Switching and redox isomerism in first-row transition metal complexes containing redox active Schiff base ligands

2014 ◽  
Vol 43 (42) ◽  
pp. 15958-15967 ◽  
Author(s):  
Ashok Sasmal ◽  
Eugenio Garribba ◽  
Carlos J. Gómez-García ◽  
Cédric Desplanches ◽  
Samiran Mitra
Keyword(s):  
Electron Transfer ◽  
Schiff Base ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Schiff Base Ligands ◽  
Redox Active Ligands ◽  
Redox Active ◽  
Redox Isomerism

Switching and redox isomerism in first row transition metal complexes through the metal-to-ligand or ligand-to-ligand electron transfer stabilize redox isomeric forms in transition metal complexes with redox-active ligands.

Schiff base ligands and their transition metal complexes in the mixtures of ionic liquid + organic solvent: a thermodynamic study

2015 ◽  
Vol 17 (3) ◽  
pp. 2179-2191 ◽  
Author(s):  
Hemayat Shekaari ◽  
Amir Kazempour ◽  
Maryam Khoshalhan
Keyword(s):  
Ionic Liquid ◽  
Schiff Base ◽  
Transition Metal ◽  
Organic Solvent ◽  
Metal Complexes ◽  
Binary Mixtures ◽  
Transition Metal Complexes ◽  
Schiff Base Complex ◽  
Partial Molar Volumes ◽  
Schiff Base Ligands

Standard partial molar volumes (V0ϕ,IL) of the IL [HMIm]Cl in the binary mixtures of a Schiff base complex + DMF at T = 298.15 to 313.15 K.

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