Ion-molecular reactions in methyl halides. Behavior of methyl cations and halide transfer reactions

1974 ◽  
Vol 96 (6) ◽  
pp. 1665-1671 ◽  
Author(s):  
J. M. S. Henis ◽  
M. D. Loberg ◽  
M. J. Welch
Keyword(s):  
Transfer Reactions ◽  
Methyl Halides ◽  
Molecular Reactions

THE TRANSFER REACTIONS OF HALOGEN ATOMS

1960 ◽  
Vol 38 (10) ◽  
pp. 1643-1647 ◽  
Author(s):  
G. C. Fettis ◽  
J. H. Knox ◽  
A. F. Trotman-Dickenson
Keyword(s):  
Transition State ◽  
Transition State Theory ◽  
Hydrogen Bromide ◽  
Bromine Atom ◽  
Activation Energies ◽  
State Theory ◽  
Transfer Reactions ◽  
Methyl Halides ◽  
Alkyl Radicals ◽  
Bond Strengths

Extensive results on the reactions of fluorine, chlorine, and bromine atoms with alkanes and with some other molecules have been obtained from the study of competitive halogenations. The comparison of the A factors of the reactions provides an excellent test of the transition state theory. The activation energies of the bromine atom reactions can be combined with measurements of the activation energies for the reactions of alkyl radicals with hydrogen bromide to yield unusually reliable values of bond strengths. Information on the influence of polar effects on the activation energies of atomic reactions can be obtained from results on the reactions of fluorine and chlorine atoms with methyl halides.

THE FORMATION OF 6Li IN MULTINUCLEON TRANSFER REACTIONS

1971 ◽  
Vol 32 (C6) ◽  
pp. C6-209-C6-215
Author(s):  
W. J. KLAGES ◽  
H. H. DUHM ◽  
H. HOMEYER ◽  
P. E. SCHUMACHER ◽  
H. YOSHIDA
Keyword(s):  
Transfer Reactions ◽  
Multinucleon Transfer Reactions

Isotopic Characterization (2H, 13C, 37Cl, 81Br) of the Abiotic Sinks of Methyl Bromide and Methyl Chloride in Water and Implications for Future Studies.

2018 ◽  
Author(s):  
Axel Horst ◽  
Magali Bonifacie ◽  
Gérard Bardoux ◽  
Hans-Hermann Richnow
Keyword(s):  
Methyl Bromide ◽  
Isotope Fractionation ◽  
Methyl Chloride ◽  
Methyl Halides ◽  
Future Studies ◽  
Halide Exchange ◽  
Isotopic Characterization

In this study we investigated the isotope fractionation of the abiotic sink (hydrolysis, halide exchange) of methyl halides in water.<br>

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