Oxidation of carbon monoxide to carbon dioxide by nickel-nitrogen dioxide complexes: a mechanistic study

1979 ◽  
Vol 101 (17) ◽  
pp. 5064-5065 ◽  
Author(s):  
Robert D. Feltham ◽  
Jeanne C. Kriege
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Nitrogen Dioxide ◽  
Mechanistic Study ◽  
Oxidation Of Carbon Monoxide

THE OXIDATION OF CARBON MONOXIDE CATALYZED BY NITROGEN DIOXIDE

Science ◽  
1934 ◽  
Vol 80 (2076) ◽  
pp. 338-338
Author(s):  
R. H. Crist ◽  
O. C. Roehling
Keyword(s):  
Carbon Monoxide ◽  
Nitrogen Dioxide ◽  
Oxidation Of Carbon Monoxide

The Rate of Oxidation of Carbon Monoxide in Presence of Nitrogen Dioxide

1936 ◽  
Vol 4 (10) ◽  
pp. 696-696 ◽  
Author(s):  
R. H. Crist ◽  
G. M. Calhoun
Keyword(s):  
Carbon Monoxide ◽  
Nitrogen Dioxide ◽  
Oxidation Of Carbon Monoxide

PRELIMINARY STUDY OF PHOTOCHEMICAL BEHAVIOR IN THE SYSTEM NITROGEN DIOXIDE – ETHANE

1955 ◽  
Vol 33 (5) ◽  
pp. 843-848
Author(s):  
T. M. Rohr ◽  
W. Albert Noyes Jr.
Keyword(s):  
Nitric Oxide ◽  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Nitrogen Dioxide ◽  
Room Temperature ◽  
Reverse Reaction ◽  
Primary Process ◽  
Photochemical Behavior ◽  
Preliminary Study ◽  
Oxygen Atoms

The addition of ethane to nitrogen dioxide either during exposure to radiation transmitted by pyrex, or afterwards, reduces the amount of oxygen formed. At room temperature this is apparently due to the effectiveness of ethane in promoting the reverse reaction of nitric oxide and oxygen to form nitrogen dioxide. At temperatures over 100° there is a reaction which uses oxygen atoms produced in the primary process. Nitroethane (or nitrosoethane) is formed along with carbon monoxide, carbon dioxide, and some methane. The results suggest that acetaldehyde is an intermediate, but acetaldehyde could not be detected because it would react thermally with nitrogen dioxide. It is not possible to give a complete explanation of the results, but suggestions can be made which might form the basis for later work.

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