Measurements, Correlations, and Mod. UNIFAC (Do) Prediction of (Solid−Liquid) Phase Equilibria Diagrams in Binary Systems (Aliphatic Ketone + an Alcohol)

2011 ◽  
Vol 56 (4) ◽  
pp. 881-888 ◽  
Author(s):  
Urszula Domańska ◽  
Kamil Paduszyński ◽  
Joanna Da̧bska
Keyword(s):  
Liquid Phase ◽  
Phase Equilibria ◽  
Binary Systems ◽  
Aliphatic Ketone ◽  
Solid Liquid

Solid–Liquid Phase Equilibria for the Ternary Systems V2O5–Na2O–Fe2O3, V2O5–Na2O–Cr2O3, and V2O5–Na2O–MgO

1973 ◽  
Vol 51 (7) ◽  
pp. 1032-1040 ◽  
Author(s):  
R. C. Kerby ◽  
J. R. Wilson
Keyword(s):  
Liquid Phase ◽  
Phase Equilibria ◽  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Binary Systems ◽  
Ternary Systems ◽  
X Ray ◽  
Equilibrium Relationships ◽  
Solid Liquid ◽  
Liquidus Temperatures

The phase equilibrium relationships of several vanadate systems have been studied by a combination of differential thermal analysis (DTA) and X-ray powder diffraction methods. All systems studied were eutectic in nature. The liquidus temperatures of the sodium vanadates were found to depend on the oxygen partial pressure for sodium oxide concentrations between 1.0 and 36 mol%. This effect was not observed for the ferric vanadate, chromic vanadate or magnesium vanadate systems. The solid–liquid phase equilibria for the ternary vanadate systems V2O5–Na2O–Fe2O3, V2O5–Na2O–Cr2O3, and V2O5–Na2O–MgO were measured by determining the temperature–composition data for various quasi-binary systems within each ternary system. Liquidus temperatures between 500 and 700 °C were found for those compositional ranges containing greater than 40 mol% V2O5 and between 10 and 60 mol% Na2O. The liquidus temperatures decreased with increasing oxygen partial pressure over much of the same compositional range.

(Solid+liquid) and (liquid+liquid) phase equilibria study and correlation of the binary systems {N-butyl-3-methylpyridinium tosylate+water, or+an alcohol, or+a hydrocarbon}

2010 ◽  
Vol 294 (1-2) ◽  
pp. 89-97 ◽  
Author(s):  
Trevor M. Letcher ◽  
Deresh Ramjugernath ◽  
Kaniki Tumba ◽  
Marek Królikowski ◽  
Urszula Domańska
Keyword(s):  
Liquid Phase ◽  
Phase Equilibria ◽  
Binary Systems ◽  
Solid Liquid

scholarly journals Solubility of Anthraquinone Derivatives in Supercritical Carbon Dioxide: New Correlations

Molecules ◽  
2021 ◽  
Vol 26 (2) ◽  
pp. 460
Author(s):  
Ratna Surya Alwi ◽  
Chandrasekhar Garlapati ◽  
Kazuhiro Tamura
Keyword(s):  
Carbon Dioxide ◽  
Liquid Phase ◽  
Supercritical Carbon Dioxide ◽  
Binary Systems ◽  
Relative Deviation ◽  
Anthraquinone Derivatives ◽  
New Models ◽  
Solubility Isotherms ◽  
Solid Liquid ◽  
Supercritical Carbon

Solubility of several anthraquinone derivatives in supercritical carbon dioxide was readily available in the literature, but correcting ability of the existing models was poor. Therefore, in this work, two new models have been developed for better correlation based on solid–liquid phase equilibria. The new model has five adjustable parameters correlating the solubility isotherms as a function of temperature. The accuracy of the proposed models was evaluated by correlating 25 binary systems. The proposed models observed provide the best overall correlations. The overall deviation between the experimental and the correlated results was less than 11.46% in averaged absolute relative deviation (AARD). Moreover, exiting solubility models were also evaluated for all the compounds for the comparison purpose.

Effect of pressure on the solid-liquid phase equilibria in (water + sodium sulfate) system

1992 ◽  
Vol 76 ◽  
pp. 163-173 ◽  
Author(s):  
Y. Tanaka ◽  
S. Hada ◽  
T. Makita ◽  
M. Moritoki
Keyword(s):  
Liquid Phase ◽  
Phase Equilibria ◽  
Sodium Sulfate ◽  
Effect Of Pressure ◽  
Solid Liquid

Solid-liquid Phase Equilibria of U(VI) in NaCl Solutions

1998 ◽  
Vol 62 (2) ◽  
pp. 245-263 ◽  
Author(s):  
P. Dı́az Arocas ◽  
B. Grambow
Keyword(s):  
Liquid Phase ◽  
Phase Equilibria ◽  
Solid Liquid
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