scholarly journals Stable isotopic compositions and fractionations of carbon monoxide at coastal and open ocean stations in the Pacific

Author(s):  
Fumiko Nakagawa
1999 ◽  
Vol 33 (27) ◽  
pp. 4357-4362 ◽  
Author(s):  
S. Kato ◽  
H. Akimoto ◽  
T. Röckmann ◽  
M. Bräunlich ◽  
C.A.M. Brenninkmeijer

1988 ◽  
Vol 25 (5) ◽  
pp. 701-709 ◽  
Author(s):  
A. E. Aksu ◽  
G. Vilks

Oxygen and carbon isotopic analyses have been performed on the tests of Planulina wuellerstorfi and three size fractions of sinistral Neogloboquadrina pachyderma recovered from 33 Arctic Ocean surface-sediment samples. Stable isotopic compositions of N. pachyderma are found to be dependent on the test size: larger specimens show considerable enrichment in both δ18O and δ18C. The difference between the isotopic compositions of the 63–125 and 125–250 μm size fractions in N. pachyderma can be explained by biogenic fractionation effects during foraminiferal test growth. Larger (250–500 μm) N. pachyderma displayed accretions of secondary calcite, i.e., the outermost shell contained significant amounts of inorganically precipitated magnesium calcite. Thus, larger foraminifera may not be suited for down-core stable isotopic studies. There is a difference of ~2‰ between δ18O values of surface samples from the eastern and western Arctic Ocean, reflecting large differences between surface-water salinity in these regions. Therefore, oxygen isotopic data may have limited use as a chronostratigraphic tool in down-core studies in the Arctic Ocean, but we can use them to infer past variations in surface-water salinities. Planulina wuellerstorfi also showed depletions of both δ18O and δ18C in its calcite tests relative to calcite precipitated in isotopic equilibrium with ambient sea water; these depletions ranged from −0.8 to −0.9‰ in δ18Oand −1.2 to −0.9‰ in δ18C. This taxon is found to deposit its shell very close to the δ18C of ΣCO2 of bottom waters.


2009 ◽  
Vol 6 (4) ◽  
pp. 7853-7896 ◽  
Author(s):  
M. Roy-Barman

Abstract. The "boundary scavenging" box model is a cornerstone of our understanding of the particle-reactive radionuclide fluxes between the open ocean and the ocean margins. However, it does not describe the radionuclide profiles in the water column. Here, I present the transport-reaction equations for radionuclides transported vertically by reversible scavenging on settling particles and laterally by horizontal currents between the margin and the open ocean. Analytical solutions of these equations are compared with existing data. In the Pacific Ocean, the model produces "almost" linear 230Th profiles (as observed in the data) despite lateral transport. However, omitting lateral transport biased the 230Th based particle flux estimates by as much as 50%. 231Pa profiles are well reproduced in the whole water column of the Pacific Margin and from the surface down to 3000 m in the Pacific subtropical gyre. Enhanced bottom scavenging or inflow of 231Pa-poor equatorial water may account for the model-data discrepancy below 3000 m. The lithogenic 232Th is modelled using the same transport parameters as 230Th but a different source function. The main source of 232Th scavenged in the open Pacific is advection from the ocean margin, whereas a net flux of 230Th produced in the open Pacific is advected and scavenged at the margin, illustrating boundary exchange. In the Arctic Ocean, the model reproduces 230Th measured profiles that the uni-dimensional scavenging model or the scavenging-ventilation model failed to explain. Moreover, if lateral transport is ignored, the 230Th based particle settling speed may by underestimated by a factor 4 at the Arctic Ocean margin. The very low scavenging rate in the open Arctic Ocean combined with the enhanced scavenging at the margin accounts for the lack of high 231Pa/230Th ratio in arctic sediments.


2016 ◽  
Vol 46 (6) ◽  
pp. 1657-1684 ◽  
Author(s):  
Zhongxiang Zhao ◽  
Matthew H. Alford ◽  
James B. Girton ◽  
Luc Rainville ◽  
Harper L. Simmons

AbstractA global map of open-ocean mode-1 M2 internal tides is constructed using sea surface height (SSH) measurements from multiple satellite altimeters during 1992–2012, representing a 20-yr coherent internal tide field. A two-dimensional plane wave fit method is employed to 1) suppress mesoscale contamination by extracting internal tides with both spatial and temporal coherence and 2) separately resolve multiple internal tidal waves. Global maps of amplitude, phase, energy, and flux of mode-1 M2 internal tides are presented. The M2 internal tides are mainly generated over topographic features, including continental slopes, midocean ridges, and seamounts. Internal tidal beams of 100–300 km width are observed to propagate hundreds to thousands of kilometers. Multiwave interference of some degree is widespread because of the M2 internal tide’s numerous generation sites and long-range propagation. The M2 internal tide propagates across the critical latitudes for parametric subharmonic instability (28.8°S/N) with little energy loss, consistent with the 2006 Internal Waves across the Pacific (IWAP) field measurements. In the eastern Pacific Ocean, the M2 internal tide loses significant energy in propagating across the equator; in contrast, little energy loss is observed in the equatorial zones of the Atlantic, Indian, and western Pacific Oceans. Global integration of the satellite observations yields a total energy of 36 PJ (1 PJ = 1015 J) for all the coherent mode-1 M2 internal tides. Finally, satellite observed M2 internal tides compare favorably with field mooring measurements and a global eddy-resolving numerical model.


1989 ◽  
Vol 102 (2) ◽  
pp. 257-263 ◽  
Author(s):  
C. L. Van Dover ◽  
B. Fry

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