Anhydrous proton conduction at 150 °C in a crystalline metal–organic framework

2009 ◽  
Vol 1 (9) ◽  
pp. 705-710 ◽  
Author(s):  
Jeff A. Hurd ◽  
Ramanathan Vaidhyanathan ◽  
Venkataraman Thangadurai ◽  
Christopher I. Ratcliffe ◽  
Igor L. Moudrakovski ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
Metal Organic ◽  
Anhydrous Proton Conduction ◽  
Crystalline Metal ◽  
Organic Framework

CsHSO4 — Proton conduction in a crystalline metal–organic framework

2012 ◽  
Vol 225 ◽  
pp. 420-423 ◽  
Author(s):  
V.G. Ponomareva ◽  
K.A. Kovalenko ◽  
A.P. Chupakhin ◽  
E.S. Shutova ◽  
V.P. Fedin
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
Metal Organic ◽  
Crystalline Metal ◽  
Organic Framework

scholarly journals Theoretical hydrogen bonding calculations and proton conduction for Eu(iii)-based metal–organic framework

RSC Advances ◽  
2021 ◽  
Vol 11 (19) ◽  
pp. 11495-11499
Author(s):  
Lu Feng ◽  
Tian-Yu Zeng ◽  
Hao-Bo Hou ◽  
Hong Zhou ◽  
Jian Tian
Keyword(s):  
Hydrogen Bonding ◽  
Theoretical Calculation ◽  
Proton Transport ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
Transport Channel ◽  
Proton Conducting ◽  
Metal Organic ◽  
Organic Framework

A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation.

scholarly journals Facile Proton Conduction via Ordered Water Molecules in a Phosphonate Metal−Organic Framework

2010 ◽  
Vol 132 (40) ◽  
pp. 14055-14057 ◽  
Author(s):  
Jared M. Taylor ◽  
Roger K. Mah ◽  
Igor L. Moudrakovski ◽  
Christopher I. Ratcliffe ◽  
Ramanathan Vaidhyanathan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
Water Molecules ◽  
Metal Organic ◽  
Ordered Water ◽  
Organic Framework

High Proton Conduction at above 100 °C Mediated by Hydrogen Bonding in a Lanthanide Metal–Organic Framework

2014 ◽  
Vol 136 (35) ◽  
pp. 12444-12449 ◽  
Author(s):  
Qun Tang ◽  
Yiwei Liu ◽  
Shuxia Liu ◽  
Danfeng He ◽  
Jun Miao ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Framework

Enhanced proton conduction of imidazole localized in one-dimensional Ni-metal-organic framework nanofibers

2020 ◽  
Vol 31 (12) ◽  
pp. 125702 ◽  
Author(s):  
Zhongxiong Bai ◽  
Shucheng Liu ◽  
Ping Chen ◽  
Guojie Cheng ◽  
Guangyao Wu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Functionality in metal–organic framework minerals: proton conductivity, stability and potential for polymorphism

2019 ◽  
Vol 10 (18) ◽  
pp. 4923-4929 ◽  
Author(s):  
Igor Huskić ◽  
Novendra Novendra ◽  
Dae-Woon Lim ◽  
Filip Topić ◽  
Hatem M. Titi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Proton ◽  
Metal Organic ◽  
Structure Retention ◽  
Organic Framework

Metal–organic framework minerals stepanovite and zhemchuzhnikovite can exhibit high proton conduction and structure retention on dehydration.

Synthesis of an ultra-stable metal–organic framework for proton conduction

CrystEngComm ◽  
2018 ◽  
Vol 20 (23) ◽  
pp. 3158-3161 ◽  
Author(s):  
Chuanfang Liu ◽  
Nian Zhao ◽  
Xiaoqin Zou ◽  
Guangshan Zhu
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
Metal Organic ◽  
Organic Framework

An ultra-stable metal organic framework material has been successfully synthesized for proton conduction.

scholarly journals Proton-conduction photomodulation in spiropyran-functionalized MOFs with large on–off ratio

2020 ◽  
Vol 11 (5) ◽  
pp. 1404-1410 ◽  
Author(s):  
Anemar Bruno Kanj ◽  
Abhinav Chandresh ◽  
Aaron Gerwien ◽  
Sylvain Grosjean ◽  
Stefan Bräse ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
Metal Organic ◽  
Organic Framework

A spiropyran functionalized metal–organic framework is presented, allowing to photomodulate the aqueous proton conductivity by two orders of magnitude.

Single Crystal Proton Conduction Study of a Metal Organic Framework of Modest Water Stability

2017 ◽  
Vol 139 (21) ◽  
pp. 7176-7179 ◽  
Author(s):  
Biplab Joarder ◽  
Jian-Bin Lin ◽  
Zaida Romero ◽  
George K. H. Shimizu
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
Water Stability ◽  
Metal Organic ◽  
Organic Framework

Dramatic Improvement of Stability by In-Situ Linker Cyclization of a Metal-Organic Framework

2018 ◽  
Author(s):  
Yun-Long Hou ◽  
Mu-Qing Li ◽  
Shengxian Cheng ◽  
Yingxue Diao ◽  
Filipe Vilela ◽  
...  
Keyword(s):  
Charge Transport ◽  
Metal Organic Framework ◽  
Dramatic Improvement ◽  
Electron Systems ◽  
Crystalline Order ◽  
Polycyclic Aromatic ◽  
Metal Organic ◽  
Crystalline Metal ◽  
Organic Framework

We employ a two-step strategy for accessing crystalline porous covalent networks of highly conjugated π-electron systems. For this, we first assembled a crystalline metal-organic framework (MOF) precursor based on Zr(IV) ions and a linear dicarboxyl linker molecule featuring backfolded, highly unsaturated alkyne backbones; massive thermocyclization of the organic linkers was then triggered to install highly conjugated, fused-aromatic bridges throughout the MOF scaffold while preserving the crystalline order. The formation of cyclized carbon links not only greatly strengthen the precursor coordination scaffold, but more importantly, enhance electroactivity and charge transport throughout the polycyclic aromatic grid.

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