Rational design and synthesis of a series of 3D lanthanide metal–organic frameworks with different structures driven by reaction conditions

CrystEngComm ◽  
2014 ◽  
Vol 16 (44) ◽  
pp. 10181-10188 ◽  
Author(s):  
Tingting Zhao ◽  
Lirong Zhang ◽  
Dongmei Wang ◽  
Guanghua Li ◽  
Qisheng Huo ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Reaction Conditions ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Lanthanide Metal

A series of novel lanthanide metal–organic frameworks with three types of structures, moc, dia and a new topology, have been constructed and their luminescence properties were investigated.

Flexible luminescent non-lanthanide metal–organic frameworks as small molecules sensors

2021 ◽  
Author(s):  
Sajal Khatua ◽  
Chidharth Krishnaraj ◽  
Debendra Chandra Baruah ◽  
Pascal Van Der Voort ◽  
Himanshu Sekhar Jena
Keyword(s):  
Small Molecules ◽  
Small Molecule ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Flexible Structure ◽  
Metal Organic ◽  
Lanthanide Metal

Non-lanthanide metal–organic frameworks with flexible structure and luminescence properties are systematically discussed as potential small molecule sensors.

Rational design and synthesis of ultramicroporous metal-organic frameworks for gas separation

2020 ◽  
Vol 423 ◽  
pp. 213485 ◽  
Author(s):  
Ting Wang ◽  
En Lin ◽  
Yun-Lei Peng ◽  
Yao Chen ◽  
Peng Cheng ◽  
...  
Keyword(s):  
Gas Separation ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Design And Synthesis ◽  
Metal Organic

Rational Design and Control of the Dimensions of Channels in a Series of 3D Pillared Metal−Organic Frameworks: Synthesis, Structures, Adsorption, and Luminescence Properties

2008 ◽  
Vol 8 (2) ◽  
pp. 427-434 ◽  
Author(s):  
Ming Xue ◽  
Guangshan Zhu ◽  
Yujian Zhang ◽  
Qianrong Fang ◽  
Ian J. Hewitt ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Metal Organic ◽  
And Control

scholarly journals The effect of metal distribution on the luminescence properties of mixed-lanthanide metal–organic frameworks

2018 ◽  
Vol 47 (7) ◽  
pp. 2360-2367 ◽  
Author(s):  
Laura K. Cadman ◽  
Mary F. Mahon ◽  
Andrew D. Burrows
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Distribution ◽  
Luminescence Properties ◽  
Mixed Metal ◽  
Metal Organic ◽  
Lanthanide Metal

The MOFs [Ln(Hodip)(H2O)]·nH2O (H4odip = 5,5′-oxydiisophthalic acid) have been prepared together with mixed-metal analogues, and the distribution of the metal centres has been shown to affect the luminescence properties.

A Rational Design of Microporous Nitrogen-Rich Lanthanide Metal–Organic Frameworks for CO2/CH4 Separation

2020 ◽  
Vol 12 (45) ◽  
pp. 50619-50627
Author(s):  
Midhun Mohan ◽  
Mohamed Essalhi ◽  
David Durette ◽  
Love Karan Rana ◽  
Follivi Kloutse Ayevide ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Lanthanide Metal

Rational Design and Synthesis of Hexanuclear Rare Earth the-a Metal–Organic Frameworks Platform Based on RE6O4(OH)4(COO)8 Clusters

2019 ◽  
Vol 19 (3) ◽  
pp. 1509-1513 ◽  
Author(s):  
Yang Feng ◽  
Xuelian Xin ◽  
Yue Zhang ◽  
Bingbing Guo ◽  
Fugang Li ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Design And Synthesis ◽  
Metal Organic

scholarly journals Minimal edge-transitive nets for the design and construction of metal–organic frameworks

2017 ◽  
Vol 201 ◽  
pp. 127-143 ◽  
Author(s):  
Zhijie Chen ◽  
Hao Jiang ◽  
Michael O’Keeffe ◽  
Mohamed Eddaoudi
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Hexagonal Prism ◽  
Design And Synthesis ◽  
Building Unit ◽  
Molecular Building Blocks ◽  
Metal Organic ◽  
Edge Transitive ◽  
Design And Construction

Highly-connected and minimal edge-transitive nets (with one or two kinds of edge) can be regarded as ideal blueprints for the rational design and construction of metal–organic frameworks (MOFs). Here we report and affirm the prominence of highly-connected nets as suitable targets in reticular chemistry for the design and synthesis of MOFs. Of special interest are augmented highly-connected binodal edge-transitive nets embedding a unique and precise positioning and connectivity of the net vertex figures, regarded as net-coded building units (net-cBUs). Explicitly, a definitenet-cBU encompasses precise geometrical information that codes a selected net uniquely and matchlessly, a compelling perquisite for the rational design of MOFs. Interestingly, the double six-membered ring (d6R) building unit offers great potential to be used as anet-cBU for the deliberate reticulation of the sole two edge-transitive nets with a vertex figure as a d6R, namely the (4,12)-coordinatedshpnet (square and hexagonal prism) and the (6,12)-coordinatedalbnet (aluminium diboride, hexagonal prism and trigonal prism). We envisioned and proposed various MOF structures based on the derivedshpandalbnets. Gaining access to the requisitenet-cBUs is essential for the successful practice of reticular chemistry; correspondingly organic and inorganic chemistries were deployed to afford concomitant molecular building blocks (MBBs) with the looked-for shape and connectivity. Practically, the combination of the 12-connected (12-c) rare-earth (RE) polynuclear, points of extension matching the 12 vertices of the hexagonal prism (d6R) with a 4-connected tetracarboxylate ligand or a 6-connected hexacarboxylate ligand afforded the targetedshp-MOF oralb-MOF, respectively. A dodecacarboxylate ligand can be conceived as, and is shown to be, a compatible 12-c MBB, plausibly affording the positioning of the carbon centers of the twelve carboxylate groups on the vertices of the desired hexagonal prism building unit, and combined with the complementary 4-c copper paddlewheel [Cu2(O2C–)4] cluster or 6-c metal trinuclear [M3O(O2C–)6] clusters/zinc tetranulcear [Zn4O(O2C–)6] clusters to credibly afford the construction of new MOF structures with underlying topologies based on derivedshpandalbnets.

Luminescence properties of a family of lanthanide metal-organic frameworks

2019 ◽  
Vol 279 ◽  
pp. 400-406 ◽  
Author(s):  
Hani Nasser Abdelhamid ◽  
Magdalena Wilk-Kozubek ◽  
Ahmed M. El-Zohry ◽  
Antonio Bermejo Gómez ◽  
Alejandro Valiente ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Metal Organic ◽  
Lanthanide Metal
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