Pressure effects on the radical–radical recombination reaction of photochromic bridged imidazole dimers

2014 ◽  
Vol 16 (33) ◽  
pp. 17537-17540 ◽  
Author(s):  
Katsuya Mutoh ◽  
Jiro Abe
Keyword(s):  
High Pressure ◽  
Pressure Effects ◽  
Recombination Reaction ◽  
Radical Recombination ◽  
Relationship Of ◽  
Radical Interaction

We revealed the structure–entropy relationship of the photochromism of bridged imidazole dimers and that the radical–radical interaction could be controlled by applying high pressure.

High-Pressure Effects in the Recombination Reaction CH3+ CH3→ C2H6

1984 ◽  
Vol 142 (1) ◽  
pp. 1-12 ◽  
Author(s):  
H. Hippler ◽  
K. Luther ◽  
A. R. Ravishankara ◽  
J. Troe
Keyword(s):  
High Pressure ◽  
Pressure Effects ◽  
Recombination Reaction ◽  
High Pressure Effects

High pressure effects on the multiplet structure of the emission spectrum of coronene in a n‐alkane matrix

1977 ◽  
Vol 66 (2) ◽  
pp. 875-876 ◽  
Author(s):  
M. Lamotte ◽  
S. Risemberg ◽  
A. M. Merle ◽  
J. Joussot‐Dubien
Keyword(s):  
High Pressure ◽  
Emission Spectrum ◽  
Pressure Effects ◽  
Multiplet Structure ◽  
High Pressure Effects

High Pressure effects on electrical resistivity and dielectric properties of nanocrystalline SnO2

2005 ◽  
Vol 66 (10) ◽  
pp. 1621-1627 ◽  
Author(s):  
P. Thangadurai ◽  
A. Chandra Bose ◽  
S. Ramasamy ◽  
R. Kesavamoorthy ◽  
T.R. Ravindran
Keyword(s):  
High Pressure ◽  
Electrical Resistivity ◽  
Dielectric Properties ◽  
Pressure Effects ◽  
High Pressure Effects

scholarly journals Crystal Growth and High-Pressure Effects of Bi-Based Superconducting Whiskers

ACS Omega ◽  
2021 ◽  
Author(s):  
Ryo Matsumoto ◽  
Sayaka Yamamoto ◽  
Yoshihiko Takano ◽  
Hiromi Tanaka
Keyword(s):  
High Pressure ◽  
Crystal Growth ◽  
Pressure Effects ◽  
High Pressure Effects

Interpretation of the high-pressure effects in the rare-earth orthoferrites

1975 ◽  
Vol 11 (7) ◽  
pp. 2705-2706 ◽  
Author(s):  
C. Boekema ◽  
F. van der Woude ◽  
G. A. Sawatzky
Keyword(s):  
High Pressure ◽  
Rare Earth ◽  
Pressure Effects ◽  
High Pressure Effects ◽  
The Rare Earth

High pressure effects on benzoic acid dimers: Vibrational spectroscopy

2014 ◽  
Vol 73 ◽  
pp. 138-143 ◽  
Author(s):  
Yuchuan Tao ◽  
Zbigniew A. Dreger ◽  
Yogendra M. Gupta
Keyword(s):  
High Pressure ◽  
Benzoic Acid ◽  
Vibrational Spectroscopy ◽  
Pressure Effects ◽  
High Pressure Effects

Pressure effect on hydrogen isotope exchange kinetics in chymotrypsinogen investigated by FT-IR spectroscopy

1991 ◽  
Vol 69 (11) ◽  
pp. 1699-1704 ◽  
Author(s):  
P. T. T. Wong
Keyword(s):  
High Pressure ◽  
Exchange Rate ◽  
Rate Constant ◽  
Bound Water ◽  
Pressure Effects ◽  
Protein Molecules ◽  
Fast Exchange ◽  
Exchange Rate Constant ◽  
Hydrogen Deuterium ◽  
Exchange Kinetics

Hydrogen/deuterium (H/D) exchange rate constants in chymotrypsinogen have been determined at several pressures up to 28.9 kbar by FTIR spectroscopy. The secondary structure of the protein molecules was monitored simultaneously at the corresponding pressures by the intensity redistribution of the infrared amide I band at these pressures. As in other proteins, the labile protons on the amide groups in chymotrypsinogen can, to a good approximation, be separated into two classes, each with distinct first order H/D exchange rates constants in the time period from 10 min to ~24 h. The fast exchange rate constant increases while the slow exchange rate constant decreases with increasing pressure. The increase in the fast exchange rate constant at high pressure is largely associated with the pressure-induced unfolding of the protein molecules. At extremely high pressure (12.8 kbar), in addition to the unfolding of protein molecules, pressure induced a distortion and weakening of the hydrogen bonds of the fold protein segments also contribute to an increase in the overall H/D exchange rate. The present results confirm that when chymotrypsinogen is dissolved in D2O, a considerable amount of D2O molecules is bound to the protein molecules on the surface as well as in the interior cavities of the molecules. The H/D exchange takes place between these bound D2O and the protons in the protein molecules. The mechanism of the H/D exchange and the interior dynamics in proteins are discussed on the basis of the present results. Key words: hydrogen/deuterium exchange, exchange kinetics, rate constant, pressure effects, infrared spectroscopy, protein, conformation structure, bound water.

High Pressure Effects on Protein Structure

1998 ◽  
pp. 59-86 ◽  
Author(s):  
Kenneth E. Prehoda ◽  
Ed S. Mooberry ◽  
John L. Markley
Keyword(s):  
High Pressure ◽  
Protein Structure ◽  
Pressure Effects ◽  
High Pressure Effects
Sign in / Sign up

Export Citation Format

Share Document