Pyrrolidinium-Based Ionic Liquids Doped with Lithium Salts: How Does Li+ Coordination Affect Its Diffusivity?

2014 ◽  
Vol 118 (47) ◽  
pp. 13679-13688 ◽  
Author(s):  
Franca Castiglione ◽  
Antonino Famulari ◽  
Guido Raos ◽  
Stefano V. Meille ◽  
Andrea Mele ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Lithium Salts

Difference in chemical bonding between lithium and sodium salts: influence of covalency on their solubility

2017 ◽  
Vol 19 (26) ◽  
pp. 17366-17372 ◽  
Author(s):  
Su Chen ◽  
Jun Ishii ◽  
Shunsuke Horiuchi ◽  
Masahiro Yoshizawa-Fujita ◽  
Ekaterina I Izgorodina
Keyword(s):  
Ionic Liquids ◽  
Chemical Bonding ◽  
Theoretical Study ◽  
Lithium Salts ◽  
Sodium Salts ◽  
The Difference

The current theoretical study explains the difference in solubility between lithium and sodium salts in ionic liquids due to increased covalency in lithium salts.

Effect of Nitrile-Functionalization of Imidazolium-Based Ionic Liquids on Their Transport Properties, Both Pure and Mixed with Lithium Salts

2014 ◽  
Vol 44 (3-4) ◽  
pp. 495-510 ◽  
Author(s):  
Hassan Srour ◽  
Mounir Traïkia ◽  
Bernard Fenet ◽  
Hélène Rouault ◽  
Margarida F. Costa Gomes ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Transport Properties ◽  
Lithium Salts

scholarly journals Molecular dynamics analysis of the effect of electronic polarization on the structure and single-particle dynamics of mixtures of ionic liquids and lithium salts

2016 ◽  
Vol 145 (20) ◽  
pp. 204507 ◽  
Author(s):  
Volker Lesch ◽  
Hadrián Montes-Campos ◽  
Trinidad Méndez-Morales ◽  
Luis Javier Gallego ◽  
Andreas Heuer ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Ionic Liquids ◽  
Single Particle ◽  
Particle Dynamics ◽  
Lithium Salts ◽  
Dynamics Analysis ◽  
Electronic Polarization

Solvation of Lithium Salts in Protic Ionic Liquids: A Molecular Dynamics Study

2014 ◽  
Vol 118 (3) ◽  
pp. 761-770 ◽  
Author(s):  
Trinidad Méndez-Morales ◽  
Jesús Carrete ◽  
Óscar Cabeza ◽  
Olga Russina ◽  
Alessandro Triolo ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Ionic Liquids ◽  
Lithium Salts ◽  
Protic Ionic Liquids

scholarly journals Efficient CO2 capture by tertiary amine-functionalized ionic liquids through Li+-stabilized zwitterionic adduct formation

2014 ◽  
Vol 10 ◽  
pp. 1959-1966 ◽  
Author(s):  
Zhen-Zhen Yang ◽  
Liang-Nian He
Keyword(s):  
Ionic Liquids ◽  
Co2 Capture ◽  
Tertiary Amine ◽  
Adduct Formation ◽  
Lithium Salts ◽  
Organic Base ◽  
Organic Bases ◽  
Amine Functionalized ◽  
Neutral Ligands ◽  
Cation Coordination

Highly efficient CO2 absorption was realized through formation of zwitterionic adducts, combining synthetic strategies to ionic liquids (ILs) and coordination. The essence of our strategy is to make use of multidentate cation coordination between Li+ and an organic base. Also PEG-functionalized organic bases were employed to enhance the CO2-philicity. The ILs were reacted with CO2 to form the zwitterionic adduct. Coordination effects between various lithium salts and neutral ligands, as well as the CO2 capacity of the chelated ILs obtained were investigated. For example, the CO2 capacity of PEG150MeBu2N increased steadily from 0.10 to 0.66 (mol CO2 absorbed per mol of base) through the formation of zwitterionic adducts being stabilized by Li+.

Solubility, ionic conductivity and viscosity of lithium salts in room temperature ionic liquids

2009 ◽  
Vol 11 (9) ◽  
pp. 1453 ◽  
Author(s):  
Zachary P. Rosol ◽  
Natalie J. German ◽  
Stephen M. Gross
Keyword(s):  
Ionic Liquids ◽  
Ionic Conductivity ◽  
Room Temperature ◽  
Lithium Salts ◽  
Room Temperature Ionic Liquids

Glass transition, viscosity, and conductivity correlations in solutions of lithium salts in PEGylated imidazolium ionic liquids

2014 ◽  
Vol 198 ◽  
pp. 398-408 ◽  
Author(s):  
Lin Wu ◽  
Ramaswamy I. Venkatanarayananan ◽  
Xingzhao Shi ◽  
Dipankar Roy ◽  
Sitaraman Krishnan
Keyword(s):  
Ionic Liquids ◽  
Glass Transition ◽  
Lithium Salts ◽  
Imidazolium Ionic Liquids
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