13C NMR Spectroscopy Studies of Branching and Sequence Distribution in Copolymers of Vinyl Acetate andn-Butyl Acrylate Prepared by Semibatch Emulsion Copolymerization

2001 ◽  
Vol 34 (4) ◽  
pp. 817-829 ◽  
Author(s):  
David Britton ◽  
Frank Heatley ◽  
Peter A. Lovell

2003 ◽  
Vol 338 (15) ◽  
pp. 1559-1569 ◽  
Author(s):  
Marc Lahaye ◽  
Corinne Rondeau-Mouro ◽  
Estelle Deniaud ◽  
Alain Buléon


2018 ◽  
Vol 297 (1) ◽  
pp. 133-139 ◽  
Author(s):  
Yusuke Iizuka ◽  
Yoshimasa Yamamoto ◽  
Seiichi Kawahara


1976 ◽  
Vol 49 (5) ◽  
pp. 1269-1275
Author(s):  
Y. Tanaka ◽  
H. Sato

Abstract Recently 13C NMR spectroscopy has been successfully applied to investigate the sequence distribution of 1,2- and 1,4-units or cis-1,4- and trans-1,4-units in polybutadienes. As for polyisoprenes, however, few investigations have been made on the sequence distribution of isomeric structures using this technique, although Duch and Grant have assigned the 13C NMR signals of cis-1,4- and trans-l,4-homopolyisoprenes. In previous work we have found new signals attributed to cis-trans linkages in the 13C NMR spectra of cis-trans isomerized polyisoprenes and assigned the signals using diad sequences of cis-1,4- and trans-l,4-units. We have also studied the 13C NMR spectra of hydrogenated polyisoprenes containing various amounts of 1,4- and 3,4-units and the sequence distribution of 1,4- and 3,4-units were discussed for n-BuLi-catalyzed polyisoprenes. In this work we have investigated the sequence distribution of chicle polyisoprene and cis-trans isomerized 1,4-polyisoprenes containing various ratios of cis-1,4- and trans-1,4-units.



2012 ◽  
Vol 17 (6) ◽  
pp. 458-467 ◽  
Author(s):  
Tay-Lung Chung ◽  
Jenn-Shing Chen ◽  
Chih-Yu Chiu ◽  
Guanglong Tian


2009 ◽  
Vol 64 (3) ◽  
pp. 259-273 ◽  
Author(s):  
Piotr Bujak ◽  
Marek Matlengiewicz ◽  
Marcin Pasich ◽  
Norbert Henzel




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