Open metal site (OMS) and Lewis basic site (LBS)-functionalized copper–organic framework with high CO2 uptake performance and highly selective CO2/N2 and CO2/CH4 separation

CrystEngComm ◽  
2020 ◽  
Vol 22 (19) ◽  
pp. 3378-3384 ◽  
Author(s):  
Cheng He ◽  
Chao Hou ◽  
Yu Min Wang ◽  
Xue Yong Gong ◽  
Hong Li Jiang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Basic Site ◽  
Co2 Uptake ◽  
High Co2 ◽  
Metal Site ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Excellent Selectivity ◽  
Organic Framework

A robust porous metal–organic framework with dual functionalities of open metal sites (OMSs) and O-rich Lewis basic sites (LBSs) has been designed and synthesized, and shows high CO2 uptake and excellent selectivity for CO2 over N2 and CH4.

Heterometallic In(III)–Pd(II) Porous Metal–Organic Framework with Square-Octahedron Topology Displaying High CO2 Uptake and Selectivity toward CH4 and N2

2018 ◽  
Vol 57 (12) ◽  
pp. 7244-7251 ◽  
Author(s):  
Ioannis Bratsos ◽  
Christos Tampaxis ◽  
Ioannis Spanopoulos ◽  
Nicola Demitri ◽  
Georgia Charalambopoulou ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Co2 Uptake ◽  
High Co2 ◽  
Metal Organic ◽  
Organic Framework

A nitro-decorated NbO-type metal–organic framework with a highly selective CO2 uptake and CH4 storage capacity

CrystEngComm ◽  
2014 ◽  
Vol 16 (28) ◽  
pp. 6287-6290 ◽  
Author(s):  
Mingxing Zhang ◽  
Qian Wang ◽  
Zhiyong Lu ◽  
Huiyan Liu ◽  
Wenlong Liu ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Co2 Uptake ◽  
Adsorption Selectivity ◽  
Total Uptake ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework ◽  
Ch4 Storage

A nitro-decorated and highly porous metal–organic framework with NbO topology was reported, exhibiting good adsorption selectivity of CO2/CH4 (8) and CO2/N2 (24) at 273 K and 1 bar, high methane total uptake of 184 cm3 cm−3 at 290 K and 35 bar.

A 3D Porous Metal Organic Framework Based on Infinite 1D Nickel(II) Chains with Rutile Topology Displaying Open Metal Sites

2014 ◽  
Vol 640 (11) ◽  
pp. 2123-2131 ◽  
Author(s):  
Kyriakos C. Stylianou ◽  
John Bacsa ◽  
Darren Bradshaw ◽  
Matthew J. Rosseinsky
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

Porous metal–organic framework based on a macrocyclic tetracarboxylate ligand exhibiting selective CO2 uptake

CrystEngComm ◽  
2012 ◽  
Vol 14 (19) ◽  
pp. 6115 ◽  
Author(s):  
Wen-Yang Gao ◽  
Youhong Niu ◽  
Yao Chen ◽  
Lukasz Wojtas ◽  
Jianfeng Cai ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Co2 Uptake ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Stabilized open metal sites in bimetallic metal–organic framework catalysts for hydrogen production from alcohols

2021 ◽  
Author(s):  
Jonathan L. Snider ◽  
Ji Su ◽  
Pragya Verma ◽  
Farid El Gabaly ◽  
Joshua D. Sugar ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Metal Organic Framework ◽  
Metal Site ◽  
Highly Active ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Alcohol Dehydrogenation ◽  
Organic Framework

Bimetallic (NixMg1−x)-MOF-74 stabilizes Ni2+ open metal site relative to Ni-MOF-74, resulting in a highly active and selective alcohol dehydrogenation catalyst.

Integrating multiple adsorption sites and tortuous diffusion paths into a metal–organic framework for C3H4/C3H6 separation

2019 ◽  
Vol 7 (44) ◽  
pp. 25254-25257 ◽  
Author(s):  
Xue-Qian Wu ◽  
Yabo Xie ◽  
Jing-Hao Liu ◽  
Tao He ◽  
Yong-Zheng Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Adsorption ◽  
Adsorption Sites ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Diffusion Paths ◽  
High Adsorption Capacity ◽  
Multiple Adsorption ◽  
Excellent Selectivity ◽  
Organic Framework

By integrating open metal sites, Lewis basic sites, and tortuous diffusion paths, a new metal–organic framework has been designed and synthesized, which exhibits high adsorption capacity and excellent selectivity for separating a C3H4/C3H6 mixture.

High CO2 Uptake Capacity and Selectivity in a Fascinating Nanotube-Based Metal–Organic Framework

2016 ◽  
Vol 56 (2) ◽  
pp. 908-913 ◽  
Author(s):  
Yun-Long Wu ◽  
Jinjie Qian ◽  
Guo-Ping Yang ◽  
Fan Yang ◽  
Yu-Tong Liang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Co2 Uptake ◽  
Uptake Capacity ◽  
High Co2 ◽  
Metal Organic ◽  
Organic Framework

N-rich zeolite-like metal–organic framework with sodalite topology: high CO2 uptake, selective gas adsorption and efficient drug delivery

2012 ◽  
Vol 3 (6) ◽  
pp. 2114 ◽  
Author(s):  
Jun-Sheng Qin ◽  
Dong-Ying Du ◽  
Wen-Liang Li ◽  
Jing-Ping Zhang ◽  
Shun-Li Li ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Co2 Uptake ◽  
High Co2 ◽  
Metal Organic ◽  
Organic Framework

Channel Partition into Nanoscale Polyhedral Cages of a Triple-Self-Interpenetrated Metal–Organic Framework with High CO2 Uptake

2014 ◽  
Vol 54 (1) ◽  
pp. 10-12 ◽  
Author(s):  
Shuang-Qiu Chen ◽  
Quan-Guo Zhai ◽  
Shu-Ni Li ◽  
Yu-Cheng Jiang ◽  
Man-Cheng Hu
Keyword(s):  
Metal Organic Framework ◽  
Co2 Uptake ◽  
High Co2 ◽  
Metal Organic ◽  
Organic Framework
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