Double thermoresponsive di- and triblock copolymers based on N-vinylcaprolactam and N-vinylpyrrolidone: synthesis and comparative study of solution behaviour

2014 ◽  
Vol 5 (22) ◽  
pp. 6534-6544 ◽  
Author(s):  
Anthony Kermagoret ◽  
Kevin Mathieu ◽  
Jean-Michel Thomassin ◽  
Charles-André Fustin ◽  
Roland Duchêne ◽  
...  
Keyword(s):  
Comparative Study ◽  
Radical Polymerization ◽  
Triblock Copolymers ◽  
Controlled Radical Polymerization ◽  
Thermally Induced ◽  
Solution Behaviour

Controlled radical polymerization produces poly(N-vinylamide)s with thermally induced multistep assembly.

Synthesis and thermal properties of triblock copolymers of methyl methacrylate using combination of anionic and controlled radical polymerization: Poly(methyl methacrylate) center block bearing different microstructures

e-Polymers ◽  
2012 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhengji Song ◽  
Carole Pelletier ◽  
Yinghua Qi ◽  
Jasim Ahmed ◽  
Sunil K. Varshney ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Thermal Properties ◽  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Triblock Copolymers ◽  
Controlled Radical Polymerization ◽  
Alkyl Methacrylate ◽  
Poly Methyl Methacrylate ◽  
H Nmr

AbstractABA and/or ABC type triblock copolymers were synthesized by living anionic and controlled radical polymerization in which poly(methyl methacrylate) was used as central block. The structural composition of these block copolymers were determined by 1H NMR. The block length/molecular weight and microstructure of these polymers were measured by SEC. The microstructure of resultant central alkyl methacrylate block can be tailored from highly syndiotactic to highly isotactic structure by varying the solvent and/or initiator. The thermal and rheological properties of center poly(methyl methacrylate) block and poly(styreneb- methyl methacrylate-b- styrene) tri block copolymers were studied in detail.

Synthesis and characterization of novel polysiloxane based ABA-type triblock copolymers using ATRP

e-Polymers ◽  
2013 ◽  
Vol 13 (1) ◽  
Author(s):  
Rajan B. Bodkhe ◽  
Dean C. Webster
Keyword(s):  
Radical Polymerization ◽  
Secondary Amine ◽  
Ring Opening ◽  
Triblock Copolymers ◽  
Gel Permeation Chromatography ◽  
Controlled Radical Polymerization ◽  
Synthesis And Characterization ◽  
Unique Material ◽  
Gel Permeation

Abstract Novel polysiloxane based ABA-type triblock copolymers having a secondary amine at the junction point were synthesized using a combination of ring opening equilibration polymerization (ROEP), Michael addition and atom transfer radical polymerization (ATRP). Polysiloxane based bifunctional ATRP macroinitiators were synthesized and subsequently used for controlled radical polymerization of t-butyl acrylate (t-BA) and sulfobetaine methacrylate (SBMA). Gel permeation chromatography (GPC) analysis of the triblocks based on t-BA showed high chain end functionality, due to the disappearance of peaks related to the macroinitiator. ROEP can be used to control the block length of the polysiloxane while ATRP can be used to control the chain length of the outer blocks, making the ABA- type triblock a unique material with secondary amine functionality which can be used for further reaction.

scholarly journals β-Myrcene/isobornyl methacrylate SG1 nitroxide-mediated controlled radical polymerization: synthesis and characterization of gradient, diblock and triblock copolymers

RSC Advances ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 3377-3395 ◽  
Author(s):  
Adrien Métafiot ◽  
Lysandre Gagnon ◽  
Sébastien Pruvost ◽  
Pascal Hubert ◽  
Jean-François Gérard ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Raw Materials ◽  
Triblock Copolymers ◽  
Controlled Radical Polymerization ◽  
Synthesis And Characterization ◽  
Nitroxide Mediated Polymerization

β-Myrcene (My), a natural 1,3-diene, and isobornyl methacrylate (IBOMA), from partially bio-based raw materials sources, were copolymerized by nitroxide-mediated polymerization (NMP) in bulk.

Synthesis of Block Copolymers Based on Polyethylene by Thermally Induced Controlled Radical Polymerization Using Mn2(CO)10

2015 ◽  
Vol 216 (9) ◽  
pp. 958-963 ◽  
Author(s):  
Mustafa Ciftci ◽  
Sébastien Norsic ◽  
Christophe Boisson ◽  
Franck D'Agosto ◽  
Yusuf Yagci
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Thermally Induced

Controlled radical polymerization of hydrophilic and zwitterionic brush-like polymers from silk fibroin surfaces

2020 ◽  
Vol 8 (45) ◽  
pp. 10392-10406
Author(s):  
Danielle L. Heichel ◽  
Ngoc Chau H. Vy ◽  
Shawn P. Ward ◽  
Douglas H. Adamson ◽  
Kelly A. Burke
Keyword(s):  
Protein Adsorption ◽  
Radical Polymerization ◽  
Silk Fibroin ◽  
Cell Attachment ◽  
Controlled Radical Polymerization

Silk fibroin films were modified with zwitterionic and hydrophilic brush-like polymers via surface-initiated ATRP, resulting in surfaces that reduced protein adsorption and cell attachment.

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