Hierarchical porous metal–organic framework monoliths

2014 ◽  
Vol 50 (92) ◽  
pp. 14314-14316 ◽  
Author(s):  
Adham Ahmed ◽  
Mark Forster ◽  
Rob Clowes ◽  
Peter Myers ◽  
Haifei Zhang
Keyword(s):  
Monolithic Column ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Hplc Separation ◽  
Powder Packing ◽  
Hierarchical Porous ◽  
Metal Organic ◽  
Organic Framework

A simple powder-packing synthesis is developed to produce crystalline MOF monoliths containing micropores and highly interconnected macropores. Fast HPLC separation using the monolithic column is demonstrated.

Enhanced catalytic activity of a hierarchical porous metal–organic framework CuBTC

CrystEngComm ◽  
2015 ◽  
Vol 17 (37) ◽  
pp. 7124-7129 ◽  
Author(s):  
Zhigang Hu ◽  
Yongwu Peng ◽  
Kai Min Tan ◽  
Dan Zhao
Keyword(s):  
Catalytic Activity ◽  
Pore Size ◽  
Lewis Acid ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Acid Catalyst ◽  
Hierarchical Porous ◽  
Metal Organic ◽  
Lewis Acid Catalyst ◽  
Organic Framework

A hierarchical porous metal–organic framework CuBTC with mesopores of 3.9 nm pore size has been facilely obtained as Lewis acid catalyst.

Multifunctionality in an Ion-Exchanged Porous Metal–Organic Framework

2021 ◽  
Vol 143 (3) ◽  
pp. 1365-1376
Author(s):  
Sérgio M. F. Vilela ◽  
Jorge A. R. Navarro ◽  
Paula Barbosa ◽  
Ricardo F. Mendes ◽  
Germán Pérez-Sánchez ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Unusual pore structure and sorption behaviour in a hexanodal zinc–organic framework material

2014 ◽  
Vol 50 (14) ◽  
pp. 1678-1681 ◽  
Author(s):  
Jinjie Qian ◽  
Feilong Jiang ◽  
Linjie Zhang ◽  
Kongzhao Su ◽  
Jie Pan ◽  
...  
Keyword(s):  
Pore Structure ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Sorption Behaviour ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework structurally consists of three topological kinds of 3-connected 1,3,5-benzenetricarboxylate ligands, Zn2(COO)4, Zn3O(COO)6 and Zn4O(COO)6 SBUs, featuring a new 3,3,3,4,4,6-c hexanodal topology.

High-Throughput Aided Synthesis of the Porous Metal−Organic Framework-Type Aluminum Pyromellitate, MIL-121, with Extra Carboxylic Acid Functionalization

2010 ◽  
Vol 49 (21) ◽  
pp. 9852-9862 ◽  
Author(s):  
Christophe Volkringer ◽  
Thierry Loiseau ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Mohamed Haouas ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
High Throughput ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Hierarchical Porous Metal-Organic Framework Materials for Efficient Oil-Water Separation

2022 ◽  
Author(s):  
HANEESH SAINI ◽  
Eva Otyepková ◽  
Andreas Schneemann ◽  
Radek Zboril ◽  
Michal Otyepka ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Water Separation ◽  
Framework Materials ◽  
Quality Of Water ◽  
Global Issue ◽  
Hierarchical Porous ◽  
Oil Water Separation ◽  
Metal Organic

Oil contaminated water is a global issue, decreasing the quality of water sources and is posing a threat to the health of humans and many ecosystems. The utilization of industrial...

A Solar Assistant Dehumidifier Based on Porous Metal-Organic Framework

2021 ◽  
Vol 896 ◽  
pp. 13-20
Author(s):  
Xiao Yu Wen
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Modern Architecture ◽  
Activated Alumina ◽  
Additional Energy ◽  
Humidity Control ◽  
Energy Inputs ◽  
Metal Organic ◽  
High Regeneration ◽  
Organic Framework

As an important factor to measure environmental comfort, humidity control is very important. However, previous dehumidification methods have many defects, such as condensation and adsorbents, which often require a lot of energy. The growing requirements of an indoor environment can stem from the development of living levels and technology. Humidity, as an important factor to measure environmental comfort, affects living and production, and indoor humidity control is an indispensable part of modern architecture. However, there are many defects in the previous dehumidification methods, such as condensation dehumidification, which often requires a lot of energy. Traditional adsorbents (such as zeolite silica and activated alumina) have problems with fragile structures or high regeneration temperatures. In this paper, an indoor dehumidification device based on the porous metal-organic framework {MOF-801, Zr6O4(OH)4(Fumarate)6}, can realize the indoor dehumidification process only by using a small amount of solar energy (1 kilowatt per square meter). The device is expected to remove 0.2113 kg/h of moisture per square meter MOF-801, only needs a few additional energy inputs.

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