Surface and Pore Structure Assessment of Hierarchical MFI Zeolites by Advanced Water and Argon Sorption Studies

2012 ◽  
Vol 116 (35) ◽  
pp. 18816-18823 ◽  
Author(s):  
Matthias Thommes ◽  
Sharon Mitchell ◽  
Javier Pérez-Ramírez
2017 ◽  
Vol 7 (16) ◽  
pp. 3598-3612 ◽  
Author(s):  
Xinquan Shen ◽  
Jincan Kang ◽  
Wei Niu ◽  
Mengheng Wang ◽  
Qinghong Zhang ◽  
...  

The increase in the pore hierarchy of ZnO/hierarchical H-ZSM-5 catalysts increased the catalyst stability and the yield of aromatics, particularly BTX, from methanol.


2012 ◽  
Vol 472-475 ◽  
pp. 2059-2063
Author(s):  
Xiu Ying Liu ◽  
Jun De Zhang ◽  
Zhi Qin Fan ◽  
Wei Guo Sun ◽  
Guang Sheng Kang

Zeolites belong to a most prominent class of nanoporous materials which have been considered as potential sorbents for hydrogen storage. The adsorption of hydrogen molecules on MFI, MOR and LTA zeolites, which encompass a range of different pore structure and chemical composition, has been simulated employing Grand Canonical Monte Carlo (GCMC) method. We compare their capacities of hydrogen storage at different temperatures and pressures. The results show that the adsorbed amounts is in order of LTA>MOR>MFI at the same condition. The effects of pore structure of zeolites, temperature and pressure on the hydrogen adsorption has been examined. The results clearly show that: (1) the temperature effect on the adsorption decreases with decreasing in the number of hydrogen molecules adsorbed. (2) A large volume of micropores and a suitable diameter near to the kinetic diameter of a hydrogen molecule are important for improving the hydrogen-storage capacity of zeolites. Based on this, we can conclude that the LTA zeolite with a large pore volume and a suitable channel diameter exhibits a most efficient hydrogen storage capacity than MOR and MFI zeolites.


Author(s):  
C. A. Callender ◽  
Wm. C. Dawson ◽  
J. J. Funk

The geometric structure of pore space in some carbonate rocks can be correlated with petrophysical measurements by quantitatively analyzing binaries generated from SEM images. Reservoirs with similar porosities can have markedly different permeabilities. Image analysis identifies which characteristics of a rock are responsible for the permeability differences. Imaging data can explain unusual fluid flow patterns which, in turn, can improve production simulation models.Analytical SchemeOur sample suite consists of 30 Middle East carbonates having porosities ranging from 21 to 28% and permeabilities from 92 to 2153 md. Engineering tests reveal the lack of a consistent (predictable) relationship between porosity and permeability (Fig. 1). Finely polished thin sections were studied petrographically to determine rock texture. The studied thin sections represent four petrographically distinct carbonate rock types ranging from compacted, poorly-sorted, dolomitized, intraclastic grainstones to well-sorted, foraminiferal,ooid, peloidal grainstones. The samples were analyzed for pore structure by a Tracor Northern 5500 IPP 5B/80 image analyzer and a 80386 microprocessor-based imaging system. Between 30 and 50 SEM-generated backscattered electron images (frames) were collected per thin section. Binaries were created from the gray level that represents the pore space. Calculated values were averaged and the data analyzed to determine which geological pore structure characteristics actually affect permeability.


2020 ◽  
Author(s):  
Peng Xia ◽  
Hongnan Li ◽  
Yong Fu ◽  
Wenlang Qiao ◽  
Chuan Guo ◽  
...  

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