Proton-Induced Disproportionation of Jahn–Teller-Active Transition-Metal Ions in Oxides Due to Electronically Driven Lattice Instability

2020 ◽  
Vol 142 (50) ◽  
pp. 21122-21130
Author(s):  
Hooman Yaghoobnejad Asl ◽  
Arumugam Manthiram
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Transition Metal Ions ◽  
Lattice Instability ◽  
Jahn Teller ◽  
Active Transition

Structural snapshots of the rearrangement of the bis(di-tert-butyl-aminophenyl)amine pincer ligand in the presence of transition metal ions

2018 ◽  
Vol 47 (33) ◽  
pp. 11303-11307 ◽  
Author(s):  
N. Leconte ◽  
B. Baptiste ◽  
C. Philouze ◽  
F. Thomas
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Transition Metal Ions ◽  
Pincer Ligand ◽  
Tert Butyl ◽  
Redox Active ◽  
Active Transition

The ligand undergoes N–N and C–N bond formations in the presence of redox-active transition metal ions, in air and coordinating solvents.

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