Evidence for the uptake of atmospheric acetone and methanol by the Arctic Ocean during late summer DMS-Emission plumes

Abstract. Oxalic and other small dicarboxylic acids have been reported as important water-soluble organic constituents of atmospheric aerosols from different environments. Their molecular distributions are generally characterized by the predominance of oxalic acid (C2) followed by malonic (C3) and/or succinic (C4) acids. In this study, we collected marine aerosols from the Arctic Ocean during late summer in 2009 when sea ice was retreating. The marine aerosols were analyzed for the molecular distributions of dicarboxylic acids as well as ketocarboxylic acids and α-dicarbonyls to better understand the source of water-soluble organics and their photochemical processes in the high Arctic marine atmosphere. We found that diacids are more abundant than ketoacids and α-dicarbonyls, but their concentrations are generally low (< 30 ng m−3), except for one sample (up to 70 ng m−3) that was collected near the mouth of Mackenzie River during clear sky condition. Although the molecular compositions of diacids are in general characterized by the predominance of oxalic acid, a depletion of C2 was found in two samples in which C4 became the most abundant. Similar depletion of oxalic acid has previously been reported in the Arctic aerosols collected at Alert after polar sunrise and in the summer aerosols from the coast of Antarctica. Because the marine aerosols that showed a depletion of C2 were collected under the overcast and/or foggy conditions, we suggest that a photochemical decomposition of oxalic acid may have occurred in aqueous phase of aerosols over the Arctic Ocean via the photo dissociation of oxalate-Fe (III) complex. We also determined stable carbon isotopic compositions (δ13C) of bulk aerosol carbon and individual diacids. The δ13C of bulk aerosols showed −26.5‰ (range: −29.7 to −24.7‰, suggesting that marine aerosol carbon is derived from both terrestrial and marine organic materials. In contrast, oxalic acid showed much larger δ13C values (average: −20.9‰, range: −24.7‰ to −17.0‰) than those of bulk aerosol carbon. Interestingly, δ13C values of oxalic acid were higher than C3 (av. −26.6‰) and C4 (−25.8‰) diacids, suggesting that oxalic acid is enriched with 13C due to its photochemical processing (aging) in the marine atmosphere.

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Arctic summer sea-ice SAR signatures, melt-season characteristics, and melt-pond fractions

Polar Record ◽

10.1017/s003224740001442x ◽

1997 ◽

Vol 33 (185) ◽

pp. 101-112 ◽

Cited By ~ 15

Author(s):

M. O. Jeffries ◽

K. Schwartz ◽

S. Li

Keyword(s):

Sea Ice ◽

Arctic Ocean ◽

Late Summer ◽

Beaufort Sea ◽

Early Summer ◽

The Arctic ◽

Late Winter ◽

Melt Pond ◽

Melt Ponds ◽

The Arctic Ocean

AbstractVariations in multiyear sea-ice backscatter from the synthetic aperture radar (SAR) aboard the ERS-1 satellite are interpreted in terms of melt-season characteristics (onset of melt in spring and of freeze-up in autumn, and the duration of the snow-decay period, the melt season, and the melt-pond season) from late winter to early autumn 1992 in two regions of the Arctic Ocean: the northeastern Beaufort Sea adjacent to the Queen Elizabeth Islands in the Canadian high Arctic and the western Beaufort Sea north of Alaska. In the northeastern Beaufort Sea, the onset of melt occurs later, and the periods of snow-cover decay and the occurrence of melt ponds are shorter than in the western Beaufort Sea. These melt-season characteristics of each area are consistent with previous observations that the northeastern Beaufort Sea has one of the most severe summer climates in the Arctic Ocean. A model, which assumes that the backscatter from multiyear floes is the sum of backscatter from bare ice and melt ponds, is used to derive the melt-pond fraction during the summer. The results show that melt-pond fractions decrease from an early-summer maximum of about 60% to a late-summer minimum around 10%. The magnitude of the melt-pond fractions and their decline during the summer is consistent with previous, more qualitative data. The SAR model, which gives melt-pond fractions with lower variability and less uncertainty than previous data, offers an improved approach to the reliable estimation of the areal extent of water on ice floes. Suggestions for further improvement of the model include accounting for the consequences of wind-speed variations, summer snowfall, and freeze/thaw cycles and their effects on melt-pond and ice-surface roughness.

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Influence of synoptic atmospheric conditions on movement of individual sea-ice floes in Fram Strait, late summer 2010

Annals of Glaciology ◽

10.3189/2015aog69a655 ◽

2015 ◽

Vol 56 (69) ◽

pp. 445-450

Author(s):

Jennifer A. King ◽

Grant R. Bigg ◽

Richard Hall

Keyword(s):

Sea Ice ◽

Arctic Ocean ◽

Late Summer ◽

The Arctic ◽

Boreal Summer ◽

Fram Strait ◽

Atmospheric Conditions ◽

Ice Dynamics ◽

The Arctic Ocean ◽

Ice Floes

AbstractIn this paper we investigate the effect on sea-ice movement of changes in the synoptic atmospheric conditions in late boreal summer 2010. Our study area is the western Fram Strait, a crucial passage for the transport of ice out of the Arctic basin. Ice dynamics here affect the movement of ice in the East Greenland Current, the transpolar drift and ice extent in the Arctic Ocean. In contrast to other times of the year, when the Fram Strait wind field is characterized by strong, persistent northerlies, we show that the weaker, more variable winds typical during late summer for the Fram Strait can slow movement of ice floes out of the area, thus slowing the export of ice from the Arctic Ocean at the end of summer, a time crucial for ice export. The Arctic Ocean could lose even more of the ice that survives the summer if this was not the case. This would leave the Arctic Ocean in an even more vulnerable position with regard to the amount of multi-year ice remaining the following summer.

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Distributions of low molecular weight dicarboxylic acids, ketoacids and α-dicarbonyls in the marine aerosols collected over the Arctic Ocean during late summer

Biogeosciences Discussions ◽

10.5194/bgd-9-10121-2012 ◽

2012 ◽

Vol 9 (8) ◽

pp. 10121-10148

Author(s):

K. Kawamura ◽

K. Ono ◽

E. Tachibana ◽

B. Charriére ◽

R. Sempéré

Keyword(s):

Oxalic Acid ◽

Arctic Ocean ◽

Late Summer ◽

Dicarboxylic Acids ◽

Water Soluble ◽

The Arctic ◽

Marine Atmosphere ◽

Marine Aerosols ◽

Δ13c Values ◽

The Arctic Ocean

Abstract. Oxalic and other small dicarboxylic acids have been reported as important water-soluble organic constituents of atmospheric aerosols from different environments. Their molecular distributions are generally characterized by the predominance of oxalic acid (C2) followed by malonic (C3) and/or succinic (C4) acids. In this study, we collected marine aerosols from the Arctic Ocean during late summer in 2009 when sea ice is retreated. The marine aerosols were analyzed for the molecular distributions of dicarboxylic acids as well as ketocarboxylic acids and α-dicarbonyls to better understand the source of water-soluble organics and their photochemical processes in the high Arctic marine atmosphere. We found that diacids are more abundant than ketoacids and α-dicarbonyls, but their concentrations are generally low (< 30 ng m−3), except for one sample (up to 70 ng m−3) that was collected near the mouth of Mackenzie River during clear sky condition. Although the molecular compositions of diacids are in general characterized by the predominance of oxalic acid, a depletion of C2 was found in two samples in which C4 became the most abundant. Similar depletion of oxalic acid has previously been reported in the Arctic aerosols collected at Alert after polar sunrise and in the summer aerosols from the coastal Antarctica. Because the marine aerosols that showed a depletion of C2 were observed under the overcast and/or foggy conditions, we suggest that a photochemical decomposition of oxalic acid may have occurred in aqueous phase of aerosols over the Arctic Ocean via the photo dissociation of oxalate-Fe (III) complex. We also determined stable carbon isotopic compositions (δ13C) of bulk aerosol carbon and individual diacids. The δ13C of bulk aerosols showed −26.5‰ (range: −29.7‰ to −24.7‰), suggesting that marine aerosol carbon is derived from both terrestrial and marine organic materials. In contrast, oxalic acid showed much larger δ13C values (average: −20.9‰, range: −24.7‰ to −17.0‰) than those of bulk aerosol carbon. Interestingly, δ13C values of oxalic acid were higher than C3 (av. −26.6‰) and C4 (−25.8‰) diacids, suggesting that oxalic acid is enriched with 13C due to its photochemical processing (aging) in the marine atmosphere.

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