A Reliable Quantum-Chemical Protocol for the Characterization of Organic Mixed-Valence Compounds

2009 ◽  
Vol 131 (44) ◽  
pp. 16292-16302 ◽  
Author(s):  
Manuel Renz ◽  
Kolja Theilacker ◽  
Christoph Lambert ◽  
Martin Kaupp
Keyword(s):  
Quantum Chemical ◽  
Mixed Valence ◽  
Mixed Valence Compounds

Darstellung und Charakterisierung von dreifach NR2-verbrückten Molybdänkomplexen des Typs η3-C7H7(CO)2Mo(μ–NR2)3Mo-η7-C7H7 / Synthesis and Characterization of Triply NR2-Bridged Molybdenum Complexes of the Type η3-C7H7(CO)2Mo(μ-NR2)3Mo-η7-C7H7

1982 ◽  
Vol 37 (1) ◽  
pp. 7-12 ◽  
Author(s):  
Winfried Dell ◽  
Manfred L. Ziegler
Keyword(s):  
Liquid Ammonia ◽  
Mixed Valence ◽  
Synthesis And Characterization ◽  
Molybdenum Complexes ◽  
Mixed Valence Compounds

Abstract The mixed-valence compounds of composition C7H7(CO)2Mo(μ-NR2)3MoC7H7 (R=H, p-NO2-C6H4, C4H4) can be synthesized by reacting η7-C7H7Mo(CO)2Br with the corresponding sodium amides. The amido compound with R=H can also be obtained from η7-C7H7MO(CO)2CH3 in liquid ammonia. Reaction of the products with CH3OH yields the known complex η3)-C7H7(CO)2Mo(μ-OCH3)3Mo-η3-C7H7.

PHONONS IN MIXED VALENCE COMPOUNDS

1981 ◽  
Vol 42 (C6) ◽  
pp. C6-3-C6-10 ◽  
Author(s):  
W. Kress ◽  
H. Bilz ◽  
G. Güntherodt ◽  
A. Jayaraman
Keyword(s):  
Mixed Valence ◽  
Mixed Valence Compounds

scholarly journals Mixed-valence Compounds: AuO2 and AuS

ChemPhysChem ◽  
2018 ◽  
Vol 19 (22) ◽  
pp. 2971-2971
Author(s):  
Meng Tang ◽  
Yanmei Zhang ◽  
Siya Li ◽  
Xi Wu ◽  
Yan Jia ◽  
...  
Keyword(s):  
Mixed Valence ◽  
Mixed Valence Compounds

Structural Characterization of Natural Products By Means of Quantum Chemical Calculations of NMR Parameters: New insights

2021 ◽  
Author(s):  
Fabio Luiz Paranhos Costa ◽  
Ana Carolina Ferreira de Albuquerque ◽  
Rodolfo Goetze Fiorot ◽  
Luciano Morais Lião ◽  
Lucas Haidar Martorano ◽  
...  
Keyword(s):  
Natural Products ◽  
Structural Characterization ◽  
Quantum Chemical ◽  
Chemical Shifts ◽  
Coupling Constants ◽  
Spin Coupling ◽  
Nmr Parameters ◽  
Spin Coupling Constants ◽  
Spin Spin Coupling

The calculation of NMR parameters for natural products was pioneered by Bifulco and coworkers in 2002. Since then, modelling 1H and 13C chemical shifts and spin-spin coupling constants for this...

ChemInform Abstract: Synthesis, Structure Determination, and Quantum-Chemical Characterization of an Alternate HgNCN Polymorph.

ChemInform ◽  
2010 ◽  
Vol 33 (43) ◽  
pp. no-no
Author(s):  
Xiaohui Liu ◽  
Paul Mueller ◽  
Peter Kroll ◽  
Richard Dronskowski
Keyword(s):  
Structure Determination ◽  
Quantum Chemical ◽  
Chemical Characterization

Orthogonal electronic coupling in multicentre arylamine mixed-valence compounds based on a dibenzofulvene–thiophene conjugated bridge

2017 ◽  
Vol 53 (64) ◽  
pp. 8960-8963 ◽  
Author(s):  
A. Beneduci ◽  
G. A. Corrente ◽  
E. Fabiano ◽  
V. Maltese ◽  
S. Cospito ◽  
...  
Keyword(s):  
Near Infrared ◽  
Mixed Valence ◽  
Infrared Region ◽  
Optical Modulation ◽  
Electronic Coupling ◽  
Voltage Dependent ◽  
Near Infrared Region ◽  
Mixed Valence Compounds

Novel H-shaped tetrarylamine mixed valence compounds showing orthogonal electronic coupling generate voltage-dependent electro-optical modulation in the near infrared region.

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