rate Constants with Nanosecond Laser Flash Photolysis

2002 ◽  
Vol 106 (7) ◽  
pp. 1248-1255 ◽  
Author(s):  
Antonio L. Maçanita ◽  
Paulo F. Moreira, ◽  
João C. Lima ◽  
Frank H. Quina ◽  
Chang Yihwa ◽  
...  
Keyword(s):  
Proton Transfer ◽  
Ground State ◽  
Rate Constants ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Nanosecond Laser ◽  
State Rate ◽  
Nanosecond Laser Flash Photolysis

A Laser Flash Photolysis Study of the Photochemistry of (Phenylethynyl)pentamethyldisilane. Absolute Rate Constants for Trapping of a Reactive 1-Silaallene by Nucleophiles

1997 ◽  
Vol 16 (26) ◽  
pp. 5804-5810 ◽  
Author(s):  
Corinna Kerst ◽  
Ralph Ruffolo ◽  
William J. Leigh
Keyword(s):  
Rate Constants ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Absolute Rate

Singlet Methylene Removal Rate Constants from the (0,1,0) Vibrational Level: Enhancement via Complex-Mediated Vibrational Relaxation

2001 ◽  
Vol 215 (6) ◽  
Author(s):  
M.A. Buntine ◽  
G.J. Gutsche ◽  
W.S. Staker ◽  
M.W. Heaven ◽  
K.D. King ◽  
...  
Keyword(s):  
Vibrational Level ◽  
Rate Constants ◽  
Vibrational Relaxation ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Removal Rate ◽  
Laser Flash ◽  
Laser Absorption ◽  
Photolysis Laser ◽  
Singlet Methylene

The technique of laser flash photolysis/laser absorption has been used to obtain absolute removal rate constants for singlet methylene,

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