Diels−Alder Reaction for the Selective Immobilization of Protein to Electroactive Self-Assembled Monolayers

1999 ◽  
Vol 121 (17) ◽  
pp. 4286-4287 ◽  
Author(s):  
Muhammad N. Yousaf ◽  
Milan Mrksich
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Self Assembled Monolayers ◽  
Diels Alder Reaction ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Selective Immobilization

scholarly journals Using TOF-SIMS Spectrometry to Study the Kinetics of the Interfacial Retro Diels–Alder Reaction

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2674
Author(s):  
Lilia Hassouna ◽  
Sachin Kumar Enganati ◽  
Florence Bally-Le Gall ◽  
Grégory Mertz ◽  
Jérôme Bour ◽  
...  
Keyword(s):  
Secondary Ion Mass Spectrometry ◽  
Alder Reaction ◽  
Diels Alder ◽  
Self Assembled Monolayers ◽  
Use Of Time ◽  
Diels Alder Reaction ◽  
Tof Sims ◽  
Reaction Conversion ◽  
Assembled Monolayers ◽  
Different Temperatures

In this work, the use of Time of Flight Secondary Ion Mass Spectrometry (TOF-SIMS) was explored as a technique for monitoring the interfacial retro Diels–Alder (retro DA) reaction occurring on well-controlled self-assembled monolayers (SAMs). A molecule containing a Diels–Alder (DA) adduct was grafted on to the monolayers, then the surface was heated at different temperatures to follow the reaction conversion. A TOF-SIMS analysis of the surface allowed the detection of a fragment from the molecule, which is released from the surface when retro DA reaction occurs. Hence, by monitoring the decay of this fragment’s peak integral, the reaction conversion could be determined in function of the time and for different temperatures. The viability of this method was then discussed in comparison with the results obtained by 1H NMR spectroscopy.

scholarly journals A K+-promoted Diels–Alder reaction by using a self-assembled macrocyclic boronic ester containing two crown ether moieties

2019 ◽  
Vol 10 (32) ◽  
pp. 7627-7632 ◽  
Author(s):  
Kosuke Ono ◽  
Morikazu Niibe ◽  
Nobuharu Iwasawa
Keyword(s):  
Crown Ether ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Boronic Ester ◽  
Self Assembled

A K+-promoted Diels–Alder reaction of 1,4,9,10-anthradiquinone with various dienes is achieved in the presence of a self-assembled macrocyclic boronic ester.

Mechanistic Insight on the Diels–Alder Reaction Catalyzed by a Self-Assembled Molecular Capsule

2013 ◽  
Vol 78 (8) ◽  
pp. 3577-3582 ◽  
Author(s):  
Lina Xu ◽  
Weijie Hua ◽  
Shugui Hua ◽  
Jun Li ◽  
Shuhua Li
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Mechanistic Insight ◽  
Molecular Capsule ◽  
Self Assembled

Self-Assembled Molecular Capsule Catalyzes a Diels−Alder Reaction

1998 ◽  
Vol 120 (29) ◽  
pp. 7389-7390 ◽  
Author(s):  
Jongmin Kang ◽  
Javier Santamaría ◽  
Göran Hilmersson ◽  
Julius Rebek
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Molecular Capsule ◽  
Self Assembled

ChemInform Abstract: Hexameric Capsule of a Resorcinarene Bearing Fluorous Feet as a Self-Assembled Nanoreactor: A Diels-Alder Reaction in a Fluorous Biphasic System.

ChemInform ◽  
2013 ◽  
Vol 44 (52) ◽  
pp. no-no
Author(s):  
Shoichi Shimizu ◽  
Asuka Usui ◽  
Masae Sugai ◽  
Yuki Suematsu ◽  
Seiji Shirakawa ◽  
...  
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Biphasic System ◽  
Diels Alder Reaction ◽  
Self Assembled

In-Plane Enyne Metathesis and Subsequent Diels−Alder Reactions on Self-Assembled Monolayers

Langmuir ◽  
2005 ◽  
Vol 21 (23) ◽  
pp. 10311-10315 ◽  
Author(s):  
Jungkyu K. Lee ◽  
Young Shik Chi ◽  
Joon Sung Lee ◽  
Yang-Gyun Kim ◽  
Young Hwan Jung ◽  
...  
Keyword(s):  
Diels Alder ◽  
Self Assembled Monolayers ◽  
Enyne Metathesis ◽  
Assembled Monolayers ◽  
Self Assembled
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