ChemInform Abstract: Asymmetric Catalytic Reduction of Carbonyl Compounds Using C2 Symmetric Diamines as Chiral Ligands.

ChemInform ◽  
2010 ◽  
Vol 26 (38) ◽  
pp. no-no
Author(s):  
P. GAMEZ ◽  
F. FACHE ◽  
M. LEMAIRE
Keyword(s):  
Carbonyl Compounds ◽  
Catalytic Reduction ◽  
Chiral Ligands ◽  
Asymmetric Catalytic

Asymmetric catalytic epoxidation of α,β-unsaturated carbonyl compounds with hydrogen peroxide: Additive-free and wide substrate scope

2012 ◽  
Vol 3 (6) ◽  
pp. 1996 ◽  
Author(s):  
Yangyang Chu ◽  
Xiaohua Liu ◽  
Wei Li ◽  
Xiaolei Hu ◽  
Lili Lin ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Carbonyl Compounds ◽  
Asymmetric Catalytic ◽  
Catalytic Epoxidation

A Metal-free Catalytic Reduction of α,β-unsaturated Carbonyl Compounds with Phenyldimethylsilane

2005 ◽  
Vol 2005 (7) ◽  
pp. 469-470 ◽  
Author(s):  
Ruizhu Mu ◽  
Zhengang Liu ◽  
Zhongquan Liu ◽  
Li Yang ◽  
Longmin Wu ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Carbonyl Compounds ◽  
Catalytic Reduction ◽  
Selective Reduction ◽  
Catalytic Amount ◽  
Metal Free

Selective reduction of α,β-unsaturated carbonyl compounds to the corresponding saturated ones by phenyldimethyl silane was promoted by a catalytic amount of I2O5 at ambient temperature in CH2Cl2.

ChemInform Abstract: Asymmetric Catalytic Reduction of meso-Imides.

ChemInform ◽  
2010 ◽  
Vol 26 (40) ◽  
pp. no-no
Author(s):  
J. KANG ◽  
J. W. LEE ◽  
J. I. KIM ◽  
C. PYUN
Keyword(s):  
Catalytic Reduction ◽  
Asymmetric Catalytic

Chiral Catalysts Utilized in the Nucleophilic Addition of Dialkyl-zinc Reagents to Carbonyl Compounds

2020 ◽  
Vol 17 (8) ◽  
pp. 571-585
Author(s):  
Adnan Cetin
Keyword(s):  
Carbonyl Compounds ◽  
Nucleophilic Addition ◽  
Bond Formation ◽  
Research Topic ◽  
Chiral Ligands ◽  
Addition Reactions ◽  
Chiral Catalyst ◽  
Carbon Carbon Bond ◽  
Drug Synthesis ◽  
Active Research

The aim of this review is an overview of diverse dialkyl zinc pro-chiral aldehydes addition reactions. One way of conducting asymmetric reactions is through the use of chiral catalyst. Therefore, new chiral ligands have attracted considerable attention in organic chemistry. Carbon-carbon bond formation reactions are an active research topic. The addition of dialkyl zinc to pro-chiral aldehydes is one of these popular reactions. Also, the chiral amino alcohols are important substrates for drug synthesis. These chiral ligands can be prepared by a simple synthetic way from easily accessible starting materials. This article reviews current catalyst reactions with the addition of dialkyl zinc to carbonyl compounds.

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