Interaction of Poly(ethylene glycol) Monoalkyl Ethers with Synthetic Saponites in Aqueous Suspensions:  A Multinuclear Magnetic Resonance Study

Langmuir ◽  
1998 ◽  
Vol 14 (5) ◽  
pp. 1037-1040 ◽  
Author(s):  
J. Grandjean





2018 ◽  
Vol 27 (5-6) ◽  
pp. 659-669 ◽  
Author(s):  
Sofia Bisso ◽  
Anna Degrassi ◽  
Davide Brambilla ◽  
Jean-Christophe Leroux


2007 ◽  
Vol 56 (4) ◽  
pp. 506-511 ◽  
Author(s):  
Alberto Prior-Cabanillas ◽  
José M Barrales-Rienda ◽  
Gloria Frutos ◽  
Isabel Quijada-Garrido


2020 ◽  
Vol 982 ◽  
pp. 26-33
Author(s):  
Ling Wei ◽  
Da Wei Li

Solid-state high-resolution 13C/7Li nuclear magnetic resonance (NMR) study was performed on the phase structure and chain dynamics of PEG-PPG-PEGn/LiCF3SO3 (n=3, 6, 12) copolymer electrolytes. PEG repeating units and Li+ form PEG3:LiCF3SO3 crystalline complex and PE3/Li+ amorphous complex in all the samples. PPG repeating units and Li+ form different complexes with respect to O:Li+ feed ratio (denoted as PP/Li+-3/6/12). The 13C chemical shifts and half widths of the signals from PP/Li+-3/6/12 remain unchanged, which implies the structures of PP/Li+-3/6/12 are similar at least in a very short range. The half width of the 7Li signals from PP/Li+-3/6/12 becomes narrower and narrower as the Li+ concentration decreases. This indicates the chain mobility of the amorphous phase increases with the decrease of ionic concentration. Moreover, neat crystalline PEG, neat amorphous PEG and neat amorphous PPG start to appear when O:Li+ is greater than 3:1 and their contents increase with the increase of O:Li+. Overall, solid-state high-resolution NMR is a powerful and unique method for understanding the phase structure and chain dynamics of solid polymer electrolytes (SPEs), more applications of this technique to studies on SPEs is expecting.



2015 ◽  
Vol 2015 ◽  
pp. 1-6 ◽  
Author(s):  
Yancong Zhang ◽  
Lianying Zhang ◽  
Xinfeng Song ◽  
Xiangling Gu ◽  
Hanwen Sun ◽  
...  

Novel method for synthesis of superparamagnetic iron oxide nanoparticles (SPIONs) coated with polyethylenimine (PEI) and modified with poly(ethylene glycol) methyl ether (MPEG), MPEG-PEI-SPIONs, was developed. PEI-SPIONs were successfully prepared in aqueous system via photochemistry, and their surface was modified with poly(ethylene glycol) methyl ether (MPEG). The so-obtained MPEG-PEI-SPIONs had a uniform hydrodynamic particle size of 34 nm. The successful coating of MPEG-PEI on the SPIONs was ascertained from FT-IR analysis, and the PEI and MPEG fractions in MPEG-PEI-SPIONs were calculated to account for 31% and 12%, respectively. Magnetic measurement revealed that the saturated magnetization of MPEG-PEI-SPIONs reached 46 emu/g and the nanoparticles showed the characteristic of being superparamagnetic. The stability experiment revealed that the MPEG-PEI modification improved the nanoparticles stability greatly.T2 relaxation measurements showed that MPEG-PEI-SPIONs show similarR2 value to the PEI-SPIONs. TheT2-weighted magnetic resonance imaging (MRI) of MPEG-PEI-SPIONs showed that the magnetic resonance signal was enhanced significantly with increasing nanoparticle concentration in water. These results indicated that the MPEG-PEI-SPIONs had great potential for application in MRI.



2011 ◽  
Vol 47 (46) ◽  
pp. 12518 ◽  
Author(s):  
Hee-Man Yang ◽  
Chan Woo Park ◽  
Sujin Lim ◽  
Sung-Il Park ◽  
Bong Hyun Chung ◽  
...  


RSC Advances ◽  
2016 ◽  
Vol 6 (68) ◽  
pp. 63788-63800 ◽  
Author(s):  
G. Ramniceanu ◽  
B.-T. Doan ◽  
C. Vezignol ◽  
A. Graillot ◽  
C. Loubat ◽  
...  

We report on the synthesis, characterization, stability and pharmacokinetics of novel iron based contrast agents for magnetic resonance imaging (MRI).



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