A nitro-decorated NbO-type metal–organic framework with a highly selective CO2 uptake and CH4 storage capacity

CrystEngComm ◽  
2014 ◽  
Vol 16 (28) ◽  
pp. 6287-6290 ◽  
Author(s):  
Mingxing Zhang ◽  
Qian Wang ◽  
Zhiyong Lu ◽  
Huiyan Liu ◽  
Wenlong Liu ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Co2 Uptake ◽  
Adsorption Selectivity ◽  
Total Uptake ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework ◽  
Ch4 Storage

A nitro-decorated and highly porous metal–organic framework with NbO topology was reported, exhibiting good adsorption selectivity of CO2/CH4 (8) and CO2/N2 (24) at 273 K and 1 bar, high methane total uptake of 184 cm3 cm−3 at 290 K and 35 bar.

Unusual pore structure and sorption behaviour in a hexanodal zinc–organic framework material

2014 ◽  
Vol 50 (14) ◽  
pp. 1678-1681 ◽  
Author(s):  
Jinjie Qian ◽  
Feilong Jiang ◽  
Linjie Zhang ◽  
Kongzhao Su ◽  
Jie Pan ◽  
...  
Keyword(s):  
Pore Structure ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Sorption Behaviour ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework structurally consists of three topological kinds of 3-connected 1,3,5-benzenetricarboxylate ligands, Zn2(COO)4, Zn3O(COO)6 and Zn4O(COO)6 SBUs, featuring a new 3,3,3,4,4,6-c hexanodal topology.

A Highly Porous Metal–Organic Framework: Structural Transformations of a Guest‐Free MOF Depending on Activation Method and Temperature

2011 ◽  
Vol 17 (26) ◽  
pp. 7251-7260 ◽  
Author(s):  
Hye Jeong Park ◽  
Dae‐Woon Lim ◽  
Woo Seung Yang ◽  
Tae‐Rog Oh ◽  
Myunghyun Paik Suh
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Structural Transformations ◽  
Activation Method ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

Quantum Rotations and Chiral Polarization of Qubit Prototype Molecules in a Highly Porous Metal–Organic Framework: 1H NMR T1 Study

2011 ◽  
Vol 115 (42) ◽  
pp. 20460-20465 ◽  
Author(s):  
Svyatoslav P. Gabuda ◽  
Svetlana G. Kozlova ◽  
Denis G. Samsonenko ◽  
Danil N. Dybtsev ◽  
Vladimir P. Fedin
Keyword(s):  
1H Nmr ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
1H Nmr T1 ◽  
Highly Porous ◽  
Organic Framework

Highly porous metal–organic framework sustained with 12-connected nanoscopic octahedra

2013 ◽  
Vol 42 (5) ◽  
pp. 1708-1714 ◽  
Author(s):  
Weigang Lu ◽  
Daqiang Yuan ◽  
Trevor A. Makal ◽  
Zhangwen Wei ◽  
Jian-Rong Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

Removal of gaseous benzene by a fixed-bed system packed with a highly porous metal-organic framework (MOF-199) coated glass beads

2022 ◽  
pp. 112655
Author(s):  
Bhaskar Anand ◽  
Ki-Hyun Kim ◽  
Ravi Kumar Sonwani ◽  
Jan E. Szulejko ◽  
Philippe M. Heynderickx
Keyword(s):  
Metal Organic Framework ◽  
Fixed Bed ◽  
Porous Metal ◽  
Glass Beads ◽  
Coated Glass ◽  
Metal Organic ◽  
Highly Porous ◽  
Gaseous Benzene ◽  
Fixed Bed System ◽  
Organic Framework

Self-assembled multifunctional core–shell highly porous metal–organic framework nanoparticles

2020 ◽  
Vol 581 ◽  
pp. 119281
Author(s):  
Jingwen Qiu ◽  
Xue Li ◽  
Karine Steenkeste ◽  
Nadine Barroca-Aubry ◽  
Caroline Aymes-Chodur ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Core Shell ◽  
Metal Organic ◽  
Self Assembled ◽  
Highly Porous ◽  
Organic Framework

A metal–organic framework functionalized with piperazine exhibiting enhanced CH4 storage

2017 ◽  
Vol 5 (1) ◽  
pp. 349-354 ◽  
Author(s):  
Mingxing Zhang ◽  
Cong Chen ◽  
Qian Wang ◽  
Wensheng Fu ◽  
Kunlin Huang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic ◽  
Organic Framework ◽  
Ch4 Storage

NJU-Bai 19, the first cycloaliphatic ring (piperazine) functionalized MOF-505 analogue, exhibits a notably high methane storage capacity of 246 cm3 (STP) cm−3 (at room temperature and 65 bar) and a working capacity of 185 cm3 (STP) cm−3.

Direct synthesis of N-sulfenylimines through oxidative coupling of amines with disulfides/thiols over copper based metal–organic frameworks

RSC Advances ◽  
2016 ◽  
Vol 6 (47) ◽  
pp. 40945-40952 ◽  
Author(s):  
Wei Long ◽  
Wenge Qiu ◽  
Chuanqiang Li ◽  
Liyun Song ◽  
Guangmei Bai ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Metal Organic Framework ◽  
Direct Synthesis ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Building Blocks ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework based on supramolecular building blocks with pcu-topology has been tested for the oxidative coupling of amines and disulfides to afford the N-sulfenylimines directly in good yields.

Highly Porous Metal-Organic Framework Containing a Novel Organosilicon Linker − A Promising Material for Hydrogen Storage

2009 ◽  
Vol 48 (14) ◽  
pp. 6559-6565 ◽  
Author(s):  
Stephanie E. Wenzel ◽  
Michael Fischer ◽  
Frank Hoffmann ◽  
Michael Fröba
Keyword(s):  
Hydrogen Storage ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Promising Material ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

Open metal site (OMS) and Lewis basic site (LBS)-functionalized copper–organic framework with high CO2 uptake performance and highly selective CO2/N2 and CO2/CH4 separation

CrystEngComm ◽  
2020 ◽  
Vol 22 (19) ◽  
pp. 3378-3384 ◽  
Author(s):  
Cheng He ◽  
Chao Hou ◽  
Yu Min Wang ◽  
Xue Yong Gong ◽  
Hong Li Jiang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Basic Site ◽  
Co2 Uptake ◽  
High Co2 ◽  
Metal Site ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Excellent Selectivity ◽  
Organic Framework

A robust porous metal–organic framework with dual functionalities of open metal sites (OMSs) and O-rich Lewis basic sites (LBSs) has been designed and synthesized, and shows high CO2 uptake and excellent selectivity for CO2 over N2 and CH4.

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