An enantioselective synthesis of the C24–C40 fragment of (−)-pulvomycin
Keyword(s):
The C24–C40 fragment of (−)-pulvomycin was prepared in enantiomerically pure form using a concise synthesis method (15 linear steps from d-fucose, 6.8% overall yield) featuring a diastereoselective addition to an aldehyde, a β-selective glycosylation and a Stille cross-coupling as the key steps.
2019 ◽
2019 ◽
Vol 16
(12)
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pp. 931-934
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Keyword(s):
Keyword(s):
2008 ◽
Vol 19
(12)
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pp. 1425-1429
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2015 ◽
Vol 21
(20)
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pp. 7379-7383
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