Highly Active and Stable Metal Single-Atom Catalysts Achieved by Strong Electronic Metal–Support Interactions

2019 ◽  
Vol 141 (37) ◽  
pp. 14515-14519 ◽  
Author(s):  
Junjie Li ◽  
Qiaoqiao Guan ◽  
Hong Wu ◽  
Wei Liu ◽  
Yue Lin ◽  
...  
Keyword(s):  
Single Atom ◽  
Highly Active ◽  
Metal Support ◽  
Metal Support Interactions

Fabrication, characterization, and stability of supported single-atom catalysts

2017 ◽  
Vol 7 (19) ◽  
pp. 4250-4258 ◽  
Author(s):  
Yaxin Chen ◽  
Zhiwei Huang ◽  
Zhen Ma ◽  
Jianmin Chen ◽  
Xingfu Tang
Keyword(s):  
Catalytic Activity ◽  
Single Atom ◽  
Metal Support ◽  
Metal Support Interactions

Strong metal–support interactions are key requirements for development of stable single-atom catalysts with pronounced catalytic activity.

scholarly journals Single atom is not alone: Metal–support interactions in single-atom catalysis

2020 ◽  
Vol 40 ◽  
pp. 173-192 ◽  
Author(s):  
Kun Qi ◽  
Manish Chhowalla ◽  
Damien Voiry
Keyword(s):  
Single Atom ◽  
Metal Support ◽  
Metal Support Interactions

Metal-Support Interactions and C1 Chemistry: Transforming Pt-CeO2 into a Highly Active and Stable Catalyst for the Conversion of Carbon Dioxide and Methane

2020 ◽  
Author(s):  
Feng Zhang ◽  
Ramón A. Gutiérrez ◽  
Pablo Lustemberg ◽  
Zongyuan Liu ◽  
Ning Rui ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Oxide ◽  
Elevated Temperatures ◽  
Chemical Properties ◽  
Oxide Interface ◽  
Highly Active ◽  
Metal Support ◽  
Metal Support Interactions ◽  
Methane Dissociation

There is an ongoing search for materials which can accomplish the activation of two dangerous greenhouse gases like carbon dioxide and methane. In the area of C1 chemistry, the reaction between CO2 and CH4 to produce syngas, known as methane dry reforming (MDR), is attracting a lot of interest due to its green nature. On Pt(111), elevated temperatures are necessary to activate the reactants and massive deposition of carbon makes this metal surface ineffective for the MDR process. In this study, we show that strong metal-support interactions present in Pt/CeO2(111) and Pt/CeO2 powders lead to systems which can bind well CO2 and CH4 at room temperature and are excellent and stable catalysts for the MDR process at moderate temperature (500 ºC). The behaviour of these systems was studied using a combination of in-situ/operando methods which pointed to an active Pt-CeO2-x interface. In this interface, the oxide is far from being a passive spectator. It modifies the chemical properties of Pt, facilitating improved methane dissociation, and is directly involved in the adsorption and dissociation of CO2 making the MDR catalytic cycle possible. A comparison of the benefits gained by the use of an effective metal-oxide interface and those obtained by plain bimetallic bonding indicates that the former is much more important when optimizing the C1 chemistry associated with CO2 and CH4 conversion. The presence of elements with a different chemical nature at the metal-oxide interface opens the possibility for truly cooperative interactions in the activation of C-O and C-H bonds.

scholarly journals Dry Reforming of Methane on a Highly-Active Ni-CeO2 Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking

2016 ◽  
Vol 128 (26) ◽  
pp. 7581-7585 ◽  
Author(s):  
Zongyuan Liu ◽  
David C. Grinter ◽  
Pablo G. Lustemberg ◽  
Thuy-Duong Nguyen-Phan ◽  
Yinghui Zhou ◽  
...  
Keyword(s):  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Bond Breaking ◽  
Highly Active ◽  
Metal Support ◽  
Metal Support Interactions

A highly active Pd/H-ZSM-5 catalyst in lean methane combustion prepared via a sol–gel method and treated by reduction–oxidation

2020 ◽  
Vol 44 (10) ◽  
pp. 3940-3949 ◽  
Author(s):  
Chao Fan ◽  
Li Yang ◽  
Li Luo ◽  
Zhiwei Wu ◽  
Zhangfeng Qin ◽  
...  
Keyword(s):  
Sol Gel ◽  
Methane Combustion ◽  
Pd Nanoparticles ◽  
Catalytic Performance ◽  
Oxidation Treatment ◽  
Gel Method ◽  
Sol Gel Method ◽  
Highly Active ◽  
Metal Support ◽  
Metal Support Interactions

The reduction–oxidation treatment can reconstruct Pd nanoparticles, strengthen metal–support interactions and enhance catalytic performance of Pd/H-ZSM-5 in methane combustion.

scholarly journals Metal-Support Interactions and C1 Chemistry: Transforming Pt-CeO2 into a Highly Active and Stable Catalyst for the Conversion of Carbon Dioxide and Methane

2020 ◽  
Author(s):  
Feng Zhang ◽  
Ramón A. Gutiérrez ◽  
Pablo Lustemberg ◽  
Zongyuan Liu ◽  
Ning Rui ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Oxide ◽  
Elevated Temperatures ◽  
Chemical Properties ◽  
Oxide Interface ◽  
Highly Active ◽  
Metal Support ◽  
Metal Support Interactions ◽  
Methane Dissociation

There is an ongoing search for materials which can accomplish the activation of two dangerous greenhouse gases like carbon dioxide and methane. In the area of C1 chemistry, the reaction between CO2 and CH4 to produce syngas, known as methane dry reforming (MDR), is attracting a lot of interest due to its green nature. On Pt(111), elevated temperatures are necessary to activate the reactants and massive deposition of carbon makes this metal surface ineffective for the MDR process. In this study, we show that strong metal-support interactions present in Pt/CeO2(111) and Pt/CeO2 powders lead to systems which can bind well CO2 and CH4 at room temperature and are excellent and stable catalysts for the MDR process at moderate temperature (500 ºC). The behaviour of these systems was studied using a combination of in-situ/operando methods which pointed to an active Pt-CeO2-x interface. In this interface, the oxide is far from being a passive spectator. It modifies the chemical properties of Pt, facilitating improved methane dissociation, and is directly involved in the adsorption and dissociation of CO2 making the MDR catalytic cycle possible. A comparison of the benefits gained by the use of an effective metal-oxide interface and those obtained by plain bimetallic bonding indicates that the former is much more important when optimizing the C1 chemistry associated with CO2 and CH4 conversion. The presence of elements with a different chemical nature at the metal-oxide interface opens the possibility for truly cooperative interactions in the activation of C-O and C-H bonds.

Single-Atom Catalysts: Advances and Challenges in Metal-Support Interactions for Enhanced Electrocatalysis

2021 ◽  
Author(s):  
Yang Mu ◽  
Tingting Wang ◽  
Jian Zhang ◽  
Changgong Meng ◽  
Yifu Zhang ◽  
...  
Keyword(s):  
Single Atom ◽  
Metal Support ◽  
Metal Support Interactions

scholarly journals Dry Reforming of Methane on a Highly-Active Ni-CeO2 Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking

2016 ◽  
Vol 55 (26) ◽  
pp. 7455-7459 ◽  
Author(s):  
Zongyuan Liu ◽  
David C. Grinter ◽  
Pablo G. Lustemberg ◽  
Thuy-Duong Nguyen-Phan ◽  
Yinghui Zhou ◽  
...  
Keyword(s):  
Dry Reforming ◽  
Dry Reforming Of Methane ◽  
Bond Breaking ◽  
Highly Active ◽  
Metal Support ◽  
Metal Support Interactions

Highly active and stable copper catalysts derived from copper silicate double-shell nanofibers with strong metal–support interactions for the RWGS reaction

2019 ◽  
Vol 55 (29) ◽  
pp. 4178-4181 ◽  
Author(s):  
Yang Yu ◽  
Renxi Jin ◽  
Justin Easa ◽  
Wei Lu ◽  
Man Yang ◽  
...  
Keyword(s):  
Copper Catalysts ◽  
Water Gas Shift ◽  
Highly Active ◽  
Reverse Water Gas Shift ◽  
Metal Support ◽  
Rwgs Reaction ◽  
Metal Support Interactions ◽  
Shift Reaction ◽  
Water Gas ◽  
Supported Copper Catalysts

Double-shell hollow nanofiber supported copper catalysts with strong metal–support interactions were prepared and applied in the reverse water–gas shift reaction.

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