Supramolecular polymers constructed by orthogonal self-assembly based on host–guest and metal–ligand interactions

2015 ◽  
Vol 44 (3) ◽  
pp. 815-832 ◽  
Author(s):  
Peifa Wei ◽  
Xuzhou Yan ◽  
Feihe Huang
Keyword(s):  
Self Assembly ◽  
Recent Progress ◽  
Metal Coordination ◽  
Supramolecular Polymers ◽  
Ligand Interactions ◽  
Metal Ligand

This review describes recent progress in the orthogonal construction of supramolecular polymers based on host–guest and metal coordination interactions.

A dual-responsive cross-linked supramolecular polymer network gel: hierarchical supramolecular self-assembly driven by pillararene-based molecular recognition and metal–ligand interactions

2018 ◽  
Vol 9 (11) ◽  
pp. 1293-1297 ◽  
Author(s):  
Li Shao ◽  
Jie Yang ◽  
Bin Hua
Keyword(s):  
Molecular Recognition ◽  
Self Assembly ◽  
Polymer Network ◽  
Supramolecular Polymers ◽  
Supramolecular Polymer ◽  
Dual Responsive ◽  
Ligand Interactions ◽  
Metal Ligand

A novel 2,2′-bipyridine-bridged pillar[5]arene dimer was synthesized and further applied for constructing linear supramolecular polymers and supramolecular polymer network gels.

Recent Progress of Synergistic Supramolecular Polymers: Preparation, Properties and Applications

2020 ◽  
Author(s):  
Yufeng Huo ◽  
Zhenfeng He ◽  
Chao Wang ◽  
Lei Zhang ◽  
Qianyu Xuan ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Recent Progress ◽  
Noncovalent Interactions ◽  
The Self ◽  
Metal Coordination ◽  
Supramolecular Polymers ◽  
Π Stacking ◽  
Self Assembled

Supramolecular polymers combine the properties of traditional polymers and supramolecules. They are normally formed by the self-assembled polymerization driven via noncovalent interactions (such as hydrogen bonding, π-π stacking, metal coordination,...

Recent developments in the construction of metallacycle/metallacage-cored supramolecular polymers via hierarchical self-assembly

2019 ◽  
Vol 55 (56) ◽  
pp. 8036-8059 ◽  
Author(s):  
Bo Li ◽  
Tian He ◽  
Yiqi Fan ◽  
Xinchao Yuan ◽  
Huayu Qiu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Recent Progress ◽  
Supramolecular Polymers ◽  
Feature Article ◽  
Light Emitting ◽  
Recent Developments ◽  
Potential Applications ◽  
Bio Imaging

This feature article summarized the recent progress on the construction of metallacycle/metallacage-cored supramolecular polymers by the hierarchical self-assembly, and the potential applications in the areas of light emitting, sensing, bio-imaging, delivery and release, etc., are also presented.

A novel supramolecular system with multiple fluorescent states constructed by orthogonal self-assembly

2016 ◽  
Vol 7 (23) ◽  
pp. 3827-3831 ◽  
Author(s):  
Qingchen Dong ◽  
Wenshan Qu ◽  
Pi Wang ◽  
Wai-Yeung Wong
Keyword(s):  
Self Assembly ◽  
Supramolecular System ◽  
Ligand Interactions ◽  
Non Covalent Interactions ◽  
Covalent Interactions ◽  
Metal Ligand

A novel supramolecular fluorescent system was successfully constructed by orthogonal self-assembly of host–guest and metal–ligand interactions. By controlling the non-covalent interactions in different ways, the system exhibits diverse fluorescent switching phenomena.

scholarly journals Formation of Microcages from a Collagen Mimetic Peptide via Metal-Ligand Interactions

Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4888
Author(s):  
Jeremy Gleaton ◽  
Ryan W. Curtis ◽  
Jean Chmielewski
Keyword(s):  
Metal Ions ◽  
Self Assembly ◽  
Thermal Conditions ◽  
Time Dependent ◽  
Mechanistic Studies ◽  
Mimetic Peptide ◽  
Hierarchical Assembly ◽  
Ligand Interactions ◽  
Triple Helices ◽  
Metal Ligand

Here, the hierarchical assembly of a collagen mimetic peptide (CMP) displaying four bipyridine moieties is described. The CMP was capable of forming triple helices followed by self-assembly into disks and domes. Treatment of these disks and domes with metal ions such as Fe(II), Cu(II), Zn(II), Co(II), and Ru(III) triggered the formation of microcages, and micron-sized cup-like structures. Mechanistic studies suggest that the formation of the microcages proceeds from the disks and domes in a metal-dependent fashion. Fluorescently-labeled dextrans were encapsulated within the cages and displayed a time-dependent release using thermal conditions.

Two-Dimensional Self-Assembly of a Porphyrin-Polypyridyl Ruthenium(II) Hybrid on HOPG Surface through Metal-Ligand Interactions

ChemPhysChem ◽  
2010 ◽  
pp. NA-NA ◽  
Author(s):  
Aimei Gao ◽  
Xinrui Miao ◽  
Jie Liu ◽  
Ping Zhao ◽  
Jinwang Huang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Two Dimensional ◽  
Ligand Interactions ◽  
Metal Ligand

scholarly journals Reversible self-assembly of gels through metal-ligand interactions

2013 ◽  
Vol 3 (1) ◽  
Author(s):  
Yuichiro Kobayashi ◽  
Yoshinori Takashima ◽  
Akihito Hashidzume ◽  
Hiroyasu Yamaguchi ◽  
Akira Harada
Keyword(s):  
Self Assembly ◽  
Ligand Interactions ◽  
Metal Ligand

Using metal–ligand interactions to access biomimetic supramolecular polymers with adaptive and superb mechanical properties

2013 ◽  
Vol 1 (37) ◽  
pp. 4809 ◽  
Author(s):  
Jinchun Yuan ◽  
Huan Zhang ◽  
Guangning Hong ◽  
Yinjun Chen ◽  
Guohua Chen ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Supramolecular Polymers ◽  
Ligand Interactions ◽  
Metal Ligand

A novel supramolecular polymer gel constructed by crosslinking pillar[5]arene-based supramolecular polymers through metal–ligand interactions

2015 ◽  
Vol 51 (98) ◽  
pp. 17431-17434 ◽  
Author(s):  
Pi Wang ◽  
Hao Xing ◽  
Danyu Xia ◽  
Xiaofan Ji
Keyword(s):  
Supramolecular Polymers ◽  
Supramolecular Polymer ◽  
Polymer Gel ◽  
Ligand Interactions ◽  
Metal Ligand

A novel heteroditopic A–B monomer was synthesized and used to construct linear supramolecular polymers utilizing pillar[5]arene-based host–guest interactions. Upon addition of Cu2+ ions, a supramolecular polymer gel formed through metal–ligand interactions.

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