Tuning the Optoelectronic Properties of Vinylene-Linked Donor−Acceptor Copolymers for Organic Photovoltaics

2010 ◽  
Vol 43 (16) ◽  
pp. 6685-6698 ◽  
Author(s):  
Sangwon Ko ◽  
Rajib Mondal ◽  
Chad Risko ◽  
Jung Kyu Lee ◽  
Sanghyun Hong ◽  
...  
2020 ◽  
Vol 22 (46) ◽  
pp. 27413-27424
Author(s):  
Michele Turelli ◽  
Domenico Alberga ◽  
Gianluca Lattanzi ◽  
Ilaria Ciofini ◽  
Carlo Adamo

Transport mechanisms in a set of crystal polymorphs of a donor–acceptor dyad used in a SMOSC, are revealed through the comparison of polymorphs’ transport efficiencies. The findings offer hints on how to improve the design of better performing dyads.


Author(s):  
Xiaoling Ma ◽  
Changquan Tang ◽  
Yunlong Ma ◽  
Xixiang Zhu ◽  
Jian Wang ◽  
...  

2020 ◽  
Author(s):  
Ain Uddin ◽  
Kyle Plunkett

A series of donor-acceptor copolymers with dicyclopenta[cd,jk]pyrene and dicyclopenta[cd,lm]perylene acceptor units was prepared via palladium catalyzed cyclopenta-annulation reactions. The acceptor units were paired with diethynyl containing donor groups based on benzo[1,2-b:4,5-b']dithiophene, thieno[3,2-b]thiophene, and 4-octyl-4H-dithieno[3,2-b:2',3'-d]pyrrole to create six polymer variants. The cyclopentannulation polymerization resulted in copolymers with molecular weights (Mn) of 6-14 kDa and broad light absorption in the visible region with band gaps of 1.38-1.85 eV. The synthetic methodology, as well as optoelectronic properties, including thin-film absorption and cyclic voltammetry, of the donor-acceptor copolymers are presented.<br> <br><br>


2017 ◽  
Vol 8 (13) ◽  
pp. 2764-2773 ◽  
Author(s):  
Monroe P. Griffin ◽  
Raluca Gearba ◽  
Keith J. Stevenson ◽  
David A. Vanden Bout ◽  
Andrei Dolocan

2021 ◽  
Author(s):  
Thomas Chaney ◽  
Andrew Levin ◽  
Sebastian Schneider ◽  
Michael F. Toney

Precise control of the complex morphology of organic photovoltaic bulk heterojunction (BHJ) active layers remains an important yet challenging approach for improving power conversion efficiency. Of particular interest are the...


Author(s):  
Chia-Hsun Chen ◽  
Chien-Ju Chen ◽  
Yi-An Chen ◽  
Yu-Hsiang Chang ◽  
Hsiao-Chiao Liu ◽  
...  

2020 ◽  
Vol 4 (4) ◽  
pp. 2026-2034
Author(s):  
Samuel S. Lawton ◽  
Daniel Warr ◽  
Luís M. A. Perdigão ◽  
Yujing Chang ◽  
Agnieszka Pron ◽  
...  

Organic photovoltaics (OPVs) are attracting significant attention due to the growing demand for economically viable and renewable energy sources.


2019 ◽  
Vol 15 ◽  
pp. 2914-2921
Author(s):  
Daniel R Sutherland ◽  
Nidhi Sharma ◽  
Georgina M Rosair ◽  
Ifor D W Samuel ◽  
Ai-Lan Lee ◽  
...  

Herein, we report a mild and efficient palladium-catalyzed C–H functionalization method to synthesize a series of benzoquinone (BQ)-based charge-transfer (CT) derivatives in good yields. The optoelectronic properties of these compounds were explored both theoretically and experimentally and correlations to their structures were identified as a function of the nature and position of the donor group (meta and para) attached to the benzoquinone acceptor. Compound 3, where benzoquinone is para-conjugated to the diphenylamine donor group, exhibited thermally activated delayed fluorescence (TADF) with a biexponential lifetime characterized by a prompt ns component and a delayed component of 353 μs.


RSC Advances ◽  
2015 ◽  
Vol 5 (81) ◽  
pp. 66005-66012 ◽  
Author(s):  
Mohamed Shaker ◽  
Jong-Hoon Lee ◽  
Cuc Kim Trinh ◽  
Wonbin Kim ◽  
Kwanghee Lee ◽  
...  

Synthesis of promising new composition low band gap small molecules based on the push–pull (donor–acceptor) system, which displayed power conversion efficiency of up to 3.24%.


2020 ◽  
Vol 26 (6) ◽  
Author(s):  
Shafiq UrRehman ◽  
Asma Alam ◽  
Shamsa Bibi ◽  
Sana Sadaf ◽  
Shanza Rauf Khan ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document