Asymmetric catalytic epoxidation of α,β-unsaturated carbonyl compounds with hydrogen peroxide: Additive-free and wide substrate scope

2012 ◽  
Vol 3 (6) ◽  
pp. 1996 ◽  
Author(s):  
Yangyang Chu ◽  
Xiaohua Liu ◽  
Wei Li ◽  
Xiaolei Hu ◽  
Lili Lin ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Carbonyl Compounds ◽  
Asymmetric Catalytic ◽  
Catalytic Epoxidation

Trapping of a Highly Reactive Oxoiron(IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide

2019 ◽  
Vol 131 (12) ◽  
pp. 4052-4056 ◽  
Author(s):  
Xenia Engelmann ◽  
Deesha D. Malik ◽  
Teresa Corona ◽  
Katrin Warm ◽  
Erik R. Farquhar ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Epoxidation ◽  
Epoxidation Of Olefins

scholarly journals Highly efficient epoxidation of vegetable oils catalyzed by a manganese complex with hydrogen peroxide and acetic acid

2019 ◽  
Vol 21 (9) ◽  
pp. 2436-2447 ◽  
Author(s):  
Jianming Chen ◽  
Marc de Liedekerke Beaufort ◽  
Lucas Gyurik ◽  
Joren Dorresteijn ◽  
Matthias Otte ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Acetic Acid ◽  
Vegetable Oils ◽  
Manganese Complex ◽  
Mild Conditions ◽  
Highly Efficient ◽  
Catalytic Epoxidation

A highly efficient catalytic epoxidation of vegetable oils under mild conditions was developed, using a homogeneous Mn catalyst and H2O2 as oxidant.

Baeyer-Villiger Oxidation of β-Aryl Substituted Unsaturated Carbonyl Compounds with Hydrogen Peroxide and Catalytic Selenium Dioxide

1995 ◽  
Vol 25 (14) ◽  
pp. 2121-2133 ◽  
Author(s):  
J. A. Guzmán ◽  
V. Mendoza ◽  
E. García ◽  
C. F. Garibay ◽  
L. Z. Olivares ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Carbonyl Compounds ◽  
Selenium Dioxide ◽  
Villiger Oxidation

scholarly journals P450BM3-Catalyzed Oxidations Employing Dual Functional Small Molecules

Catalysts ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 567 ◽  
Author(s):  
Willot ◽  
Tieves ◽  
Girhard ◽  
Urlacher ◽  
Hollmann ◽  
...  
Keyword(s):  
Amino Acids ◽  
Hydrogen Peroxide ◽  
Cytochrome P450 ◽  
Small Molecules ◽  
Bacillus Megaterium ◽  
Cytochrome P450 Monooxygenase ◽  
Oxidation Reactions ◽  
P450 Monooxygenase ◽  
Dual Functional ◽  
Catalytic Epoxidation

A set of dual functional small molecules (DFSMs) containing different amino acids has been synthesized and employed together with three different variants of the cytochrome P450 monooxygenase P450BM3 from Bacillus megaterium in H2O2-dependent oxidation reactions. These DFSMs enhance P450BM3 activity with hydrogen peroxide as an oxidant, converting these enzymes into formal peroxygenases. This system has been employed for the catalytic epoxidation of styrene and in the sulfoxidation of thioanisole. Various P450BM3 variants have been evaluated in terms of activity and selectivity of the peroxygenase reactions.

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