scholarly journals Conformational Preferences of N,N-Dimethylsuccinamate as a Function of Alkali and Alkaline Earth Metal Salts: Experimental Studies in DMSO and Water As Determined by 1H NMR Spectroscopy

2014 ◽  
Vol 118 (11) ◽  
pp. 1965-1970 ◽  
Author(s):  
Holden W. H. Lai ◽  
Albert Tianxiang Liu ◽  
Bright U. Emenike ◽  
William R. Carroll ◽  
John D. Roberts

2016 ◽  
Vol 45 (8) ◽  
pp. 3590-3598 ◽  
Author(s):  
Jiaping Zhu ◽  
Shaohua Jin ◽  
Li Wan ◽  
Chunyuan Zhang ◽  
Lijie Li ◽  
...  

4,4′-Azo-bis(1,2,4-triazolone) (ZTO) based salts from alkaline (Li+, K+, Na+, and Cs+), alkaline earth metal salts (Mg2+, Ca2+, Sr2+, and Ba2+) and hydrazinium salt were synthesized in a simple, straightforward manner and were characterized by IR and NMR spectroscopy, elemental analysis.



2006 ◽  
Vol 36 (8) ◽  
pp. 487-501 ◽  
Author(s):  
Spring M. Downer ◽  
Philip J. Squattrito ◽  
Naima Bestaoui ◽  
Abraham Clearfield




2016 ◽  
Vol 128 (11) ◽  
pp. 1765-1774 ◽  
Author(s):  
BIKSHANDARKOIL R SRINIVASAN ◽  
KIRAN T DHAVSKAR ◽  
CHRISTIAN NÄTHER


Tetrahedron ◽  
2005 ◽  
Vol 61 (46) ◽  
pp. 10965-10974 ◽  
Author(s):  
James R. Burgeson ◽  
Delvis D. Dore ◽  
Jean M. Standard ◽  
Shawn R. Hitchcock


2013 ◽  
Vol 30 ◽  
pp. 1-4 ◽  
Author(s):  
Elliot Combs ◽  
Basak Cinlar ◽  
Yomaira Pagan-Torres ◽  
James A. Dumesic ◽  
Brent H. Shanks


1997 ◽  
Vol 52 (4) ◽  
pp. 351-357 ◽  
Author(s):  
A. Kondoh ◽  
T. Oi

Abstract Interaction of alkaline earth metal (magnesium, calcium, strontium and barium) ions with acetic and lactic acid in aqueous media was investigated by 13C NMR spectroscopy. In the acetate systems, signals whose chemical shifts were the averages of those of the free and bound acetate ions were observed. Downfield shifts of the carboxylate carbon signals with increasing metal ion concentration indicated that the acetate ion acted as a monodentate ligand coordinating to the metal ion using the carboxylate group. The metal ion concentration dependence of the peak positions of the methine and carboxylate carbon signals of the lactate ion in the lactate systems suggested that the lactate ion coordinated to a metal ion using the carboxylate and hydroxyl groups. Unique upfield shifts upon complexation in the magnesium lactate systems suggested that the lactate ion coordinated to the magnesium ion from outside the primary hydration sphere.The present results were consistent with the isotope effects of the alkaline earth metals observed in cation exchange chromatography.



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