Liquid−Liquid Phase Equilibria of (Ethanol or Methanol + Water) Containing either Dipotassium Hydrogen Phosphate or Sodium Dihydrogen Phosphate

2006 ◽  
Vol 51 (3) ◽  
pp. 914-918 ◽  
Author(s):  
Hirotake Katayama ◽  
Masahito Miyahara
2014 ◽  
Vol 809-810 ◽  
pp. 477-484
Author(s):  
Zhao Qing Qi ◽  
Hong Tao Wang ◽  
Jun Liang Dang ◽  
Shi Hao Zhang ◽  
Jian Hua Ding

The capacity of 10%, 30%, and 50% ammonium dihydrogen phosphate were replaced with an equal amount of three phosphate (potassium dihydrogen phosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate) respectively. Magnesium phosphate cement was made by phosphate of replaced, which strength, setting time, fluidity, hydration temperature, and the hydration products was researched. The results show that: MPC was made that replaced with the equal amount of three kind of phosphate, which has good mechanical properties. Setting time and fluidity change along with the replacment. Three kind of phosphate replace ammonium dihydrogen phosphate, which change the hydration process of MPC. When ammonium dihydrogen phosphate was replaced by an equal amount of disodium hydrogen phosphate, the temperature of hydration is only 69.4 °C. XRD showed that the diffraction peaks of composite’s magnesium phosphate cement increases.


1961 ◽  
Vol 7 (2) ◽  
pp. 156-164 ◽  
Author(s):  
Edward B Hendry

Abstract With the use of the Fiske Osmometer, the mean total osmolarity of normal human serum was found to be 289 mOsM (S.D., 4), which is equivalent to a mean freezing point of -0.537°. The isosmotic concentrations of some important biologic solutions were determined. It was also found that M/15 solutions of disodium hydrogen phosphate and of potassium dihydrogen phosphate are very hypotonic, and that 3.8% sodium citrate is hypertonic. Hemolysis of erythrocytes in isosmotic ammonium chloride solution can be considerably delayed by the addition of 3.0% glucose to the solution. Isosmotic concentrations of disodium hydrogen phosphate and sodium dihydrogen phosphate were precisely determined, as were pH levels of buffer solutions made from these two salts. The cause of the slight changes in osmolarity that occur when these two isosmotic solutions are mixed is discussed.


2021 ◽  
pp. 19-25

The aim of the research is the synthesis of sodium ammonium hydrogen phosphate and sodium dihydrogen phosphate based on purified extraction phosphoric acid. The acid was purified from accompanying impurities by precipitation methods using sodium carbonate and metasilicate, washed burnt phosphoconcentrate, barium carbonate, acid neutralization with gaseous ammonia. Pre-neutralization of the purified solution of monoammonium phosphate with sodium carbonate to the ratio Na2O:P2O5 = 0.44 and subsequent drying at a temperature of 50 °С allows to obtain sodium ammonium hydrogen phosphate tetrahydrate, and at 100 °С sodium dihydrogen phosphate monohydrate. The individuality and purity of the synthesized substances was established by the methods of X-ray diffraction, IR spectroscopy, thermogravimetry and scanning electron microscope.


2021 ◽  
pp. 14-18

The aim of the research is the synthesis of sodium ammonium hydrogen phosphate and sodium dihydrogen phosphate based on purified extraction phosphoric acid. The acid was purified from accompanying impurities by precipitation methods using sodium carbonate and metasilicate, washed burnt phosphoconcentrate, barium carbonate, acid neutralization with gaseous ammonia. Pre-neutralization of the purified solution of monoammonium phosphate with sodium carbonate to the ratio Na2O:P2O5 = 0.44 and subsequent drying at a temperature of 50 °С allows to obtain sodium ammonium hydrogen phosphate tetrahydrate, and at 100 °С sodium dihydrogen phosphate monohydrate. The individuality and purity of the synthesized substances was established by the methods of X-ray diffraction, IR spectroscopy, thermogravimetry and scanning electron microscope.


2011 ◽  
Vol 236-238 ◽  
pp. 2340-2343
Author(s):  
Guang Lei Li ◽  
Fei Lu ◽  
Su Juan Du ◽  
Jie Zeng

The preparation of sweet potato starch phosphates which possess height stable paste was optimized in this study. A central composite design of response surface methodology involving phosphate (sodium dihydrogen phosphate and disodium hydrogen phosphate) concentration, the ratio of sodium dihydrogen phosphate and disodium hydrogen phosphate, phosphorylation temperature and urea concentration was used, and second-order model for paste stability was employed to generate the response surface. The optimum condition for preparation of sweet potato starch phosphates was as follows: phosphate concentration 4.89%, the ratio of sodium dihydrogen phosphate and disodium hydrogen 0.50, phosphorylation temperature 143°C, urea concentration 2.0%. The predicted value for paste stability of sweet potato starch phosphates at the optimum condition was 0.5721. Experimental verification gave values of 0.5708±0.0003.


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