Palladium nanoparticles encapsulated inside the pores of a metal–organic framework as a highly active catalyst for carbon–carbon cross-coupling

RSC Advances ◽  
2014 ◽  
Vol 4 (97) ◽  
pp. 54487-54493 ◽  
Author(s):  
Ningzhao Shang ◽  
Shutao Gao ◽  
Xin Zhou ◽  
Cheng Feng ◽  
Zhi Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
Active Catalyst ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

Palladium nanoparticles were successfully encapsulated in the cages of MIL-101, which exhibited high catalytic activity toward the C–C coupling reactions.

CoII immobilized on an aminated magnetic metal–organic framework catalyzed C–N and C–S bond forming reactions: a journey for the mild and efficient synthesis of arylamines and arylsulfides

2019 ◽  
Vol 43 (39) ◽  
pp. 15525-15538 ◽  
Author(s):  
Arezou Mohammadinezhad ◽  
Batool Akhlaghinia
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Efficient Synthesis ◽  
Bond Forming ◽  
Cross Coupling Reactions ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Organic Framework

The catalytic activity of Fe3O4@AMCA-MIL53(Al)-NH2-CoII NPs as a novel and inexpensive catalyst was investigated in the C–N and C–S cross coupling reactions.

High Catalytic Activity of C 60 Pd n Encapsulated in Metal–Organic Framework UiO‐67, for Tandem Hydrogenation Reaction

2018 ◽  
Vol 24 (72) ◽  
pp. 19141-19145 ◽  
Author(s):  
Deng‐Yue Zheng ◽  
Xue‐Meng Zhou ◽  
Suresh Mutyala ◽  
Xiao‐Chun Huang
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Hydrogenation Reaction ◽  
High Catalytic Activity ◽  
Metal Organic ◽  
Organic Framework

The metal–organic framework UiO-66 with missing-linker defects: A highly active catalyst for carbon dioxide cycloaddition

2020 ◽  
Vol 277 ◽  
pp. 115560 ◽  
Author(s):  
Wenlong Xiang ◽  
Jie Ren ◽  
Si Chen ◽  
Chenyang Shen ◽  
Yifei Chen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Active Catalyst ◽  
Metal Organic Framework ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

A metal–organic framework with in situ generated low-coordinate binuclear Cu(i) units as a highly effective catalyst for photodriven hydrogen production

2020 ◽  
Vol 56 (49) ◽  
pp. 6700-6703
Author(s):  
Ning-Yu Huang ◽  
Hai He ◽  
Hao Li ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Production ◽  
Synergistic Effect ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Binuclear Copper ◽  
Metal Organic ◽  
Cu Ions ◽  
Organic Framework

Here, we report a metal–organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g−1 h−1) for photodriven H2 generation, which is attributed to the synergistic effect between the two Cu ions.

Cobalt nanoparticle-embedded nitrogen-doped carbon/carbon nanotube frameworks derived from a metal–organic framework for tri-functional ORR, OER and HER electrocatalysis

2019 ◽  
Vol 7 (8) ◽  
pp. 3664-3672 ◽  
Author(s):  
Hele Guo ◽  
Qichun Feng ◽  
Jixin Zhu ◽  
Jingsan Xu ◽  
Qianqian Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carbon Nanotube ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Nitrogen Doped ◽  
Metal Organic ◽  
Nitrogen Doped Carbon ◽  
Cobalt Nanoparticle ◽  
Organic Framework

A Co@N-CNTF electrocatalyst derived from a metal–organic framework exhibits high catalytic activity in the ORR, OER and HER.

A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

2019 ◽  
Vol 55 (98) ◽  
pp. 14781-14784 ◽  
Author(s):  
Ning-Yu Huang ◽  
Xue-Wen Zhang ◽  
Yu-Zhi Xu ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Co2 Reduction ◽  
Metal Center ◽  
High Catalytic Activity ◽  
Methylene Groups ◽  
Metal Organic ◽  
Repulsive Forces ◽  
Organic Framework

The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.

Interfacial assembly and hydrolysis for synthesizing a TiO2/metal–organic framework composite

Soft Matter ◽  
2017 ◽  
Vol 13 (48) ◽  
pp. 9174-9178 ◽  
Author(s):  
Lifei Liu ◽  
Fanyu Zhang ◽  
Jianling Zhang ◽  
Xiuniang Tan ◽  
Bingxing Zhang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Interfacial Assembly ◽  
Metal Organic ◽  
Organic Framework

The interfacial assembling and hydrolysis route is proposed for fabricating TiO2/UiO-67 composites, which have shown high catalytic activity for photocatalytic CO2 reduction.

scholarly journals A base-free Chan–Lam reaction catalyzed by an easily assembled Cu(II)-carboxylate metal-organic framework

2021 ◽  
pp. 174751982110265
Author(s):  
Xinhai Zhang ◽  
Jianhua Qin ◽  
Ruixuan Ma ◽  
Lei Shi
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Coupling Reaction ◽  
High Catalytic Activity ◽  
Arylboronic Acids ◽  
Metal Organic ◽  
Organic Framework

A new copper(II) metal-organic framework is constructed as a sustainable copper heterogeneous catalyst. Cu-DPTCA, with high catalytic activity, can effectively promote the Chan–Lam coupling reaction of arylboronic acids and amines without adding any base or additive.

scholarly journals Polyvinylpyrrolidone - Reduced Graphene Oxide - Pd Nanoparticles as an Efficient Nanocomposite for Catalysis Applications in Cross-Coupling Reactions

2019 ◽  
Vol 14 (3) ◽  
pp. 490
Author(s):  
Hany A. Elazab ◽  
Tamer T. El-Idreesy
Keyword(s):  
Graphene Oxide ◽  
Catalytic Activity ◽  
Reduced Graphene Oxide ◽  
Cross Coupling ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Highly Active ◽  
Defect Sites ◽  
Reduced Graphene

This paper reported a scientific approach adopting microwave-assisted synthesis as a synthetic route for preparing highly active palladium nanoparticles stabilized by polyvinylpyrrolidone (Pd/PVP) and supported on reduced Graphene oxide (rGO) as a highly active catalyst used for Suzuki, Heck, and Sonogashira cross coupling reactions with remarkable turnover number (6500) and turnover frequency of 78000 h-1. Pd/PVP nanoparticles supported on reduced Graphene oxide nanosheets (Pd-PVP/rGO) showed an outstanding performance through high catalytic activity towards cross coupling reactions. A simple, reproducible, and reliable method was used to prepare this efficient catalyst using microwave irradiation synthetic conditions. The synthesis approach requires simultaneous reduction of palladium and in the presence of Gaphene oxide (GO) nanosheets using ethylene glycol as a solvent and also as a strong reducing agent. The highly active and recyclable catalyst has so many advantages including the use of mild reaction conditions, short reaction times in an environmentally benign solvent system. Moreover, the prepared catalyst could be recycled for up to five times with nearly the same high catalytic activity. Furthermore, the high catalytic activity and recyclability of the prepared catalyst are due to the strong catalyst-support interaction. The defect sites in the reduced Graphene oxide (rGO) act as nucleation centers that enable anchoring of both Pd/PVP nanoparticles and hence, minimize the possibility of agglomeration which leads to a severe decrease in the catalytic activity. Copyright © 2019 BCREC Group. All rights reserved 

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