Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H2Activation and the Role of Acid−Base Properties

2009 ◽  
Vol 131 (30) ◽  
pp. 10701-10710 ◽  
Author(s):  
Tibor András Rokob ◽  
Andrea Hamza ◽  
Imre Pápai
Keyword(s):  
Frustrated Lewis Pairs ◽  
Acid Base ◽  
Base Properties ◽  
Lewis Pairs

Development of silica-supported frustrated Lewis pairs: highly active transition metal-free catalysts for the Z-selective reduction of alkynes

2016 ◽  
Vol 6 (3) ◽  
pp. 882-889 ◽  
Author(s):  
Kai C. Szeto ◽  
Wissam Sahyoun ◽  
Nicolas Merle ◽  
Jessica Llop Castelbou ◽  
Nicolas Popoff ◽  
...  
Keyword(s):  
Transition Metal ◽  
Lewis Acid ◽  
Selective Reduction ◽  
Frustrated Lewis Pairs ◽  
Acid Base ◽  
Metal Free ◽  
Highly Active ◽  
Active Transition ◽  
Lewis Pairs

Supported Lewis acid/base systems based have been prepared and characterized.

The crucial role of the inter-ring hydrogen bond to explain the properties of morin

2018 ◽  
Vol 42 (10) ◽  
pp. 7691-7702 ◽  
Author(s):  
Aurélien Moncomble ◽  
Diksha Jani Thaviligadu ◽  
Anaëlle Raoumbé Djendja ◽  
Jean-Paul Cornard
Keyword(s):  
Hydrogen Bond ◽  
Crucial Role ◽  
Acid Base ◽  
Theoretical Approaches ◽  
Base Properties

The acid-base properties of morin and its complexation with the ZnII cation are investigated by experimental and theoretical approaches.

Role of Solvents on the Thermodynamics and Kinetics of Forming Frustrated Lewis Pairs

2012 ◽  
Vol 3 (22) ◽  
pp. 3312-3319 ◽  
Author(s):  
Liem X. Dang ◽  
Gregory K. Schenter ◽  
Tsun-Mei Chang ◽  
Shawn M. Kathmann ◽  
Tom Autrey
Keyword(s):  
Frustrated Lewis Pairs ◽  
Thermodynamics And Kinetics ◽  
Kinetics Of ◽  
Lewis Pairs

Direct synthesis of dimethyl carbonate from CO2 and methanol over CaO–CeO2 catalysts: the role of acid–base properties and surface oxygen vacancies

2017 ◽  
Vol 41 (20) ◽  
pp. 12231-12240 ◽  
Author(s):  
Bin Liu ◽  
Congming Li ◽  
Guoqiang Zhang ◽  
Lifei Yan ◽  
Zhong Li
Keyword(s):  
Oxygen Vacancies ◽  
Dimethyl Carbonate ◽  
Direct Synthesis ◽  
Surface Oxygen ◽  
Acid Base ◽  
Base Properties

The addition of CaO to the CeO2 catalyst had a significant impact on the acid–base properties and amounts of oxygen vacancies on the surface catalyst.

Understanding the role of frustrated Lewis pairs as ligands in transition metal-catalyzed reactions

2020 ◽  
Vol 49 (10) ◽  
pp. 3129-3137 ◽  
Author(s):  
Jorge Juan Cabrera-Trujillo ◽  
Israel Fernández
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
State Of The Art ◽  
Density Functional Theory Calculations ◽  
Frustrated Lewis Pairs ◽  
Functional Theory ◽  
Catalyzed Reactions ◽  
Metal Catalyzed ◽  
Lewis Pairs

The role of frustrated Lewis pairs (FLPs) as ligands in gold(i) catalyzed-reactions has been computationally investigated by using state-of-the-art density functional theory calculations.

scholarly journals Influence of acid–base properties of Mg-based catalysts on transesterification: role of magnesium silicate hydrate formation

2017 ◽  
Vol 7 (8) ◽  
pp. 1701-1712 ◽  
Author(s):  
Damien Cornu ◽  
Longfei Lin ◽  
Maya Mounir Daou ◽  
Maguy Jaber ◽  
Jean-Marc Krafft ◽  
...  
Keyword(s):  
Large Range ◽  
Hydrate Formation ◽  
Magnesium Silicate ◽  
Acid Base ◽  
Basic Properties ◽  
Base Properties

Catalysts with the strongest basic properties are not always the most efficient ones for transesterification, a series of magnesium-based materials, exhibiting a large range of acido–basic properties, was investigated.

The role of acid-base properties in the interactions across the oxide-primer interface in aerospace applications

2015 ◽  
Vol 48 (8) ◽  
pp. 712-720 ◽  
Author(s):  
S.T. Abrahami ◽  
T. Hauffman ◽  
J.M.M. de Kok ◽  
H. Terryn ◽  
J.M.C. Mol
Keyword(s):  
Acid Base ◽  
Aerospace Applications ◽  
Base Properties
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