Intrusion of basaltic sills into highly porous sediments, and resulting hydrothermal activity

Nature ◽  
1980 ◽  
Vol 283 (5746) ◽  
pp. 441-445 ◽  
Author(s):  
Gerhardt Einsele ◽  
Joris M. Gieskes ◽  
Joseph Curray ◽  
David M. Moore ◽  
Eduardo Aguayo ◽  
...  
Author(s):  
Steven D. Toteda

Zirconia oxygen sensors, in such applications as power plants and automobiles, generally utilize platinum electrodes for the catalytic reaction of dissociating O2 at the surface. The microstructure of the platinum electrode defines the resulting electrical response. The electrode must be porous enough to allow the oxygen to reach the zirconia surface while still remaining electrically continuous. At low sintering temperatures, the platinum is highly porous and fine grained. The platinum particles sinter together as the firing temperatures are increased. As the sintering temperatures are raised even further, the surface of the platinum begins to facet with lower energy surfaces. These microstructural changes can be seen in Figures 1 and 2, but the goal of the work is to characterize the microstructure by its fractal dimension and then relate the fractal dimension to the electrical response. The sensors were fabricated from zirconia powder stabilized in the cubic phase with 8 mol% percent yttria. Each substrate was sintered for 14 hours at 1200°C. The resulting zirconia pellets, 13mm in diameter and 2mm in thickness, were roughly 97 to 98 percent of theoretical density. The Engelhard #6082 platinum paste was applied to the zirconia disks after they were mechanically polished ( diamond). The electrodes were then sintered at temperatures ranging from 600°C to 1000°C. Each sensor was tested to determine the impedance response from 1Hz to 5,000Hz. These frequencies correspond to the electrode at the test temperature of 600°C.


Author(s):  
Ian M. Anderson ◽  
Arnulf Muan ◽  
C. Barry Carter

Oxide mixtures which feature a coexistence of phases with the wüstite and spinel structures are considered model systems for the study of solid-state reaction kinetics, phase boundaries, and thin-film growth, and such systems are especially suited to TEM studies. (In this paper, the terms “wüstite” and “spinel” will refer to phases of those structure types.) The study of wüstite-spinel coexistence has been limited mostly to systems near their equilibrium condition, where the assumptions of local thermodynamic equilibrium are valid. The cation-excess spinels of the type Ni2(1+x)Ti1-xO4, which reportedly exist only above 1375°C4, provide an excellent system for the study of wüstite-spinel coexistence under highly nonequilibrium conditions. The nature of these compounds has been debated in the literature. X-ray and neutron powder diffraction patterns have been used to advocate the existence of a single-phase, non- stoichiometric spinel. TEM studies of the microstructure have been used to suggest equilibrium coexistence of a stoichiometric spinel, Ni2TiO4, and a wüstite phase; this latter study has shown a coexistence of wüstite and spinel phases in specimens thought to have been composed of a single, non- stoichiometric spinel phase. The microstructure and nature of this phase coexistence is the focus of this study. Specimens were prepared by ball-milling a mixture of NiO and TiO2 powders with 10 wt.% TiO2. The mixture was fired in air at 1483°C for 5 days, and then quenched to room temperature. The aggregate thus produced was highly porous, and needed to be infiltrated prior to TEM sample preparation, which was performed using the standard techniques of lapping, dimpling, and ion milling.


2004 ◽  
Vol 46 (5) ◽  
pp. 243-247
Author(s):  
Wolfram Harbich ◽  
Udo Mücke ◽  
Georg Berger

Author(s):  
Jesper Kresten Nielsen ◽  
Mikael Pedersen

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Kresten Nielsen, J., & Pedersen, M. (1998). Hydrothermal activity in the Upper Permian Ravnefjeld Formation of central East Greenland – a study of sulphide morphotypes. Geology of Greenland Survey Bulletin, 180, 81-87. https://doi.org/10.34194/ggub.v180.5090 _______________ Bituminous shales of the Ravnefjeld Formation were deposited in the subsiding East Greenland basin during the Upper Permian. The shales are exposed from Jameson Land in the south (71°N; Fig. 1) to Clavering Ø in the north (74°20′N) and have attracted considerable attention due to their high potential as hydrocarbon source rocks (Piasecki & Stemmerik 1991; Scholle et al. 1991; Christiansen et al. 1992, 1993a, b). Furthermore, enrichment of lead, zinc and copper has been known in the Ravnefjeld Formation on Wegener Halvø since 1968 (Lehnert-Thiel 1968; Fig. 1). This mineralisation was assumed to be of primary or early diagenetic origin due to similarities with the central European Kupferschiefer (Harpøth et al. 1986). Later studies, however, suggested base metal mineralisation in the immediately underlying carbonate reefs to be Tertiary in age (Stemmerik 1991). Due to geographical coincidence between the two types of mineralisation, a common history is a likely assumption, but a timing paradox exists. A part of the TUPOLAR project on the ‘Resources of the sedimentary basins of North and East Greenland’ has been dedicated to re-investigation of the mineralisation in the Ravnefjeld Formation in order to determine the genesis of the mineralisation and whether or not primary or early diagenetic base metal enrichment has taken place on Wegener Halvø, possibly in relation to an early period of hydrothermal activity. One approach to this is to study the various sulphides in the Ravnefjeld Formation; this is carried out in close co-operation with a current Ph.D. project at the University of Copenhagen, Denmark. Diagenetically formed pyrite is a common constituent of marine shales and the study of pyrite morphotypes has previously been successful from thermalli immature parts of elucidating depositional environment and thermal effects in the Alum Shale Formation of Scandinavia (Nielsen 1996; Nielsen et al. 1998). The present paper describes the preliminary results of a similar study on pyrite from thermally immature parts of the Ravnefjeld Formation which, combined with the study of textures of base metal sulphides in the Wegener Halvø area (Fig. 1), may provide an important step in the evaluation of the presence or absence of early thermal activity on (or below) the Upper Permian sea floor.


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