scholarly journals Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of M-BTT Metal–Organic Frameworks

2013 ◽  
Vol 135 (3) ◽  
pp. 1083-1091 ◽  
Author(s):  
Kenji Sumida ◽  
David Stück ◽  
Lorenzo Mino ◽  
Jeng-Da Chai ◽  
Eric D. Bloch ◽  
...  
2011 ◽  
Vol 142 (1) ◽  
pp. 208-213 ◽  
Author(s):  
Ping Song ◽  
Yaoqi Li ◽  
Bei He ◽  
Junzhi Yang ◽  
Jie Zheng ◽  
...  

2019 ◽  
Vol 43 (10) ◽  
pp. 4092-4099 ◽  
Author(s):  
Jiong Xu ◽  
Jin Liu ◽  
Zhen Li ◽  
Xianbiao Wang ◽  
Yongfei Xu ◽  
...  

The optimized MOF-808 exhibited relatively high chemical stability and excellent hydrogen storage properties at different temperatures.


2016 ◽  
Vol 852 ◽  
pp. 835-840 ◽  
Author(s):  
Tian Bao Yang ◽  
Li Xian Sun ◽  
Fen Xu ◽  
Zi Qiang Wang

Metal-organic frameworks (MOFs: copper containing CuBTC)-graphene oxide (GO) composite (CG) was synthesized using microwave heating. The parent material and the composite were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), nitrogen sorption, scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), Fourier transform infrared spectroscopy (HRTEM) and Raman spectroscopy. Then their hydrogen storage properties were systematically tested. The composite material CG shows a remarkable H2 capacity up to 2.43 wt% (28.6% increases vs. CuBTC) and higher surface area and pore volume compared to the neat CuBTC. And the particle size of CG is down to nanometer scale.


2017 ◽  
Vol 727 ◽  
pp. 683-687 ◽  
Author(s):  
Tian Bao Yang ◽  
Li Xian Sun ◽  
Fen Xu ◽  
Zi Qiang Wang ◽  
Yong Jin Zou ◽  
...  

Metal-organic frameworks (MOFs: MIL-125)-graphene oxide (GO) composite (MO) was synthesized by solvothermal method. All the materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), high resolution transmission electron microscopy (HRTEM), Fourier transform infrared spectroscopy (FT-IR) and Raman spectroscopy. Then their hydrogen storage properties were systematically tested under 1 bar and 77K. The composite material MO-1 possesses higher surface area than the parent material MIL-125 and shows a remarkable H2 capacity up to 2.5 wt% (38% increases vs. MIL-125).


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