scholarly journals Emission, oxidation, and secondary organic aerosol formation of volatile organic compounds as observed at Chebogue Point, Nova Scotia

2007 ◽  
Vol 112 (D10) ◽  
Author(s):  
R. Holzinger ◽  
D. B. Millet ◽  
B. Williams ◽  
A. Lee ◽  
N. Kreisberg ◽  
...  
Keyword(s):  
Nova Scotia ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Secondary Organic Aerosol ◽  
Organic Aerosol ◽  
Aerosol Formation ◽  
Volatile Organic ◽  
Secondary Organic Aerosol Formation

scholarly journals Gasoline aromatics: a critical determinant of urban secondary organic aerosol formation

2017 ◽  
Vol 17 (17) ◽  
pp. 10743-10752 ◽  
Author(s):  
Jianfei Peng ◽  
Min Hu ◽  
Zhuofei Du ◽  
Yinhui Wang ◽  
Jing Zheng ◽  
...  
Keyword(s):  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Urban Areas ◽  
Secondary Organic Aerosol ◽  
Organic Aerosol ◽  
Urban Atmosphere ◽  
Aerosol Formation ◽  
Vehicle Exhaust ◽  
Aromatic Content ◽  
Volatile Organic

Abstract. Gasoline vehicle exhaust is an important contributor to secondary organic aerosol (SOA) formation in urban atmosphere. Fuel composition has a potentially considerable impact on gasoline SOA production, but the link between fuel components and SOA production is still poorly understood. Here, we present chamber experiments to investigate the impacts of gasoline aromatic content on SOA production through chamber oxidation approach. A significant amplification factor of 3–6 for SOA productions from gasoline exhausts is observed as gasoline aromatic content rose from 29 to 37 %. Considerably higher emission of aromatic volatile organic compounds (VOCs) using high-aromatic fuel plays an essential role in the enhancement of SOA production, while semi-volatile organic compounds (e.g., gas-phase PAHs) may also contribute to the higher SOA production. Our findings indicate that gasoline aromatics significantly influence ambient PM2. 5 concentration in urban areas and emphasize that more stringent regulation of gasoline aromatic content will lead to considerable benefits for urban air quality.

scholarly journals Enhanced secondary organic aerosol formation from the photo-oxidation of mixed anthropogenic volatile organic compounds

2020 ◽  
Author(s):  
Junling Li ◽  
Hong Li ◽  
Kun Li ◽  
Yan Chen ◽  
Hao Zhang ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Motor Vehicle ◽  
Secondary Organic Aerosol ◽  
Reaction System ◽  
Organic Aerosol ◽  
Mass Spectrometry Analysis ◽  
Aerosol Formation ◽  
Volatile Organic

Abstract. Motor vehicle exhaust is one of the important contribution sources of secondary organic aerosol (SOA) in urban areas. Long-chain alkanes and aromatic hydrocarbons are included in gaseous organic pollutants of vehicle emissions, representative for diesel and gasoline vehicles respectively. In this work, the SOA production from individual anthropogenic volatile organic compounds (AVOCs) (n-dodecane, 1,3,5-trimethylbenzene) and mixed AVOCs (n-dodecane + 1,3,5-trimethylbenzene) were studied with a large-scale outdoor smog chamber. Results showed that the SOA formation from the mixed AVOCs was enhanced compared to the predicted SOA mass concentration based on the SOA yield of individual AVOCs. According to the results of mass spectrometry analysis with electrospray ionization time-of-flight mass spectrometry (ESI-TOF-MS), interaction occurred between intermediate products from the two precursors, which could be the main reason for the enhanced SOA production from the mixed AVOCs reaction system. This study indicates that further studies on SOA chemistry from the mixed VOCs reaction system are needed, as the interactions between them and the effect on SOA formation can give us a further understanding of the SOA formed in the atmosphere.

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