Di-tert-butyl nitroxide quenching of the photoaddition of olefins to the carbon-nitrogen double bond of 3-ethoxyisoindolenone

1977 ◽  
Vol 99 (19) ◽  
pp. 6332-6340 ◽  
Author(s):  
David R. Anderson ◽  
Joseph S. Keute ◽  
Tad H. Koch ◽  
Robert H. Moseley
Keyword(s):  
Double Bond ◽  
Tert Butyl ◽  
Nitrogen Double Bond

Configuration stability at the carbon-nitrogen double bond

1962 ◽  
Vol 3 (26) ◽  
pp. 1269-1274 ◽  
Author(s):  
D.Y. Curtin ◽  
C.G. McCarty
Keyword(s):  
Double Bond ◽  
Nitrogen Double Bond

Mechanisms of Nucleophilic Attack at Carbon Nitrogen Double-Bonds: The Reaction of Benzohydrazonoyl Halides With Amines

1987 ◽  
Vol 40 (10) ◽  
pp. 1777 ◽  
Author(s):  
AF Hegarty ◽  
P Rigopoulos ◽  
JE Rowe
Keyword(s):  
Double Bond ◽  
Nucleophilic Attack ◽  
Rate Data ◽  
Double Bonds ◽  
Nitrogen Double Bond

Rate data for the reaction of a series of benzohydrazonoyl halides with pyrrolidine and butan- 1-amine at 303 K are presented. Linear Hammett plots were obtained with each amine. The mechanism of the reactions and the stereochemical outcome of these displacements at the carbon-nitrogen double bond are discussed.

scholarly journals Chemoselective and metal-free reduction of α,β-unsaturated ketones by in situ produced benzeneselenol from O-(tert-butyl) Se-phenyl selenocarbonate

RSC Advances ◽  
2020 ◽  
Vol 10 (56) ◽  
pp. 33706-33717
Author(s):  
Andrea Temperini ◽  
Marco Ballarotto ◽  
Carlo Siciliano
Keyword(s):  
Double Bond ◽  
Hydrochloric Acid ◽  
Unsaturated Ketones ◽  
Metal Free ◽  
Tert Butyl ◽  
Carbon Double Bond

The carbon–carbon double bond of arylidene acetones and chalcones can be selectively reduced with benzeneselenol generated in situ by reacting O-(tert-butyl) Se-phenyl selenocarbonate with hydrochloric acid in ethanol.

A NEW MUSTARD OIL GLUCOSIDE SYNTHESIS: THE SYNTHESIS OF GLUCOTROPAEOLIN

1963 ◽  
Vol 41 (11) ◽  
pp. 2836-2838 ◽  
Author(s):  
M. H. Benn
Keyword(s):  
Double Bond ◽  
Mustard Oil ◽  
Nitrile Oxides ◽  
New Synthesis ◽  
Nitrogen Double Bond

A new synthesis of mustard oil glucosides is described, illustrated by the synthesis of glucotropaeolin. This synthesis, based on the reaction of thiols with nitrile oxides, leads to a conclusion concerning the stereochemistry about the carbon–nitrogen double bond in the mustard oil glucosides.

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