Atomistic Description of the Solubilisation of Testosterone Propionate in a Sodium Dodecyl Sulfate Micelle

2014 ◽  
Vol 118 (46) ◽  
pp. 13192-13201 ◽  
Author(s):  
Daniel T. Allen ◽  
Yussif Saaka ◽  
M. Jayne Lawrence ◽  
Christian D. Lorenz

2006 ◽  
Vol 44 (6) ◽  
pp. 586-593 ◽  
Author(s):  
Brandon A. Begotka ◽  
Jennifer L. Hunsader ◽  
Chinelo Oparaeche ◽  
Jonathan K. Vincent ◽  
Kevin F. Morris


Langmuir ◽  
2012 ◽  
Vol 28 (11) ◽  
pp. 4931-4938 ◽  
Author(s):  
Hui Yan ◽  
Peng Cui ◽  
Cheng-Bu Liu ◽  
Shi-Ling Yuan


2010 ◽  
Vol 114 (8) ◽  
pp. 2719-2727 ◽  
Author(s):  
Fang Li ◽  
Lingyun Wang ◽  
Nan Xiao ◽  
Minghui Yang ◽  
Ling Jiang ◽  
...  


2002 ◽  
Vol 80 (12) ◽  
pp. 1655-1661 ◽  
Author(s):  
Lin Guo ◽  
Ying-qiu Liang

5,10,15-Tri(4-hydroxyphenyl)-20-(4-hexadecyloxyphenyl)porphyrin (P) was solubilized in sodium dodecyl sulfate (SDS) micelle solutions. Taking advantage of the protonation and deprotonation properties of the amphiphilic porphyrin allowed the study of the pH-controlled transfer process of P in SDS micelle by means of UV–vis and fluorescence spectra. In neutral SDS micelle, P may be protonated and located at the outer surface of the micelle. In mildly basic conditions the hydrophilic ability of P decreases and the porphyrin moiety may transfer to the inner layer of SDS micelle. In strong basic conditions the porphyrin may transfer back to the outer aqueous surface of the micelle. The kinetic study of the porphyrin complexed with Cu(II) shows that the metalation rate of P could be controlled by changing the pH.Key words: porphyrin, location, metalation, sodium dodecyl sulfate, micelle.



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