Photochemistry and Surface Properties of Self-Assembled Monolayers of cis- and trans-4-Cyano-4'-(10-thiodecoxy)stilbene on Polycrystalline Gold

1995 ◽  
Vol 117 (6) ◽  
pp. 1845-1846 ◽  
Author(s):  
Michael O. Wolf ◽  
Marye Anne Fox
Keyword(s):  
Surface Properties ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Polycrystalline Gold ◽  
Self Assembled ◽  
Cis And Trans

Air Oxidation of Self-Assembled Monolayers on Polycrystalline Gold:  The Role of the Gold Substrate

Langmuir ◽  
1998 ◽  
Vol 14 (22) ◽  
pp. 6419-6423 ◽  
Author(s):  
Mong-Tung Lee ◽  
Chen-Chan Hsueh ◽  
Michael S. Freund ◽  
Gregory S. Ferguson
Keyword(s):  
Self Assembled Monolayers ◽  
Gold Substrate ◽  
Air Oxidation ◽  
Assembled Monolayers ◽  
Polycrystalline Gold ◽  
Self Assembled

scholarly journals The Potential of a Nanostructured Titanium Oxide Layer with Self-Assembled Monolayers for Biomedical Applications: Surface Properties and Biomechanical Behaviors

2020 ◽  
Vol 10 (2) ◽  
pp. 590 ◽  
Author(s):  
Wen-Chien Lan ◽  
Ta-Sen Huang ◽  
Yung-Chieh Cho ◽  
Yueh-Tzu Huang ◽  
Christopher J. Walinski ◽  
...  
Keyword(s):  
Titanium Oxide ◽  
Surface Properties ◽  
Contact Stiffness ◽  
Substrate Surface ◽  
Stress Shielding ◽  
Shielding Effect ◽  
Self Assembled Monolayers ◽  
Nanostructured Titanium ◽  
Assembled Monolayers ◽  
Self Assembled

This study investigated the surface properties and biomechanical behaviors of a nanostructured titanium oxide (TiO) layer with different self-assembled monolayers (SAMs) of phosphonate on the surface of microscope slides. The surface properties of SAMs were analyzed using scanning electron microscopy, X-ray photoemission spectroscopy, and contact angle goniometry. Biomechanical behaviors were evaluated using nanoindentation with a diamond Berkovich indenter. Analytical results indicated that the homogenous nanostructured TiO surface was formed on the substrate surface after the plasma oxidation treatment. As the TiO surface was immersed with 11-phosphonoundecanoic acid solution (PUA-SAM/TiO), the formation of a uniform SAM can be observed on the sample surface. Moreover, the binding energy of O 1s demonstrated the presence of the bisphosphonate monolayer on the SAMs-coated samples. It was also found that the PUA-SAM/TiO sample not only possessed a higher wettability performance, but also exhibited low surface contact stiffness. A SAM surface with a high wettability and low contact stiffness could potentially promote biocompatibility and prevent the formation of a stress shielding effect. Therefore, the self-assembled technology is a promising approach that can be applied to the surface modification of biomedical implants for facilitating bone healing and osseointegration.

Self-assembled monolayers of parent and derivatized [n]staffane-3,3(n-1)-dithiols on polycrystalline gold electrodes

1992 ◽  
Vol 114 (25) ◽  
pp. 9943-9952 ◽  
Author(s):  
Yaw S. Obeng ◽  
Mark E. Laing ◽  
Andrienne C. Friedli ◽  
Huey C. Yang ◽  
Dongni Wang ◽  
...  
Keyword(s):  
Self Assembled Monolayers ◽  
Gold Electrodes ◽  
Assembled Monolayers ◽  
Polycrystalline Gold ◽  
Self Assembled

scholarly journals Electron-beam patterned self-assembled monolayers as templates for Cu electrodeposition and lift-off

2012 ◽  
Vol 3 ◽  
pp. 101-113 ◽  
Author(s):  
Zhe She ◽  
Andrea DiFalco ◽  
Georg Hähner ◽  
Manfred Buck
Keyword(s):  
Electron Beam ◽  
Copper Surface ◽  
Self Assembled Monolayers ◽  
Metal Structures ◽  
Step Procedure ◽  
Assembled Monolayers ◽  
Polycrystalline Gold ◽  
Self Assembled ◽  
Lift Off ◽  
Surface Morphologies

Self-assembled monolayers (SAMs) of 4'-methylbiphenyl-4-thiol (MBP0) adsorbed on polycrystalline gold substrates served as templates to control electrochemical deposition of Cu structures from acidic solution, and enabled the subsequent lift-off of the metal structures by attachment to epoxy glue. By exploiting the negative-resist behaviour of MBP0, the SAM was patterned by means of electron-beam lithography. For high deposition contrast a two-step procedure was employed involving a nucleation phase around −0.7 V versus Cu2+/Cu and a growth phase at around −0.35 V versus Cu2+/Cu. Structures with features down to 100 nm were deposited and transferred with high fidelity. By using substrates with different surface morphologies, AFM measurements revealed that the roughness of the substrate is a crucial factor but not the only one determining the roughness of the copper surface that is exposed after lift-off.

Sign in / Sign up

Export Citation Format

Share Document