Speed of sound in and isothermal compressibility and isobaric expansivity of pure liquids at 298.15 K

1986 ◽  
Vol 31 (4) ◽  
pp. 492-493 ◽  
Author(s):  
G. Tardajos ◽  
M. Diaz Pena ◽  
A. Lainez ◽  
E. Aicart

2020 ◽  
Vol 56 (7) ◽  
Author(s):  
Dushmanta Sahu ◽  
Sushanta Tripathy ◽  
Raghunath Sahoo ◽  
Archita Rani Dash




1973 ◽  
Vol 19 (2) ◽  
pp. 555-563 ◽  
Author(s):  
G. Fritsch ◽  
M. Nehmann ◽  
P. Korpiun ◽  
E. Lüscher


2018 ◽  
Vol 83 (1) ◽  
pp. 61-73 ◽  
Author(s):  
Javid Safarov ◽  
Aygul Namazova ◽  
Astan Shahverdiyev ◽  
Egon Hassel

(p,?,T) data of 1-octyl-3-methylimidazolium tetrafluoroborate [OMIM][BF4] over a wide range of temperatures, from 278.15 to 413.15 K, and pressures, p, up to 140 MPa are reported with an estimated ?0.01?0.08 % experimental relative average percent deviation (APD) in the density. The measurements were performed using an Anton Paar DMA HPM vibration tube densimeter. (p,?,T) Data for [OMIM][BF4] was fitted and the parameters of the applied equation were determined as a function of pressure and temperature. After a thorough analysis of literature values and validity of the used equation of state, various thermophysical properties, such as isothermal compressibility, isobaric thermal expansibility, differences in isobaric and isochoric heat capacities, thermal pressure coefficient, internal pressure, heat capacities at constant pressure and volume, speed of sound and isentropic exponent at temperatures in the range 278.15?413.15 K and pressures p up to 140 MPa were calculated.



Author(s):  
Matt Taher

Abstract In many practical applications of thermodynamics, the use of simplified relationships of the ideal-gas model over a more accurate but more complex real gas model, is a critical decision to make. Thermodynamic departure functions provide screening criteria to evaluate whether the ideal-gas model can accurately represent a gas behavior. This paper reports several departure functions to evaluate deviation of a real gas from the ideal-gas model. Included in this paper is the derivation of departure functions based on isothermal compressibility, isobaric expansivity, isochoric change of pressure with temperature, isochoric change of internal energy with pressure, sonic speed, and heat capacities difference. The description of each of these departure functions is accompanied by a numerical example. Departure functions defined in this paper have led to improved representation of deviation from the ideal-gas model across a range of ±2% deviation of the specific volume departure (also known as the compressibility factor, Z) for a typical gas mixture encountered in natural gas processing. The limitations involved in using the compressibility factor, Z, to evaluate departure from the ideal-gas model is highlighted. It is shown that even as the compressibility factor, Z, approaches unity at certain thermodynamic conditions, other departure functions exhibit considerable deviations from the ideal-gas model. It is concluded that the compressibility factor, Z, should not be used as “the only criterion” to evaluate conformance to the ideal-gas model. This paper also explains the physical significance of Schultz compressibility functions X, Y, and L [3] by introducing departure functions based on isothermal compressibility and isobaric expansivity.



1976 ◽  
Vol 54 (12) ◽  
pp. 1282-1291 ◽  
Author(s):  
John Stephenson

Some elementary properties of loci of extrema of thermodynamic functions are established and discussed in connection with maxima and minima of the constant volume specific heat, CV, the isothermal compressibility, χT, and the constant pressure specific heat, CP, along isotherms, and the extremum properties of the isobaric coefficient of expansion, αP, along isobars. Experimental results for fluid argon are used to construct the required loci of extrema. Van der Waals' equation is applied to obtain loci of extrema for χT, CP, and αP, for the speed of sound W, and for related inflexion loci.



1975 ◽  
Vol 53 (14) ◽  
pp. 1367-1384 ◽  
Author(s):  
John Stephenson

The properties of fluid argon are investigated via the maxima and minima along isotherms of selected thermodynamic functions, the isothermal compressibility, χT, the constant volume specific heat, CV, and the speed of sound, W. Calculations are based on an equation of state due to Gosman, McCarty, and Hust and on speed of sound data compiled by Thoen, Vangeel, and Van Dael. The calculation of CV in the dense liquid region, from the equation of state and from the speed of sound, is discussed in detail. Also, the linear dependence of W on the density in the liquid region is reconciled with the behaviour of W at temperatures above critical to obtain a unified description of the variation of W along isotherms.





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