Rational Design and Synthesis of Hexanuclear Rare Earth the-a Metal–Organic Frameworks Platform Based on RE6O4(OH)4(COO)8 Clusters

2019 ◽  
Vol 19 (3) ◽  
pp. 1509-1513 ◽  
Author(s):  
Yang Feng ◽  
Xuelian Xin ◽  
Yue Zhang ◽  
Bingbing Guo ◽  
Fugang Li ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Design And Synthesis ◽  
Metal Organic

Rational design and synthesis of ultramicroporous metal-organic frameworks for gas separation

2020 ◽  
Vol 423 ◽  
pp. 213485 ◽  
Author(s):  
Ting Wang ◽  
En Lin ◽  
Yun-Lei Peng ◽  
Yao Chen ◽  
Peng Cheng ◽  
...  
Keyword(s):  
Gas Separation ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Design And Synthesis ◽  
Metal Organic

Rational design and synthesis of a series of 3D lanthanide metal–organic frameworks with different structures driven by reaction conditions

CrystEngComm ◽  
2014 ◽  
Vol 16 (44) ◽  
pp. 10181-10188 ◽  
Author(s):  
Tingting Zhao ◽  
Lirong Zhang ◽  
Dongmei Wang ◽  
Guanghua Li ◽  
Qisheng Huo ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Reaction Conditions ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Lanthanide Metal

A series of novel lanthanide metal–organic frameworks with three types of structures, moc, dia and a new topology, have been constructed and their luminescence properties were investigated.

scholarly journals Minimal edge-transitive nets for the design and construction of metal–organic frameworks

2017 ◽  
Vol 201 ◽  
pp. 127-143 ◽  
Author(s):  
Zhijie Chen ◽  
Hao Jiang ◽  
Michael O’Keeffe ◽  
Mohamed Eddaoudi
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Hexagonal Prism ◽  
Design And Synthesis ◽  
Building Unit ◽  
Molecular Building Blocks ◽  
Metal Organic ◽  
Edge Transitive ◽  
Design And Construction

Highly-connected and minimal edge-transitive nets (with one or two kinds of edge) can be regarded as ideal blueprints for the rational design and construction of metal–organic frameworks (MOFs). Here we report and affirm the prominence of highly-connected nets as suitable targets in reticular chemistry for the design and synthesis of MOFs. Of special interest are augmented highly-connected binodal edge-transitive nets embedding a unique and precise positioning and connectivity of the net vertex figures, regarded as net-coded building units (net-cBUs). Explicitly, a definitenet-cBU encompasses precise geometrical information that codes a selected net uniquely and matchlessly, a compelling perquisite for the rational design of MOFs. Interestingly, the double six-membered ring (d6R) building unit offers great potential to be used as anet-cBU for the deliberate reticulation of the sole two edge-transitive nets with a vertex figure as a d6R, namely the (4,12)-coordinatedshpnet (square and hexagonal prism) and the (6,12)-coordinatedalbnet (aluminium diboride, hexagonal prism and trigonal prism). We envisioned and proposed various MOF structures based on the derivedshpandalbnets. Gaining access to the requisitenet-cBUs is essential for the successful practice of reticular chemistry; correspondingly organic and inorganic chemistries were deployed to afford concomitant molecular building blocks (MBBs) with the looked-for shape and connectivity. Practically, the combination of the 12-connected (12-c) rare-earth (RE) polynuclear, points of extension matching the 12 vertices of the hexagonal prism (d6R) with a 4-connected tetracarboxylate ligand or a 6-connected hexacarboxylate ligand afforded the targetedshp-MOF oralb-MOF, respectively. A dodecacarboxylate ligand can be conceived as, and is shown to be, a compatible 12-c MBB, plausibly affording the positioning of the carbon centers of the twelve carboxylate groups on the vertices of the desired hexagonal prism building unit, and combined with the complementary 4-c copper paddlewheel [Cu2(O2C–)4] cluster or 6-c metal trinuclear [M3O(O2C–)6] clusters/zinc tetranulcear [Zn4O(O2C–)6] clusters to credibly afford the construction of new MOF structures with underlying topologies based on derivedshpandalbnets.

Phase selectivity and tunable photophysical nature of rare earth metal–organic frameworks of EuxY1−x-PTC (H3PTC = 2,4,6-pyridine tricarboxylic acid; x = 0–1)

2020 ◽  
Vol 49 (42) ◽  
pp. 14985-14994
Author(s):  
Xu-Sheng Gao ◽  
Mei-Juan Ding ◽  
Jin Zhang ◽  
Li-Duo Zhao ◽  
Xiao-Ming Ren
Keyword(s):  
Rare Earth ◽  
Solid Solutions ◽  
Rare Earth Metal ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Tricarboxylic Acid ◽  
Excitation Wavelength ◽  
Metal Organic ◽  
Phase Selectivity

All solid solutions (EuxY1−x-PTC, x = 0.013–0.82) are isomorphic to Eu-PTC, but different from Y-PTC, and show phase selectivity as well as excitation wavelength dependent emission.

scholarly journals Selective Crystallization of Rare‐Earth Ions into Cationic Metal‐Organic Frameworks for Rare‐Earth Separation

2021 ◽  
Author(s):  
Huajun Yang ◽  
Fang Peng ◽  
Danielle E. Schier ◽  
Stipe A. Markotic ◽  
Xiang Zhao ◽  
...  
Keyword(s):  
Rare Earth ◽  
Metal Organic Frameworks ◽  
Rare Earth Ions ◽  
Selective Crystallization ◽  
Metal Organic

Design and Synthesis of Conductive Metal‐Organic Frameworks and Their Composites for Supercapacitors

2021 ◽  
Author(s):  
Ting Yue ◽  
Chenfeng Xia ◽  
Xiaobang Liu ◽  
Zhitong Wang ◽  
Kai Qi ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Design And Synthesis ◽  
Metal Organic

Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu
Keyword(s):  
Building Block ◽  
High Stability ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Excellent Performance ◽  
Design And Synthesis ◽  
Molecular Building Block ◽  
Secondary Building Units ◽  
Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

Predictive Acid Gas Adsorption in Rare Earth DOBDC Metal–Organic Frameworks via Complementary Cluster and Periodic Structure Models

2020 ◽  
Vol 124 (49) ◽  
pp. 26801-26813
Author(s):  
Dayton J. Vogel ◽  
Zachary R. Lee ◽  
Caitlin A. Hanson ◽  
Susan E. Henkelis ◽  
Caris M. Smith ◽  
...  
Keyword(s):  
Rare Earth ◽  
Periodic Structure ◽  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Acid Gas ◽  
Metal Organic

Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks

2008 ◽  
Vol 130 (6) ◽  
pp. 1833-1835 ◽  
Author(s):  
Farid Nouar ◽  
Jarrod F. Eubank ◽  
Till Bousquet ◽  
Lukasz Wojtas ◽  
Michael J. Zaworotko ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Building Blocks ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Highly Porous

Rare‐Earth‐Based Metal–Organic Frameworks as Multifunctional Platforms for Catalytic Conversion

Small ◽  
2021 ◽  
pp. 2005371
Author(s):  
Xiaomeng Shi ◽  
Bo Cao ◽  
Jinghai Liu ◽  
Jun Zhang ◽  
Yaping Du
Keyword(s):  
Rare Earth ◽  
Metal Organic Frameworks ◽  
Catalytic Conversion ◽  
Metal Organic
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