Synthesis and characterization of antimony mixed-valence compounds in view of solid state isotopic exchange studies

1998 ◽  
Vol 231 (1-2) ◽  
pp. 127b-132
Author(s):  
S. Fernandez-Valverde ◽  
E. Ordońez-Regil ◽  
P. Bosch ◽  
G. Duplâtre
Keyword(s):  
Solid State ◽  
Isotopic Exchange ◽  
Mixed Valence ◽  
Synthesis And Characterization ◽  
Mixed Valence Compounds

Darstellung und Charakterisierung von dreifach NR2-verbrückten Molybdänkomplexen des Typs η3-C7H7(CO)2Mo(μ–NR2)3Mo-η7-C7H7 / Synthesis and Characterization of Triply NR2-Bridged Molybdenum Complexes of the Type η3-C7H7(CO)2Mo(μ-NR2)3Mo-η7-C7H7

1982 ◽  
Vol 37 (1) ◽  
pp. 7-12 ◽  
Author(s):  
Winfried Dell ◽  
Manfred L. Ziegler
Keyword(s):  
Liquid Ammonia ◽  
Mixed Valence ◽  
Synthesis And Characterization ◽  
Molybdenum Complexes ◽  
Mixed Valence Compounds

Abstract The mixed-valence compounds of composition C7H7(CO)2Mo(μ-NR2)3MoC7H7 (R=H, p-NO2-C6H4, C4H4) can be synthesized by reacting η7-C7H7Mo(CO)2Br with the corresponding sodium amides. The amido compound with R=H can also be obtained from η7-C7H7MO(CO)2CH3 in liquid ammonia. Reaction of the products with CH3OH yields the known complex η3)-C7H7(CO)2Mo(μ-OCH3)3Mo-η3-C7H7.

Synthesis and Characterization of Temperature Controlled SnO2 Nanoparticles by Solid-state Reaction Method

2020 ◽  
Vol 12 (4) ◽  
pp. 04004-1-04004-6
Author(s):  
Vijay Garg ◽  
◽  
Harsh Sharma ◽  
Divya Rehani ◽  
Renu Kumari ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Sno2 Nanoparticles ◽  
Solid State Reaction Method ◽  
Synthesis And Characterization ◽  
Reaction Method ◽  
Temperature Controlled

Solid-state synthesis and characterization of two-dimensional hexagonal BCN nanosheet using a free template method

2021 ◽  
Vol 115 ◽  
pp. 108350
Author(s):  
Majid Mirzaee ◽  
Alimorad Rashidi ◽  
Ashkan Zolriasatein ◽  
Majid Rezaei Abadchi
Keyword(s):  
Solid State ◽  
Solid State Synthesis ◽  
Synthesis And Characterization ◽  
Template Method ◽  
Two Dimensional

Synthesis and characterization of LAGP-glass-ceramics-based composite solid polymer electrolyte for solid-state Li-ion battery application

2021 ◽  
Vol 558 ◽  
pp. 120654
Author(s):  
Anurup Das ◽  
Madhumita Goswami ◽  
Kavya Illath ◽  
T.G. Ajithkumar ◽  
A. Arya ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Polymer Electrolyte ◽  
Glass Ceramics ◽  
Solid Polymer ◽  
Synthesis And Characterization ◽  
Li Ion Battery ◽  
Li Ion ◽  
Composite Solid ◽  
Battery Application

Synthesis and Characterization of the Hole-Conducting Silica/Polymer Nanocomposites and Application in Solid-State Dye-Sensitized Solar Cell

2013 ◽  
Vol 5 (10) ◽  
pp. 4155-4161 ◽  
Author(s):  
Wen Yuan ◽  
Hui Zhao ◽  
Heyi Hu ◽  
Shen Wang ◽  
Gregory L. Baker
Keyword(s):  
Solar Cell ◽  
Solid State ◽  
Polymer Nanocomposites ◽  
Dye Sensitized Solar Cell ◽  
Synthesis And Characterization ◽  
Dye Sensitized

Mechanochemical solid state synthesis and characterization of CdxZn1−xS nanocrystals

2008 ◽  
Vol 179 (21-26) ◽  
pp. 1242-1245 ◽  
Author(s):  
Erika Dutková ◽  
Peter Baláž ◽  
Parviz Pourghahramani ◽  
Anh V. Nguyen ◽  
Vladimír Šepelák ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Synthesis ◽  
Synthesis And Characterization

Synthesis and characterization of a new open-framework mixed-valence aluminum–iron phosphate (C4H12N2)2[Fe2Al5(PO4)8(H2O)]

2014 ◽  
Vol 47 ◽  
pp. 99-101 ◽  
Author(s):  
Yanan Guo ◽  
Yuchen Qiu ◽  
Jiyang Li ◽  
Lang Shao ◽  
Xiaowei Song
Keyword(s):  
Mixed Valence ◽  
Iron Phosphate ◽  
Synthesis And Characterization ◽  
Open Framework ◽  
Aluminum Iron

Synthesis and characterization of the binuclear diamido titanium chalcogenides [(Ar)NCH2CH2CH2N(Ar)]2Ti(µ-E)2 (E = Se, Te)

2002 ◽  
Vol 80 (11) ◽  
pp. 1524-1529 ◽  
Author(s):  
Tianle Zhang ◽  
Warren E Piers ◽  
Masood Parvez
Keyword(s):  
Solid State ◽  
Key Words ◽  
Synthesis And Characterization ◽  
Catalyst Precursor ◽  
Tellurium Atom ◽  
Titanium Complex ◽  
X Ray ◽  
X Ray Crystallography ◽  
Atom Source

Reaction of McConville's chelating amido titanium complex [(Ar)NCH2CH2CH2N(Ar)]Ti(CH3)2 (Ar = 2,6-i-Pr2C6H3) with either elemental Se or the tellurium atom source Te=PBu3 resulted in the formation of bis-µ-chalcogenido dimers [(Ar)NCH2CH2CH2N(Ar)]2Ti(µ-E)2 (E = Se, 2; Te, 3) with concommitant loss of EMe2. The dimers 2 and 3 were characterized spectroscopically and via X-ray crystallography. The two compounds are isostructural in the solid state. The tellurido dimer 3 may also be synthesized by reduction of the diamido dichloride [(Ar)NCH2CH2CH2N(Ar)]2TiCl2 with Na–Hg amalgam followed by treatment with Te=PBu3. This dimer is unreactive toward further Te=PBu3 or stannanes such as HSnBu3. Unlike decamethyltitanocene derivatives, the diamido complex is not an effective catalyst precursor for the heterohydrodecoupling of Te=PBu3 and HSnBu3.Key words: diamido titanium complexes, selenides, tellurides.

scholarly journals Synthesis and Thermal Properties of Cerium-Dysprosium Oxide

2016 ◽  
Vol 61 (2) ◽  
pp. 965-969 ◽  
Author(s):  
M. Mikuśkiewicz ◽  
M. Stopyra ◽  
G. Moskal
Keyword(s):  
Thermal Properties ◽  
Phase Composition ◽  
Thermal Diffusivity ◽  
Solid State ◽  
Cerium Oxide ◽  
Solid State Reaction ◽  
Synthesis And Characterization ◽  
Equimolar Ratio ◽  
Dysprosium Oxide

Abstract The paper presents results of investigation on synthesis and characterization of cerium-dysprosium oxide. The input powders - dysprosium oxide Dy2O3 and cerium oxide CeO2 - were mixed so as to obtain equimolar ratio of cations, milled in alcohol and synthesized via solid state reaction process at 1350°C under 15MPa in vacuum for 2h. The microstructure, phase composition and thermal properties were analyzed. The obtained material was multiphase. Non-stoichiometric compounds were identified. Thermal diffusivity of investigated material decreased in the temperature range of 25-1000°C from 0,71 to 0,45 mm2/s.

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