Nanostructures in ionic liquids: correlation of iridium nanoparticles’ size and shape with imidazolium salts’ structural organization and catalytic properties

2010 ◽  
Vol 12 (25) ◽  
pp. 6826 ◽  
Author(s):  
Pedro Migowski ◽  
Daniela Zanchet ◽  
Giovanna Machado ◽  
Marcos A. Gelesky ◽  
Sérgio R. Teixeira ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Structural Organization ◽  
Catalytic Properties ◽  
Imidazolium Salts ◽  
Size And Shape ◽  
Iridium Nanoparticles

Probing the microscopic structural organization of neat ionic liquids (ILs) and ionic liquid-based gels through resonance energy transfer (RET) studies

2017 ◽  
Vol 19 (34) ◽  
pp. 23194-23203 ◽  
Author(s):  
Debashis Majhi ◽  
Moloy Sarkar
Keyword(s):  
Ionic Liquid ◽  
Energy Transfer ◽  
Ionic Liquids ◽  
Structural Organization ◽  
Rhodamine 6G ◽  
Resonance Energy Transfer ◽  
Resonance Energy

With the aim to understand the role of the ionic constituents of ionic liquids (ILs) in their structural organization, resonance energy transfer (RET) studies between ionic liquids (donor) and rhodamine 6G (acceptor) have been investigated.

Tetracarboxyl-Functionalized Ionic Liquid: Synthesis and Catalytic Properties

2015 ◽  
Vol 68 (10) ◽  
pp. 1513 ◽  
Author(s):  
Miaona Feng ◽  
Guoying Zhao ◽  
Hongling Gao ◽  
Suojiang Zhang
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Propionic Acid ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
High Stability ◽  
Ammonium Acetate ◽  
Catalytic Properties ◽  
Potential Applications

Novel tetracarboxyl-functionalized 2,2′-biimidazolium-based ionic liquids (ILs) with different anions were synthesized in two steps from readily available and sustainable starting materials including ammonium acetate, glyoxal, and halogenated propionic acid. The functionalized IL exhibited higher catalytic activity towards the cycloaddition of CO2 to terminal epoxides. With propylene oxide as a substrate, the optimum yield of propylene carbonate reached 82.7 % at an initial CO2 pressure of 2.0 MPa for 4 h at 140°C. Moreover, the functionalized IL catalyst displayed a high stability and can be reused for at least five cycles without obvious loss of catalytic activity. The results provide a simple and economical way to synthesize multi-functionalized imidazolium-based ILs with versatile potential applications.

Synthesis and structural organization of ruthenium(IV) cluster Li8Ru2OCl14 and its catalytic properties in the water oxidation reaction

2016 ◽  
Vol 61 (6) ◽  
pp. 688-694 ◽  
Author(s):  
Z. M. Dzhabieva ◽  
G. V. Shilov ◽  
V. Yu. Tkachenko ◽  
L. V. Avdeeva ◽  
T. S. Dzhabiev
Keyword(s):  
Water Oxidation ◽  
Oxidation Reaction ◽  
Structural Organization ◽  
Catalytic Properties

A High-Pressure Study of the Effects of TiO2 Nanoparticles on the Structural Organization of Ionic Liquids

2011 ◽  
Vol 115 (48) ◽  
pp. 23778-23783 ◽  
Author(s):  
Hai-Chou Chang ◽  
Shu-Chieh Chang ◽  
Tzu-Chieh Hung ◽  
Jyh-Chiang Jiang ◽  
Jer-Lai Kuo ◽  
...  
Keyword(s):  
High Pressure ◽  
Ionic Liquids ◽  
Tio2 Nanoparticles ◽  
Structural Organization ◽  
High Pressure Study
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