Mass spectrometric and electron impact study of the spatial separation of mixtures of butane and argon in a pulsed supersonic jet

1997 ◽  
Vol 93 (17) ◽  
pp. 3005-3012 ◽  
Author(s):  
Alexander Malakhovskii ◽  
Aharon Gedanken
1962 ◽  
Vol 40 (9) ◽  
pp. 1730-1737 ◽  
Author(s):  
A. G. Harrison ◽  
T. W. Shannon

The appearance potential of the CH2Cl+ ion has been measured from methyl chloride, dichloromethane, bromochloromethane, and ethyl chloride. The results lead to ΔHf(CH2Cl+) = 230 ± 3 kcal/mole. The heat of formation of CHCl2+ is estimated to be 215 ± 3 kcal/mole from the appearance potential of this ion in the mass spectrum of chloroform and of bromodichloromethane. By the indirect mass spectrometric method ΔHf(CH2Cl) = 29 ± 3 kcal/mole and ΔHf(CHCl2) = 15 ± 3 kcal/mole are obtained. The ionization potentials of a number of chlorine-containing compounds have been measured.


1987 ◽  
Vol 22 (2) ◽  
pp. 109-111
Author(s):  
Henryk J. Bartoń ◽  
Jerzy L. Mokrosz ◽  
Maria H. Paluchowska ◽  
Jacek T. Bojarski
Keyword(s):  

2011 ◽  
Vol 115 (44) ◽  
pp. 12380-12389 ◽  
Author(s):  
Georges Brügger ◽  
Hans-Martin Frey ◽  
Patrick Steinegger ◽  
Philipp Kowalewski ◽  
Samuel Leutwyler

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