"Redox Tautomerism" in High-Valent Metal-oxo-aquo Complexes. Origin of the Oxygen Atom in Epoxidation Reactions Catalyzed by Water-Soluble Metalloporphyrins. [Erratum to document cited in CA122:105083]

1994 ◽  
Vol 116 (26) ◽  
pp. 12135-12135 ◽  
Author(s):  
Jean Bernadou ◽  
Anne-Sylvie Fabiano ◽  
Anne Robert ◽  
Bernard Meunier
Keyword(s):  
Oxygen Atom ◽  
Water Soluble ◽  
High Valent

Origin of the oxygen atom in hydroxylation reactions catalyzed by water-soluble metalloporphyrins

1995 ◽  
Vol 59 (2-3) ◽  
pp. 508
Author(s):  
R.J. Balahura ◽  
A. Sorokin ◽  
J. Bernadou ◽  
B. Meunier
Keyword(s):  
Oxygen Atom ◽  
Water Soluble

scholarly journals Catalysis of “outer-phase” oxygen atom exchange reactions by encapsulated “inner-phase” water in {V15Sb6}-type polyoxovanadates

2016 ◽  
Vol 7 (4) ◽  
pp. 2684-2694 ◽  
Author(s):  
Michael Wendt ◽  
Ulrike Warzok ◽  
Christian Näther ◽  
Jan van Leusen ◽  
Paul Kögerler ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Water Molecule ◽  
Oxygen Exchange ◽  
Water Soluble ◽  
Exchange Reactions ◽  
Phase Water

A water molecule encapsulated inside water-soluble {V15Sb6} antimonato polyoxovanadate cages accelerates oxygen-exchange reactions in the cluster periphery.

Biomimetic models of nitric oxide synthase for the oxidation of oximes to carbonyl compounds catalyzed by water-soluble manganese porphyrins in aqueous solution

2011 ◽  
Vol 15 (03) ◽  
pp. 211-216 ◽  
Author(s):  
Qing-Gang Ren ◽  
Xian-Tai Zhou ◽  
Hong-Bing Ji
Keyword(s):  
Carbonyl Compounds ◽  
Water Soluble ◽  
Ambient Conditions ◽  
Manganese Porphyrin ◽  
Manganese Porphyrins ◽  
Vis Spectroscopy ◽  
Excellent Activity ◽  
High Valent ◽  
Manganese Species ◽  
Oxide Synthase

A mild green and efficient approach for hydrogen peroxide oxidative converting oximes to the corresponding carbonyl compounds with a water-soluble manganese porphyrin as catalyst in water/acetone mixture has been developed. The water-soluble manganese porphyrin showed an excellent activity for the oxidative deoximation reactions of various oximes under ambient conditions in the absence of any additive. The oxidative deoximation was through the formation of high valent oxo-manganese species, which was confirmed by in situ UV-vis spectroscopy.

Spectroscopic and electrochemical studies of high-valent water soluble manganese porphyrine. Electrocatalytic water oxidation

2014 ◽  
Vol 135 ◽  
pp. 301-310 ◽  
Author(s):  
Maria Alejandra Luna ◽  
Fernando Moyano ◽  
Leonides Sereno ◽  
Fabiana D’Eramo
Keyword(s):  
Water Oxidation ◽  
Water Soluble ◽  
Electrochemical Studies ◽  
High Valent
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