Reactions of carbanions of dimethyl sulfoxide and dimethyl sulfone with isocyanates, isothiocyanates, and other electrophilic reagents. Preparation of .beta.-amido and .beta.-thioamido sulfoxides and sulfones

1971 ◽  
Vol 36 (13) ◽  
pp. 1742-1744 ◽  
Author(s):  
Maximilian Von Strandtmann ◽  
S. Klutchko ◽  
D. Connor ◽  
John Shavel
Keyword(s):  
Dimethyl Sulfoxide ◽  
Dimethyl Sulfone ◽  
Electrophilic Reagents

Why are dimethyl sulfoxide and dimethyl sulfone such good solvents?

2008 ◽  
Vol 14 (8) ◽  
pp. 689-697 ◽  
Author(s):  
Timothy Clark ◽  
Jane S. Murray ◽  
Pat Lane ◽  
Peter Politzer
Keyword(s):  
Dimethyl Sulfoxide ◽  
Dimethyl Sulfone

A new approach to large scale production of dimethyl sulfone: a promising and strong recyclable solvent for ligand-free Cu-catalyzed C–C cross-coupling reactions

2020 ◽  
Vol 22 (6) ◽  
pp. 2069-2076
Author(s):  
Shen Cheng ◽  
Wei Wei ◽  
Xingyu Zhang ◽  
Hewei Yu ◽  
Mingming Huang ◽  
...  
Keyword(s):  
Dimethyl Sulfoxide ◽  
Large Scale ◽  
Cross Coupling ◽  
Scale Production ◽  
Coupling Reactions ◽  
New Approach ◽  
Dimethyl Sulfone ◽  
Cross Coupling Reactions ◽  
Large Scale Production ◽  
Ligand Free

Dimethyl sulfone (DMSN or MSM) was prepared via efficient oxidation of dimethyl sulfoxide and used and developed as an efficient, viscose, and recyclable solvent for ligand-free CuI-catalyzed Heck, Suzuki, and Sonogashira cross-coupling reactions.

Origins of the Acidity Trends in Dimethyl Sulfide, Dimethyl Sulfoxide, and Dimethyl Sulfone

1994 ◽  
Vol 116 (20) ◽  
pp. 9257-9261 ◽  
Author(s):  
Peter Speers ◽  
Keith E. Laidig ◽  
Andrew Streitwieser
Keyword(s):  
Dimethyl Sulfoxide ◽  
Dimethyl Sulfide ◽  
Dimethyl Sulfone

Determination of dimethyl sulfoxide and dimethyl sulfone in air

1991 ◽  
Vol 63 (2) ◽  
pp. 186-189 ◽  
Author(s):  
Russell F. Lang ◽  
Cheryl J. Brown
Keyword(s):  
Dimethyl Sulfoxide ◽  
Dimethyl Sulfone
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