The poisoning effects of alkali metals (K and Na) and alkaline earth metals (Ca and Mg) on catalytic performance of the 2Nb4Ce/Zr-PILC catalyst for the selective catalytic reduction of NOx with NH3 (NH3-SCR) were investigated, and physicochemical properties of the catalysts were characterized by means of the X-ray diffraction XRD (XRD), Brunner−Emmet−Teller (BET), hydrogen temperature-programmed reduction (H2-TPR), X-ray Photoelectron Spectroscopy (XPS), ammonia temperature-programmed desorption (NH3-TPD), and in situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS) techniques. Doping of M (M = K, Na, Ca, and Mg) deactivated the 2Nb4Ce/Zr-PILC catalyst according to the sequence of 0.8 K > 0.8 Na > 0.8 Ca > 0.8 Mg (M/Ce molar ratio = 0.8). The characterization results showed that the decreases in redox ability, NH3 adsorption, Ce3+/Ce4+ atomic ratio, and amount of the chemisorbed oxygen (Oβ) were the important factors influencing catalytic activities of the alkali metal-and alkaline earth metal-doped samples. Consequently, compared with the Mg- and Ca-doped samples, doping of K caused the 2Nb4Ce/Zr-PILC sample to possess the lowest redox ability, NH3 adsorption, and amount of the Oβ species, which resulted in an obvious deactivation effect.
Poisoning Effects of Alkali and Alkaline Earth Metal Doping on Selective Catalytic Reduction of NO with NH3 over the Nb-Ce/Zr-PILC Catalysts
