Self-Assembly in Supramolecular Systems By Leonard F. Lindoy (University of Sydney) and Ian M. Atkinson (James Cook University). Monographs in Supramolecular Chemistry. Volume 7. Series edited by J. Fraser Stoddart. Royal Society of Chemistry:  Cambridge. 2000. x + 224 pp. £69.70. ISBN 0-85404-512-0.

2001 ◽  
Vol 123 (35) ◽  
pp. 8647-8647
Author(s):  
Hicham Fenniri
Nanophotonics ◽  
2013 ◽  
Vol 2 (4) ◽  
pp. 265-277 ◽  
Author(s):  
Katsuhiko Ariga ◽  
Hirokazu Komatsu ◽  
Jonathan P. Hill

AbstractSupramolecular chemistry has become a key area in emerging bottom-up nanoscience and nanotechnology. In particular, supramolecular systems that can produce a photonic output are increasingly important research targets and present various possibilities for practical applications. Accordingly, photonic properties of various supramolecular systems at the nanoscale are important in current nanotechnology. In this short review, nanophotonics in supramolecular chemistry will be briefly summarized by introducing recent examples of control of photonic responses of supramolecular systems. Topics are categorized according to the fundamental actions of their supramolecular systems: (i) self-assembly; (ii) recognition; (iii) manipulation.


2009 ◽  
Vol 17 (2) ◽  
pp. 263-280 ◽  
Author(s):  
Jean-Marie Lehn

Chemistry has developed from molecular chemistry, mastering the combination and recombination of atoms into increasingly complex molecules, to supramolecular chemistry, harnessing intermolecular forces for the generation of informed supramolecular systems and processes through the implementation of molecular information carried by electromagnetic interactions. Supramolecular chemistry is actively exploring systems undergoing self-organization, i.e. systems capable of spontaneously generating well-defined functional supramolecular architectures by self-assembly from their components, on the basis of the molecular information stored in the covalent framework of the components and read out at the supramolecular level through specific molecular recognition interactional algorithms, thus behaving as programmed chemical systems. Supramolecular entities as well as molecules containing reversible bonds are able to undergo a continuous change in constitution by reorganization and exchange of building blocks. This capability defines a Constitutional Dynamic Chemistry (CDC) on both the molecular and supramolecular levels. CDC introduces a paradigm shift with respect to constitutionally static chemistry. It takes advantage of dynamic constitutional diversity to allow variation and selection and thus adaptation. The merging of the features of supramolecular systems – information and programmability; dynamics and reversibility; constitution and structural diversity – points towards the emergence of adaptive chemistry. A further development will concern the inclusion of the arrow of time, i.e. of non-equilibrium, irreversible processes and the exploration of the frontiers of chemical evolution towards the establishment of evolutive chemistry, where the features acquired by adaptation are conserved and transmitted. In combination with the corresponding fields of physics and biology, chemistry thus plays a major role in the progressive elaboration of a science of informed, organized, evolutive matter, a science of complex matter.


Molecules ◽  
2021 ◽  
Vol 26 (3) ◽  
pp. 716
Author(s):  
Yi-Xiong Hu ◽  
Gui-Yuan Wu ◽  
Xu-Qing Wang ◽  
Guang-Qiang Yin ◽  
Chang-Wei Zhang ◽  
...  

The precise operation of molecular motion for constructing complicated mechanically interlocked molecules has received considerable attention and is still an energetic field of supramolecular chemistry. Herein, we reported the construction of two tris[2]pseudorotaxanes metallacycles with acid–base controllable molecular motion through self-sorting strategy and host–guest interaction. Firstly, two hexagonal Pt(II) metallacycles M1 and M2 decorated with different host–guest recognition sites have been constructed via coordination-driven self-assembly strategy. The binding of metallacycles M1 and M2 with dibenzo-24-crown-8 (DB24C8) to form tris[2]pseudorotaxanes complexes TPRM1 and TPRM2 have been investigated. Furthermore, by taking advantage of the strong binding affinity between the protonated metallacycle M2 and DB24C8, the addition of trifluoroacetic acid (TFA) as a stimulus successfully induces an acid-activated motion switching of DB24C8 between the discrete metallacycles M1 and M2. This research not only affords a highly efficient way to construct stimuli-responsive smart supramolecular systems but also offers prospects for precisely control multicomponent cooperative motion.


Each number of Notes and Records contains a short bibliography of books and articles dealing with the history of the Royal Society or its Fellows which have been noted since the publication of the last number. If Fellows would be good enough to draw the Editor’s attention to omissions these would be added to the list in the next issue. Books Badash, L. (Editor). Rutherford and Boltwood: letters on radioactivity. (Yale studies in the History of Sciences and Medicine, Vol. 4.) New Haven: Yale University Press, 1969. $12.50. Begg, A. C. and Begg, N.C. James Cook and New Zealand . Wellington, N.Z.: A. R. Shearer, 1969. £ 2 5s. Berkeley, E. and Berkeley, Dorothy, S. Dr Alexander Gordon of Charles Town . University of North Carolina Press, 1969. $10.00. Bestcrman, T. Voltaire. London: Longmans, 1969. 8s. Bowden, D. K. Leibniz as a librarian and eighteenth-century librarians Germany . London: University College, 1969. 7s. 6d. Darwin, C. R. Questions about the breeding of animals . Facsim. repr. with an introduction by Sir Gavin Dc Beer. London: Society for the Bibliography of Natural History, 1969. £1 15s. Davis, N. P. Lawrence and Openhimer . London: Cape, 1969. 2s. Dobson, J. John Hunter. Edinburgh & London: E. & S. Livingstone, 1969. £ 2 10s. Eales, N. B. The Cole library of early medicine and zoology . Catalogue of books and pamphlets. Part 1. 1472 to 1800. Oxford: Aldcn Press for the Library, University of Reading, 1969. £$ 5s. Edleston, J. (Editor). Correspondence of Sir Isaac Newton and Professor Cotes . (1830.) (Cass Library of Science Classics. No. 12.) London: Frank Cass, 1969. £ 6 6s. Fothergill, B. Sir William Hamilton . Faber and Faber, 1969. £ 2 10s. French, R. K. Robert Whytt, the soul, and medicine . (Publications of the Wellcome Institute, No. 17.) London: Wellcome Institute of the History of Medicine, 1969. £ 2 5s.


On 5 May 1768 Lieutenant James Cook was chosen by the Admiralty to take command of a Royal Society expedition funded by George III on the ship Endeavour , the purpose being to sail to a suitable point (Tahiti) in the Southern Pacific from which to observe the transit of Venus across the Sun on 3 June 1769. It was thought that, by observing the transit from different points on Earth, it would be possible to determine the distance of the Earth from both Venus and the Sun. The Royal Society asked that Joseph Banks (then a young Fellow aged 25) and a group of seven be allowed to join. Among them were two artists, Alexander Buchan and Sydney Parkinson, who were employed to draw views and specimens of natural historical interest, and Daniel Carl Solander a distinguished Swedish natural historian. Banks’s enthusiasm ensured that the voyage was exceptionally well equipped to handle natural historical discoveries. Having observed the transit of Venus, Cook was secretly under orders from the Admiralty then to sail to 40° south in search of the supposed Great Southern Continent; if not encountered, he was then to head due west to find the east coast of New Zealand. Following these instructions, Cook arrived at New Zealand on 6 October 1769. He then initiated the first detailed geographical survey of New Zealand, and Banks and Solander began putting together their rich collections of New Zealand flora; Cook also observed the transit of Mercury in Mercury Bay. On his second voyage in 1772 Cook went further south, entered the Antarctic circle twice (to 71° 10' S) and ruled out the existence of a Great Southern Continent, and first defined Antarctica as we know it. He returned to London in 1775 to be promoted to Captain and elected to the Royal Society. Banks went on to be elected President in 1778, a post which he held for nearly 42 years. Three other ties between Cook and the Royal Society include the naming of the Society Islands after his sponsors, the testing of a new chronometer for them, and a report to the Society on scurvy, which was to have great consequences for the future health of seamen. The Royal Society was thus instrumental in making possible Cook’s voyages, the outcome of which was a set of pioneering geographical, botanical, geological and anthropological descriptions of New Zealand. Here we trace some aspects of the subsequent interactions between New Zealand and the Royal Society by outlining the careers of relevant Fellows, namely (a) those foreign-born Fellows (30 identified) who spent parts of their careers in New Zealand, and (b) those New Zealand-born scientists (34) who have been elected Fellows for their work, whether carried out in New Zealand or elsewhere.


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