A simple kinetic spectrophotometric method for simultaneous determination of tetracyclines by use of chemometrics

2010 ◽  
Vol 2 (9) ◽  
pp. 1302 ◽  
Author(s):  
Yongnian Ni ◽  
Na Deng ◽  
Serge Kokot
2011 ◽  
Vol 410 (2) ◽  
pp. 289-295 ◽  
Author(s):  
Masoud Rohani Moghadam ◽  
Shayessteh Dadfarnia ◽  
Ali Mohammad Haji Shabani ◽  
Parviz Shahbazikhah

2012 ◽  
Vol 77 (3) ◽  
pp. 349-361 ◽  
Author(s):  
Abdolhossein Naseri ◽  
Shokoofeh Malakzadeh-Rousta

In this paper, a new and very simple kinetic - spectrophotometric method is developed for the simultaneous determination of binary mixtures without prior separational steps. The method is based on the calculation of the variation of ratio kinetic profiles. The mathematical explanation of the procedure is also illustrated. The proposed method can be used for simultaneous determination of two analytes A and B that react with the same reagent to give the same absorbing species. In order to evaluate the applicability of the method, a model data as well as an experimental data were tested. The results from experimental data relating to the simultaneous spectrophotometric determination of Co (II) and V (IV) based on their oxidation reactions with Fe (III) in the presence 1, 10- Phenanthroline (Phen) in micellar media were presented as a real model for resolution of the binary systems. The applicability of the method in tap water and synthesized alloy samples was also assessed by spiking experiments with different amount of Co (II) and V (IV).


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