scholarly journals Immobilized transition metal-catalysts on functionalized metal-organic framework (MOF) and their catalytic properties for cross-coupling reactions

2020 ◽  
Author(s):  
Palani Elumalai
Keyword(s):  
Transition Metal ◽  
Catalytic Properties ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Metal Organic ◽  
Organic Framework

CoII immobilized on an aminated magnetic metal–organic framework catalyzed C–N and C–S bond forming reactions: a journey for the mild and efficient synthesis of arylamines and arylsulfides

2019 ◽  
Vol 43 (39) ◽  
pp. 15525-15538 ◽  
Author(s):  
Arezou Mohammadinezhad ◽  
Batool Akhlaghinia
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Efficient Synthesis ◽  
Bond Forming ◽  
Cross Coupling Reactions ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Organic Framework

The catalytic activity of Fe3O4@AMCA-MIL53(Al)-NH2-CoII NPs as a novel and inexpensive catalyst was investigated in the C–N and C–S cross coupling reactions.

scholarly journals The effects of active site and support on hydrogen elimination over transition-metal-functionalized yttria-decorated metal–organic frameworks

2019 ◽  
Vol 9 (24) ◽  
pp. 7003-7015
Author(s):  
Bo Yang ◽  
Kamal Sharkas ◽  
Laura Gagliardi ◽  
Donald G. Truhlar
Keyword(s):  
Transition Metal ◽  
Active Site ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Hydrogen Elimination ◽  
Metal Organic ◽  
Catalytic Cycles ◽  
Organic Framework

Transition-metal catalysts supported on a metal–organic framework have been screened computationally to reveal the best catalytic candidates for hydrogen elimination reactions, which are critical in many catalytic cycles.

scholarly journals Heterogeneous Metal–Organic Framework Catalysts for Suzuki-Miyaura Cross Coupling in the Pharma Industry

2021 ◽  
Vol 75 (11) ◽  
pp. 972-978
Author(s):  
Daniele Cartagenova ◽  
Stephan Bachmann ◽  
Jeroen A. Van Bokhoven ◽  
Kurt Püntener ◽  
Marco Ranocchiari
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
Critical Parameters ◽  
Coupling Reactions ◽  
Present Contribution ◽  
Heterogeneous Catalytic ◽  
Cross Coupling Reactions ◽  
Metal Organic ◽  
Organic Framework

The synthesis of drug substances (DS) requires the continuous effort of the pharma industry to ensure high sustainability standards. The Suzuki-Miyaura cross coupling is a fundamental C–C bond-forming reaction to produce complex DS intermediates. The present contribution points out the way in which the synthesis of DS intermediates by C–C cross coupling can be economically competitive, while minimizing waste by selecting the appropriate heterogeneous catalyst. By comparing homogeneous, immobilized heterogeneous catalysts on silica and metal–organic framework (MOF) catalysts, while considering the perspectives of academia and industry, the critical parameters for a successful industrial application of heterogeneous catalytic Suzuki-Miyaura cross coupling reactions were identified. Heterogeneous catalysts, such as MOFs, may provide a complementary platform for reducing waste and the costs of production related to such transformations.

Deoxygenative Transition-Metal-Promoted Reductive Coupling and Cross-Coupling of Alcohols and Epoxides

Synthesis ◽  
2020 ◽  
Vol 53 (02) ◽  
pp. 267-278
Author(s):  
Kenneth M. Nicholas ◽  
Chandrasekhar Bandari
Keyword(s):  
Transition Metal ◽  
Bond Activation ◽  
Bond Formation ◽  
Cross Coupling ◽  
Transition Metal Catalysts ◽  
Coupling Reactions ◽  
Reductive Coupling ◽  
Practical Applications ◽  
Cross Coupling Reactions ◽  
Carbon Carbon Bond

AbstractThe prospective utilization of abundant, CO2-neutral, renewable feedstocks is driving the discovery and development of new reactions that refunctionalize oxygen-rich substrates such as alcohols and polyols through C–O bond activation. In this review, we highlight the development of transition-metal-promoted reactions of renewable alcohols and epoxides that result in carbon–carbon bond-formation. These include reductive self-coupling reactions and cross-coupling reactions of alcohols with alkenes and arene derivatives. Early approaches to reductive couplings employed stoichiometric amounts of low-valent transition-metal reagents to form the corresponding hydrocarbon dimers. More recently, the use of redox-active transition-metal catalysts together with a reductant has enhanced the practical applications and scope of the reductive coupling of alcohols. Inclusion of other reaction partners with alcohols such as unsaturated hydrocarbons and main-group organometallics has further expanded the diversity of carbon skeletons accessible and the potential for applications in chemical synthesis. Catalytic reductive coupling and cross-coupling reactions of epoxides are also highlighted. Mechanistic insights into the means of C–O activation and C–C bond formation, where available, are also highlighted.1 Introduction2 Stoichiometric Reductive Coupling of Alcohols3 Catalytic Reductive Coupling of Alcohols3.1 Heterogeneous Catalysis3.2 Homogeneous Catalysis4 Reductive Cross-Coupling of Alcohols4.1 Reductive Alkylation4.2 Reductive Addition to Olefins5 Epoxide Reductive Coupling Reactions6 Conclusions and Future Directions

Palladium nanoparticles encapsulated inside the pores of a metal–organic framework as a highly active catalyst for carbon–carbon cross-coupling

RSC Advances ◽  
2014 ◽  
Vol 4 (97) ◽  
pp. 54487-54493 ◽  
Author(s):  
Ningzhao Shang ◽  
Shutao Gao ◽  
Xin Zhou ◽  
Cheng Feng ◽  
Zhi Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
Active Catalyst ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

Palladium nanoparticles were successfully encapsulated in the cages of MIL-101, which exhibited high catalytic activity toward the C–C coupling reactions.

Sign in / Sign up

Export Citation Format

Share Document