Time-resolved color-changed long-afterglow for security systems based on metal-organic hybrids

Organic solid-state materials with p-RTP (persistent room-temperature phosphorescence) properties have been made infusive achievements. However, researches on metal-organic hybrids with p-RTP are limited, in which dual phosphorescent ones are relatively...

Reversible Luminescent "Off-On" Regulation Based on Tunable Photodimerization via Crystal-to-Cocrystal Transformation

The photophysical properties of organic solid-state materials are inextricably linked to the molecular structures and packing modes. However, it is still a challenge to accurately tune the fluorescent color or...

Opportunities Using Boron to Direct Reactivity in the Organic Solid State

This Account describes work by our research group that highlights opportunities to utilize organoboron molecules to direct chemical reactivity in the organic solid state. Specifically, we convey a previously unexplored use of hydrogen bonding of boronic acids and boron coordination in boronic esters to achieve [2+2]-photocycloadditions in crystalline solids. Organoboron molecules act as templates or ‘shepherds’ to organize alkenes in a suitable geometry to undergo regio- and stereoselective [2+2]-photocycloadditions in quantitative yields. We also provide a selection of publications that served as an inspiration for our strategies and offer challenges and opportunities for future developments of boron in the field of materials and solid-state chemistry.1 Introduction1.1 Template Strategy for [2+2]-Photocycloadditions in the Solid State2 Boronic Acids as Templates for [2+2]-Photocycloadditions in the Solid State2.1 Supramolecular Catalysis of [2+2]-Photocycloadditions in the Solid State Using Boronic Acids3 Boronic Esters as Templates for [2+2]-Photocycloadditions in the Solid State3.1 Application of Photoproducts: Separation of Thiophene from Benzene through Crystallization3.2 Crystal Reactivity of B←N-Bonded Adducts: The Case of Styryl­thiophenes4 Conclusions and Perspectives